[Summary]

[Problem]

The problem addressed by the present invention lies in providing an exhaust gas purification filter which can efficiently treat particulate matter in exhaust gas.

[Solution]

The present invention provides an exhaust gas purification filter including a substrate comprising a plurality of porous partitions, wherein the partitions form an exhaust gas flow path, a porous catalytic layer is provided on the partitions and the catalytic layer having a thickness of 10 m or greater is provided over at least 20% of the total length of the partitions in the lengthwise direction thereof, and the catalytic layer having a thickness of 10 m or greater is not present on the partitions 15 mm from an outflow side.

A hydrocarbon burner for an enclosed environment includes a heat exchanger having a first heat exchanger inlet connected to an inlet of the hydrocarbon burner and a first heat exchanger outlet connected to a heater, and a second heat exchanger inlet connected to a reactor outlet and a second heat exchanger outlet connected to an outlet of the hydrocarbon burner. A reactor includes a reactor inlet, the reactor outlet, and a catalyst mixture disposed in a reactor bed between the reactor inlet and the reactor outlet. The heater connects the first heat exchanger outlet to the reactor inlet. The reactor is a low temperature reactor configured to convert at least one hydrocarbon to at least one of H2O and CO2.

A gas clean-up unit includes a first conversion unit configured to perform a first conversion process of converting hydrogen cyanide contained in gas to be treated to ammonia, in presence of a first catalyst and at a first predetermined temperature; a second conversion unit configured to perform a second conversion process of converting carbonyl sulfide in the gas that has been subjected to the first conversion process to hydrogen sulfide, in presence of a second catalyst and at a second predetermined temperature lower than the first predetermined temperature; a cleaning unit configured to perform a cleaning process of bringing the gas into gas-liquid contact with cleaning liquid to remove the ammonia by cleaning; and a desulfurization unit configured to absorb and remove hydrogen sulfide in the gas by bringing the gas that has been subjected to the cleaning process into gas-liquid contact with absorbent.

The invention provides an automotive catalyst composite effective for abating carbon monoxide, hydrocarbons, and NOx emission in an automotive exhaust gas stream, which includes a catalytic material on a carrier, the catalytic material including a plurality of core-shell support particles comprising a core and a shell surrounding the core, the core including a plurality of particles having a primary particle size distribution d.sub.90 of up to about 5 ?m, wherein the core particles comprise particles of one or more metal oxides, the shell including nanoparticles of one or more metal oxides, wherein the nanoparticles have a primary particle size distribution d90 in the range of about 5 nm to about 1000 nm (1 ?m), and one or more platinum group metals (PGMs) on the core-shell support. The invention also provides an exhaust gas treatment system and related method of treating exhaust gas utilizing the catalyst composite.

The present disclosure generally provides low-temperature nitrogen oxides (NO.sub.x) adsorbers used in the treatment of a NO.sub.x-containing exhaust gas stream and to methods of preparing and using the same. In particular, the NO.sub.x adsorber composition includes an active metal and a metal oxide support, wherein the metal oxide support includes greater than 50% by weight ceria based on the total weight of the NO.sub.x adsorber composition, and wherein the active metal includes about 0.01% to about 5% by weight ruthenium based on the total weight of the NO.sub.x adsorber composition.

Described herein are catalytic converter substrates or cores based on triply periodic minimal surfaces (TPMS) geometries, along with methods of making and using the same.

An article includes a closed-environment air purification system that has a purifier through which air can be recirculated. The purifier is capable at a temperature of equal or less than 35 C. of converting hydrogen in the air to water and converting carbon monoxide in the air to carbon dioxide. The purifier has a reactor bed that includes media comprised of support particles and a metal catalyst disposed on the support particles.

An exhaust gas-purifying catalyst includes a support and a catalytic metal supported thereby. The support includes a composite oxide represented by AO.xB.sub.2-C.sub.O.sub.3, wherein A represents at least one of an element having a valence of 1 and an element having a valence of 2, B represents an element having a valence of 3, C represents one or more elements selected from iridium, ruthenium, tantalum, niobium, molybdenum, and tungsten, x represents a numerical value of 1 to 6, and represents a numerical value greater than 0 and less than 2. The catalytic metal includes one or more precious metals selected from rhodium, palladium, and platinum.

The invention provides an automotive catalyst composite that includes a catalytic material on a carrier, the catalytic material including a plurality of core-shell support particles including a core and a shell surrounding the core, wherein the core includes a plurality of particles having a primary particle size distribution d.sub.90 of up to about 5 ?m, wherein the core particles include particles of one or more molecular sieves and optionally particles of one or more refractory metal oxides; and wherein the shell comprises nanoparticles of one or more refractory metal oxides, wherein the nanoparticles have a primary particle size distribution d.sub.90 in the range of about 5 nm to about 1000 nm (1 ?m); and optionally, one or more platinum group metals (PGMs) on the core-shell support. The invention also provides an exhaust gas treatment system and related method of treating exhaust gas utilizing the catalyst composite.

An exhaust gas purification device includes: a substrate of wall-flow structure having an inlet cell, an outlet cell and a porous partition wall; an upstream catalyst layer provided inside the partition wall and disposed in an upstream portion, including an exhaust gas inflow end section, of the substrate; and a downstream catalyst layer provided inside the partition wall and disposed in a downstream portion, including an exhaust gas outflow end section, of the substrate. The downstream catalyst layer contains a carrier, and Rh supported on the carrier. The upstream catalyst layer contains a carrier, and Pd and/or Pt supported on the carrier.