An aminated siliceous adsorbent, which is the reaction product of dried acidified rice husk ash having disordered mesopores and an amino silane, wherein amine functional groups are present on an external surface and within the mesopores of the dried acidified rice husk ash, and wherein the aminated siliceous adsorbent has a carbon content of 24 to 30 wt. %, based on a total weight of the aminated siliceous adsorbent. A method of making the aminated siliceous adsorbent and a method of capturing CO.sub.2 from a gas mixture with the aminated siliceous adsorbent.

A zirconium metal-organic framework, which is a coordination product formed between zirconium ion clusters and a linker that links together adjacent zirconium ion clusters, wherein the linker is of formula (I) ##STR00001##
wherein R.sup.1 is hydrogen or an optionally substituted alkyl, and R.sup.2 to R.sup.4 are independently hydrogen, an optionally substituted alkyl, an optionally substituted aryl, or an optionally substituted arylalkyl. A method of capturing CO.sub.2 from a gas mixture with the zirconium metal-organic framework.

Polymeric sorbents for carbon dioxide are provided. More particularly, the polymeric sorbents are a reaction product of a divinylbenzene/maleic anhydride precursor polymeric material with a nitrogen-containing compound. The nitrogen-containing compound is covalently attached to the polymeric sorbents. Additionally, methods of sorbing carbon dioxide on the polymeric sorbents and compositions resulting from sorbing carbon dioxide on the polymeric sorbents are provided. The polymeric sorbents typically are porous and can selectively remove carbon dioxide from other gases such as methane or hydrogen.

A continuous desulfurization process and process system are described for removal of reduced sulfur species at gas stream concentrations in a range of from about 5 to about 5000 ppmv, using fixed beds containing regenerable sorbents, and for regeneration of such regenerable sorbents. The desulfurization removes the reduced sulfur species of hydrogen sulfide, carbonyl sulfide, carbon disulfide, and/or thiols and disulfides with four or less carbon atoms, to ppbv concentrations. In specific disclosed implementations, regenerable metal oxide-based sorbents are integrated along with a functional and effective process to control the regeneration reaction and process while maintaining a stable dynamic sulfur capacity. A membrane-based process and system is described for producing regeneration and purge gas for the desulfurization.

The present invention provides a process for capturing CO.sub.2 from a gas stream, the process at least comprising the steps of: (a) providing a CO.sub.2-containing gas stream; (b) contacting the gas stream as provided in step (a) in an adsorption zone with solid adsorbent particles thereby obtaining CO.sub.2-enriched solid adsorbent particles (c) passing CO.sub.2-enriched solid adsorbent particles as obtained in step (b) from the bottom of the adsorption zone to the bottom of a first desorption zone; (d) removing a part of the CO.sub.2 from the CO.sub.2-enriched solid adsorbent particles in the first desorption zone, thereby obtaining partly CO.sub.2-depleted solid adsorbent particles and a first CO.sub.2-enriched gas stream; (e) passing the partly CO.sub.2-depleted solid adsorbent particles as obtained in step (d) via a riser to a second desorption zone; (f) removing a further part of the CO.sub.2 from the partly CO.sub.2-depleted solid adsorbent particles in the second desorption zone thereby obtaining regenerated solid adsorbent particles and a second CO.sub.2-enriched gas stream; and (g) recycling regenerated solid adsorbent particles as obtained in step (f) to the adsorption zone of step (b); wherein the second desorption zone is located above the adsorption zone.

A natural gas adsorptive separation system and method is described. A method of separating natural gas includes directing a natural gas mixture through an activated carbon adsorption tower until the adsorption tower is saturated, collecting methane from the output of the adsorption tower, heating the saturated carbon adsorption tower with adsorbate using a heater and/or a vacuum pump in a closed loop circuit with the carbon adsorption tower until the input to the vacuum pump is within a specified temperature of the output of the heater, lowering the pressure in the heated activated carbon adsorption tower using the vacuum pump to desorb at least one hydrocarbon compound of the plurality of different hydrocarbon compounds, compressing and cooling the desorbed hydrocarbon compound, separating the cooled and compressed hydrocarbon compound into gas and liquid in a fluid separator, and collecting the liquid from the fluid separator.

A raw material supply device according to an embodiment of the present disclosure generates a reactive gas from a solution obtained by dissolving a solid raw material in a solvent or a dispersion obtained by dispersing the solid raw material in a dispersion medium. The raw material supply device includes: a container configured to store the solution or the dispersion; an injector configured to inject the solution or the dispersion into the container; an exhaust port configured to evacuate an interior of the container; and a filter provided in the container and configured to partition the interior of the container into a plurality of regions including a first region in which the injector is provided and a second region in which the exhaust port is provided.

An aminated siliceous adsorbent, which is the reaction product of dried acidified rice husk ash having disordered mesopores and an amino silane, wherein amine functional groups are present on an external surface and within the mesopores of the dried acidified rice husk ash, and wherein the aminated siliceous adsorbent has a carbon content of 24 to 30 wt. %, based on a total weight of the aminated siliceous adsorbent. A method of making the aminated siliceous adsorbent and a method of capturing CO.sub.2 from a gas mixture with the aminated siliceous adsorbent.

An atmospheric water harvesting generator includes an adsorbent with a nanopore structure and a moisture-condensing substrate with an amphiphilic structure such that water can be efficiently harvested from the atmosphere even in a dry climate, the generator is easy to operate with little power, and the flow of air can be controlled with a simple control to efficiently and continuously harvest water.

A composite material is used for desulfurization. The composite material contains activated carbon, alkali metal oxides, silicon oxides, iron oxides, and rare earth element oxides. The weight ratio among the activated carbon, iron oxides and rare earth element oxides is 100:(0.5-5):(1-10). The composite material, used as a sulfur adsorbent, has a higher sulfur breakthrough capacity and desulfurization rate.