A carbon dioxide absorbent of an embodiment includes a chain amine, a cyclic amine, and an acid. The chain amine is a compound expressed by Formula (1) of FIG. 1. R.sup.1 in Formula (1) is hydrogen or an alkyl chain having at least one hydroxyl group and 1 to 7 carbon atoms. R.sup.2 in Formula (1) is an alkyl chain having at least one hydroxyl group and 1 to 7 carbon atoms. R.sup.3 in Formula (1) is hydrogen, a straight alkyl chain having 1 to 7 carbon atoms, a branched alkyl chain having 1 to 7 carbon atoms, or a cyclic alkyl chain having 5 to 7 carbon atoms.

A method for treating sulfur contaminants is provided. The method comprises introducing a methylmorpholine-N-oxide solution to a vessel, wherein the vessel comprises a water layer and a gas layer, wherein the water layer and the gas layer comprise the hydrogen sulfide; introducing methylmorpholine-N-oxide into the water layer; and treating the water layer by allowing the methylmorpholine-N-oxide to react with the hydrogen sulfide.

The use of an amine of the formula (I)

##STR00001##

in which the R.sup.1 to R.sup.5 radicals are each as defined in the description, and an absorbent and a process for removing acidic gases from a fluid stream, especially for selectively removing hydrogen sulfide over carbon dioxide. The invention also relates to particular amines suitable for selective removal of hydrogen sulfide. Absorbents based on amines of the formula (I) have high selectivity, high loading capacity and good regeneration capacity.

The use of an amine of the formula (I) ##STR00001##
in which the R.sup.1 to R.sup.5 radicals are each as defined in the description, and an absorbent and a process for removing acidic gases from a fluid stream, especially for selectively removing hydrogen sulfide over carbon dioxide. The invention also relates to particular amines suitable for selective removal of hydrogen sulfide. Absorbents based on amines of the formula (I) have high selectivity, high loading capacity and good regeneration capacity.

The embodiment provides an acidic gas absorbent. The acidic gas absorbent comprises an amine compound of the formula (1) and a cyclic amino compound of the formula (2) or (3):

##STR00001##

[In the formulas, each R.sup.1 is independently a straight-chain hydroxyalkyl having a hydroxy at the terminal; R.sup.2 is a branched-chain secondary alkyl group; R.sup.3 and R.sup.4 are hydrogen, hydroxy, a hydroxyalkyl or aminoalkyl, provided that at least one of R.sup.3 and R.sup.4s is a hydroxyalkyl or aminoalkyl; each p is independently an integer of 2 to 4; each R.sup.5 is independently hydrogen, hydroxy, or a hydroxyalkyl or aminoalkyl, provided that at least one of R.sup.5s is a hydroxyalkyl or aminoalkyl; and q is an integer of 3 to 8.]

The acidic gas removal method and apparatus according to the embodiment uses the above acidic gas absorbent.

The present invention aims to provide a carbon dioxide absorbent that can efficiently absorb, fix, and simply separate and recover carbon dioxide in the air. The present invention relates to an atmospheric carbon dioxide absorbent consisting of an amine selected from the group consisting of m-xylylene diamine, benzylamine, phenethylamine, p-methoxybenzylamine, and p-trifluoromethylbenzylamine, and water, and having the amine content of 1 to 50 wt % with respect to the total amount. The present invention also relates to a method for generating carbon dioxide which uses the aforementioned carbon dioxide absorbent and is simple and superior in energy efficiency.

A class of water lean, organic solvents that can bind with various acid gasses to form acid gas bound molecules having a high degree of intramolecular hydrogen bonding which enables their use as regenerable solvents for acid gas capture. Unlike the other devices described in the prior art, the present invention takes advantage of shortened distances between the portions of the molecule that form hydrogen bonds within the structures when loaded with an acid gas so as to create a molecule with a higher internal bonding affinity and a reduced proclivity for agglomeration with other molecules.

A method of removing impurities from formation fluids includes introducing a formation fluid into a first end of a first tubular, directing the formation fluid along a first flow path toward a second end of the first tubular, redirecting the formation fluid along a second flow path defined by a second tubular arranged radially outwardly of the first flow path toward the first end, spraying a treatment fluid along the first flow path into the formation fluid, and directing a treated formation fluid through an outlet fluidically connected to the second flow path.

An in-line pipe contactor includes a first tubular having an outer surface and an inner surface. The inner surface defines a first flow path and the outer surface defines, in part, a second flow path. A second tubular is arranged radially outwardly of the first tubular. The second tubular includes an outer surface portion and an inner surface portion. The inner surface portion defines at least in part, the second flow path. A first end cap is mounted at the first end. The first end cap supports a first plurality of atomizers. At least one of the first plurality of atomizers is directed along the first flow path. A second end cap is mounted at the second end portion. The second end cap supports a second plurality of atomizers. At least one of the second plurality of atomizers is directed along the second flow path.

A process to remove H.sub.2S from a stream comprising the steps of adding a silica nanoparticle composition and optionally a triazine, wherein the stream is selected from the group consisting of Oil streams, Gas streams, CO.sub.2 point source purification streams and Geothermal Energy System streams.