A method of removing impurities from a natural gas stream. A selective solvent is provided that absorbs a first impurity at a first rate and a second impurity at a second rate that is slower than the first rate. The solvent is cooled to a temperature below 60° F. to provide a cooled solvent. The cooled solvent is contacted with the natural gas stream, thereby generating a rich solvent that includes the first impurity. The rich solvent is removed from the natural gas stream, wherein an amount of the first impurity remaining in the natural gas stream is below a sales gas requirement.

The present invention relates to methods for improving carbon capture using entrained catalytic-particles within an amine solvent. The particles are functionalized and appended with a CO.sub.2 hydration catalyst to enhance the kinetics of CO.sub.2 hydration and improve overall mass transfer of CO.sub.2 from an acid gas.

The present invention relates to an aqueous alkanolamine solution demonstrating low volatility comprising 2-di-methylamino-2-hydroxymethyl-1, 3-propanediol useful for removing acid gases from gaseous mixtures. Said aqueous alkanolamine solution may further comprise one or more of an acid or acid-forming compound, another amino compound, an activator, a physical solvent, or one or more other compounds used in gal-liquid treatment practices. Further, the present invention relates to a process for removing acid gases from a gaseous mixture, preferably hydrogen sulfide, comprising the step of contacting the gaseous mixture with said aqueous alkanolamine solution. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.

The present invention relates to a carbon dioxide absorbent comprising an oxygen-containing diamine, a cyclodiamine and a polyalkylene glycol dialkyl ether. The carbon dioxide absorbent according to the present invention can improve the carbon dioxide absorption capacity, absorption rate and regeneration performance thereof simultaneously by using the oxygen-containing diamine as a main absorbent, the cylodiamine as a rate enhancer, and the polyalkylene glycol dialkyl ether as a fine disproportionation agent and a regeneration promoter.

An elemental sulfur recovery unit comprising a thermal unit configured to combust an acid gas feed comprising hydrogen sulfide, an oxygen source, and a fuel gas to create a reaction furnace outlet stream, comprising elemental sulfur, a waste heat boiler configured to capture heat from the reaction furnace outlet stream to create a waste heat boiler effluent, a condenser configured to condense the waste heat boiler effluent to produce a non-condensed gases stream and a condensed stream comprising elemental sulfur, a process gas reheater configured to generate a hot gases stream, a hydrogenation reactor configured to convert the hot gases stream to create a hydrogenation effluent comprising hydrogen sulfide, a process desuperheater configured to cool the hydrogenation effluent to generate a cooled effluent, and an absorber unit configured to absorb the hydrogen sulfide from the cooled effluent to produce a hydrogen sulfide recycle stream and a waste gas stream.

The present invention relates to methods for improving carbon capture by providing particles within an amine solvent. The particles provide for increased turbulence at the interface between the counter-flowing gas and solvent, which allows for increased amine and carbamate salt diffusion between the liquid film and bulk.

An organic amine decarbonization solution includes: i) one or more organic amines serving as a carbon dioxide absorbent; and ii) an antioxidant. The antioxidant includes: a) one or more organometallic complexes of Formula [M.sub.x(L).sub.y]A.sub.n, wherein each M independently represents a central atom selected from the group consisting of transition metals, Group IVA metals and Group VA metals at a lower valence state; each L independently represents a bidentate or multidentate organic ligand with each ligating atom thereof being independently one of O, S, N and P; each A independently represents an uncoordinated counter-ion suitable for forming an outer sphere of a complex; x is 1, 2 or 3; y is 1, 2, 3, 4, 5, 6, 7 or 8; and n is 0, 1, 2, 3 or 4; and b) optionally one or more metal chelating agents.

A process for selectively removing hydrogen sulphide relative to carbon dioxide from a gaseous mixture containing at least hydrogen sulphide H.sub.2S and carbon dioxide CO.sub.2, includes a step of contacting the gaseous mixture with an absorbent solution including at least one amine, water, and at least one C.sub.2 to C.sub.4 thioalkanol. A use of the absorbent solution for selectively removing hydrogen sulphide relative to carbon dioxide from a gaseous mixture containing at least hydrogen sulphide and carbon dioxide, is disclosed. Disclosed is a use of at least one C.sub.2 to C.sub.4 thioalkanol as an additive in an absorbent solution including at least one amine, and water, for increasing the selectivity of the absorbent solution for the removal of hydrogen sulphide relative to carbon dioxide from a gaseous mixture containing at least hydrogen sulphide and carbon dioxide.

A carbonic acid gas absorbing material on an embodiment includes a liquid carbonic acid gas absorbent and a solid carbonic acid gas absorbent. The liquid carbonic acid gas absorbent is a solution containing a first amine and a solvent. The solid carbonic acid gas absorbent is a second amine of any one among a polyamine, a base material and an amine fixed to the base material, or a polyamine, a base material, and an amine fixed to the base material.

A co-axial co-current contactor (CA-CCC) is described herein. The CA-CCC includes an outer annular support ring and an inner annular support ring configured to maintain the CA-CCC within an outer pipe and an inner pipe, respectively. The CA-CCC includes rich liquid flow channels located between the outer annular support ring and the inner annular support ring that are configured to allow a rich liquid stream to flow through the CA-CCC, and a central gas entry cone and gas flow channels configured to allow a gas stream to flow through the CA-CCC. The CA-CCC further includes radial blades configured to secure the central gas entry cone to the inner annular support ring and allow a lean liquid stream to flow into the central gas entry cone and the gas flow channels. The CA-CCC provides for efficient incorporation of liquid droplets formed from the lean liquid stream into the gas stream.