According to embodiments disclosed herein, a method for absorption and desorption of CO.sub.2 may comprise absorbing CO.sub.2 onto an absorbent solution comprising a CO.sub.2-depleted amidoxime compound, wherein absorbing CO.sub.2 onto the absorbent solution comprising the CO.sub.2-depleted amidoxime compound may comprise contacting the absorbent solution with a gas comprising CO.sub.2 at a first temperature to form an absorbent solution comprising a CO.sub.2-enriched amidoxime compound; and then desorbing the CO.sub.2 from the absorbent solution comprising the CO.sub.2-enriched amidoxime compound, wherein desorbing the CO.sub.2 from the absorbent solution comprising the CO.sub.2-enriched amidoxime compound may comprise heating the absorbent solution comprising the CO.sub.2-enriched amidoxime compound to a second temperature greater than the first temperature to remove at least a portion of the CO.sub.2 from the CO.sub.2-enriched amidoxime compound and form the CO.sub.2-depleted amidoxime compound, wherein the second temperature is less than or equal to 80 C.

An acid gas absorbing mixture and a process for the removal of acid gases from gaseous mixtures containing them, such as natural gas, air and flue gases and an absorbent mixture usable for the removal of acid gases from gaseous mixtures containing them includes at least one diol of general formula R(OH).sub.2 having a normal boiling point equal to or greater than 100 C.; at least one organic base having a pK.sub.b (in water) lower than or equal to 3; and a polar aprotic solvent having a dielectric constant F at 25 C. greater than or equal to 30, a viscosity p at 25 C. lower than or equal to 40 cP (centipoise). The organic base/diol weight ratio is lower than or equal to 0.6, and the aprotic solvent/diol weight ratio is between 0.05 and 0.6.

A chemical composition for use in degassing of vessels is taught, said chemical composition including 1-10% by weight of an oxyalkylated dodecyl thiol; and 1-20% by weight of an alkyl di-substituted 9-decenamide. A method is further provided for degassing a vessel. The method includes charging said vessel with chemical composition and a carrier medium, wherein said chemical composition comprises 1-10% by weight of an oxyalkylated dodecyl thiol and 1-20% by weight of an alkyl di-substituted 9-decenamide.

Certain functionalized aldehydes scavengers may be used to at least partially scavenge sulfur-containing contaminants from fluid systems containing hydrocarbons and/or water. The contaminants scavenged or otherwise removed include, but are not necessarily limited to, H.sub.2S, mercaptans, and/or sulfides. Suitable scavengers include, but are not necessarily limited to, reaction products of glycolaldehyde with aldehydes; reaction products of glycolaldehyde with a nitrogen-containing reactant (e.g. an amine, a triazine, an imine, an aminal, and/or polyamines); non-nitrogen-containing reaction products of a hydrated aldehyde with certain second aldehydes; reaction products of 1,3,5-trioxane with hydroxyl-rich compounds (e.g. glyoxal, polyethylene glycol, polypropylene glycol, pentaerythritol, and/or sugars); and reaction products of certain aldehydes with certain phenols; and combinations of these reaction products.

A vapor/smoke capturing trap system featuring a smoke chamber trap for precipitating the smoke dispersed in the chamber. The chamber includes a bottom pool for containing a reservoir of a liquid solvent, and a gas filled portion in which a lower smog portion contains fog-sized droplets of the liquid solvent and into which the smoke is introduced, and an upper clear portion in which the concentration of the smoke and the droplets is decreased, respective of their concentration in the smog portion. A fog-condenser, disposed between the smog portion and the clear portion, precipitates the fog droplets of the smog portion into the pool. A fine mist generator streams a jet of fog-sized droplets of the liquid solvent mixed with smoke toward a concentration of the smoke at the smog portion. A closed loop gas circulator withdraws gas from the clear portion and recirculates the gas under pressure through the fine mist generator into the smog portion. Fresh smoke is introduced into the gas circulator via a smoke conveying conduit. A complementary smoke capturing method includes filling the reservoir, streaming the jet of fog-sized droplets toward a concentration of smoke dispersed within the lower smog portion of the gas filled portion, precipitating droplets, in the smog portion, into the pool by a fog-condenser disposed between the lower smog portion and the upper clear portion of the gas filled portion, recirculating under pressure, in a closed loop gas circulator, gas withdrawn from the clear portion into the smog portion through the fine mist generator, and conducting fresh smoke via smoke conveying conduit into the gas circulator.

Solvent absorption processes for separating components of an impure feed gas are disclosed. The processes involve two stages of gas purification. The acid gases including hydrogen sulfide, carbon dioxide and other sulfur compounds are simultaneously removed from the feed gas by contact with a physical solvent in two stages. The subject matter disclosed provides improved processes to reduce the operating costs of the system.

The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of the gas processing system.

The present disclosure relates to a cucurbituril-polyethylenimine-silica complex, a method for preparing the same and a carbon dioxide absorbent containing the same. According to the present disclosure, a cucurbituril-polyethylenimine-silica complex may be prepared by forming a complex wherein a cucurbituril is bound to polyethylenimine and including the same inside silica, and it may be used as a carbon dioxide absorbent with superior thermal stability and prevented formation of urea.

An absorbent composition includes an amino-siloxane having structure (I): wherein R is independently at each occurrence a C.sub.1-C.sub.6 aliphatic or aromatic radical; R.sup.2 is independently at each occurrence a C.sub.2-C.sub.10 aliphatic or aromatic radical; R.sup.3 is independently at each occurrence a hydrogen atom or a C.sub.1-C.sub.6 aliphatic or aromatic radical; R.sup.4 is independently at each occurrence a C.sub.1-C.sub.18 aliphatic or aromatic radical or R.sup.5, wherein R.sup.5 comprises structure (II): wherein X is independently at each occurrence an oxygen atom or a sulfur atom; w is between 0 and 5; y is between 0 and 10; and z is between 0 and 10; wherein, when R.sup.4 is R.sup.5 comprising the structure (II), a sum of w, y, and z is greater than or equal to 0, and, when R.sup.4 is not R.sup.5, a sum of w, y, and z is greater than or equal to 1.

##STR00001##

A composition, process, and apparatus are disclosed. The composition includes a cyclopropeneimine-carbon dioxide (CPI-CO.sub.2) adduct. The process includes forming the CPI-CO.sub.2 adduct by reacting a CPI with CO.sub.2 gas. The apparatus includes components for providing the CPI and mixing the CPI with CO.sub.2 gas. The mixing results in formation of the CPI-CO.sub.2 adduct.