An absorbent for removing carbon dioxide from a fluid stream, comprising an aqueous solution a) of an amine of the general formula (I)

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in which R.sub.1, R.sub.2 and R.sub.3 are each independently selected from C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; each R.sub.4 is independently selected from hydrogen, C.sub.1-4alkyl and C.sub.1-4-hydroxyalkyl; each R.sub.5 is independently selected from hydrogen, C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; X is OH or NH(CR.sub.1R.sub.2R.sub.3); m is 2, 3, 4 or 5; n is 2, 3, 4 or 5; and o is 0 or 1; and b) at least one activator selected from b1) a sterically unhindered primary amine and/or a sterically unhindered secondary amine; and a carboanhydrase. The absorbent allows rapid absorption of carbon dioxide from fluid streams.

The invention relates to methods and systems for determining operating and/or dimensioning parameters of a gas treatment plant including at least one gas treatment unit as well as methods and systems for generating a request to initiate the determination of operating and/or dimensioning parameters of a gas treatment plant. The invention further relates to a computer program and non-volatile or non-transitory storage medium with the computer program, which when executed on one or more processors, performs one or more of the methods.

The invention relates to a process for removing a target gas from a gas stream rich in the target gas and to an absorbent solution for absorbing a gas, such as carbon dioxide, from a gas stream. The invention involves the use of a photoactive compound that is convertible from a first state to a second state upon irradiation to facilitate removal or collection of a target gas from a gas stream.

This disclosure relates to a process for removing acid gases from a gas stream enriched in acid gases, wherein: (a) the gas stream enriched in acid gases is contacted in an absorption zone with an absorption medium, wherein the absorption medium is an aqueous medium comprising an amine, to form a gas stream depleted in acid gases which comprises an entrained amine and an absorption medium enriched in acid gases; and (b) treating the gas stream depleted in acid gases which comprises an entrained amine in a scrubbing zone with a scrubbing medium, wherein the scrubbing medium is an aqueous medium comprising an amine, the amount of amine comprised by the scrubbing medium being about 0 to about 10.0 wt. %, to form a gas stream depleted in acid gases and in amine and a scrubbing medium enriched in amine.

An absorbent for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide, wherein the absorbent contains an aqueous solution, comprising: a) an amine or a mixture of amines of the general formula (I) wherein R.sup.1 is C.sub.1-C.sub.5-alkyl; R.sup.2 is C.sub.1-C.sub.5-alkyl; R.sup.3 is selected from hydrogen and C.sub.1-C.sub.5-alkyl; x is an integer from 2 to 10; and b) an ether or a mixture of ethers of the general formula (II): R.sup.4—[O—CH.sub.2—CH.sub.2].sub.y—OH; wherein R.sup.4 is C.sub.1-C.sub.5-alkyl; and y is an integer from 2 to 10; wherein R.sup.1 and R.sup.4 are identical; wherein the mass ratio of b) to a) is from 0.08 to 0.5. The absorbent is suitable for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide. The absorbent has a reduced tendency for phase separation at temperatures falling within the usual range of regeneration temperatures for the aqueous amine mixtures and is easily obtainable. ##STR00001##

A method of removing impurities from a natural gas stream. A selective solvent is provided that absorbs a first impurity at a first rate and a second impurity at a second rate that is slower than the first rate. The solvent is cooled to a temperature below 60° F. to provide a cooled solvent. The cooled solvent is contacted with the natural gas stream, thereby generating a rich solvent that includes the first impurity. The rich solvent is removed from the natural gas stream, wherein an amount of the first impurity remaining in the natural gas stream is below a sales gas requirement.

Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.

An acid gas absorbent includes at least one kind of secondary amine compound represented by formula (1): ##STR00001##
where R.sup.1 is a cyclopentyl group or a cyclohexyl group which may be substituted by a substituted or non-substituted alkyl group having 1 to 3 carbon atoms, R.sup.2 and R.sup.3 each indicate an alkylene group having 2 to 4 carbon atoms, and R.sup.2 and R.sup.3 may each be the same or different, and be a straight chain or have a side chain.

An elemental sulfur recovery unit comprising a thermal unit configured to combust an acid gas feed comprising hydrogen sulfide, an oxygen source, and a fuel gas to create a reaction furnace outlet stream, comprising elemental sulfur, a waste heat boiler configured to capture heat from the reaction furnace outlet stream to create a waste heat boiler effluent, a condenser configured to condense the waste heat boiler effluent to produce a non-condensed gases stream and a condensed stream comprising elemental sulfur, a process gas reheater configured to generate a hot gases stream, a hydrogenation reactor configured to convert the hot gases stream to create a hydrogenation effluent comprising hydrogen sulfide, a process desuperheater configured to cool the hydrogenation effluent to generate a cooled effluent, and an absorber unit configured to absorb the hydrogen sulfide from the cooled effluent to produce a hydrogen sulfide recycle stream and a waste gas stream.

An organic amine decarbonization solution includes: i) one or more organic amines serving as a carbon dioxide absorbent; and ii) an antioxidant. The antioxidant includes: a) one or more organometallic complexes of Formula [M.sub.x(L).sub.y]A.sub.n, wherein each M independently represents a central atom selected from the group consisting of transition metals, Group IVA metals and Group VA metals at a lower valence state; each L independently represents a bidentate or multidentate organic ligand with each ligating atom thereof being independently one of O, S, N and P; each A independently represents an uncoordinated counter-ion suitable for forming an outer sphere of a complex; x is 1, 2 or 3; y is 1, 2, 3, 4, 5, 6, 7 or 8; and n is 0, 1, 2, 3 or 4; and b) optionally one or more metal chelating agents.