Patent classifications
B01D2255/2065
SYSTEMS AND METHODS FOR REACTIVE REGENERATION OF SELECTIVE CATALYTIC REDUCTION CATALYSTS
A controller for controlling regeneration of a selective catalytic reduction (SCR) catalyst of an aftertreatment system is configured to cause increase in a SCR catalyst temperature of the SCR catalyst to a first regeneration temperature, the first regeneration temperature being lower than a high regeneration temperature that is equal to or greater than 500 degrees Celsius. The controller is configured to determine an amount of ammonia slip downstream of the SCR catalyst; and cause an increase in the SCR catalyst temperature to a second regeneration temperature greater than the first regeneration temperature but lower than the high regeneration temperature based on the determined amount of ammonia slip.
CATALYTIC OXIDATION OF CARBON BLACK EXHAUST GAS
Method for treating a carbon black tail gas wherein the carbon black tail gas is catalytically oxidized to produce an oxidized tail gas. The oxidized tail gas is then treated to remove particulate matter and sulfur oxides. If present, nitrogen oxides can be also removed.
Synthesis of high surface area, high entropy oxides
High surface area, high entropy oxides comprising multiple metal cations in a single-phase fluorite lattice material enables intrinsic catalytic activity without platinum group metals, tunable oxygen storage capacity, and thermal stability. These properties can be obtained through a facile sol-gel synthesis to provide a low-temperature route for production of phase-pure multi-cationic oxides. The resulting materials achieved significantly higher surface area and catalytic performance, taking advantage of all the properties endowed by the various cations in the composition.
Oxygen storage material and method for producing the same
An oxygen storage material including a ceria-zirconia based composite oxide containing a composite oxide of ceria and zirconia, wherein the ceria-zirconia based composite oxide comprises at least one rare-earth element selected from the group consisting of lanthanum, yttrium, and neodymium, and an amount of the rare-earth element(s) contained in total is 1 to 10% by atom in terms of element relative to a total amount of cerium and zirconium in the ceria-zirconia based composite oxide, 60 to 85% by atom of the entire amount of the rare-earth element(s) is contained in a near-surface upper-layer region extending from a surface of each primary particle of the ceria-zirconia based composite oxide to a depth of 50 nm in the primary particle, and 15 to 40% by atom of the entire amount of the rare-earth element(s) is contained in a near-surface lower-layer region extending from a depth of 50 nm to a depth of 100 nm in the primary particle, a content ratio of cerium and zirconium in the ceria-zirconia based composite oxide is in a range of 40:60 to 60:40 in terms of an atomic ratio ([Ce]:[Zr]), and the ceria-zirconia based composite oxide has an intensity ratio {I(14/29) value} between a diffraction line at 2θ=14.5° and a diffraction line at 2θ=29° which satisfies the following condition:
I(14/29) value≥0.032,
where the intensity ratio {I(14/29) value} is determined from an X-ray diffraction pattern using CuKα obtained by an X-ray diffraction measurement conducted after heating in air under a temperature condition of 1100° C. for 5 hours.
Catalytically active particulate filter
The present invention relates to a particulate filter which comprises a wall flow filter of length L and two different catalytically active coatings Y and Z, wherein the wall flow filter comprises channels E and A that extend in parallel between a first and a second end of the wall flow filter and are separated by porous walls which form the surfaces O.sub.E and O.sub.A, respectively, and wherein the channels E are closed at the second end and the channels A are closed at the first end. The invention is characterized in that the coating Y is located in the channels E on the surfaces O.sub.E and the coating Z is located in the channels A on the surfaces O.sub.A.
EXHAUST GAS EMISSIONS ABATEMENT SYSTEM
A system for removing methane oxidation catalyst (MOC) poisons from an exhaust gas including a methane abatement unit that may receive the exhaust gas having methane (CH.sub.4)and the MOC poisons. The methane abatement unit includes a guard bed that may remove the MOC poisons from the exhaust gas and may generate an intermediate exhaust gas having the CH.sub.4 and devoid of the MOC poisons. The guard bed includes a MOC poisons capturing component having a first transition metal oxide, an aluminum oxide (Al.sub.2O.sub.3) support material, and a dolomite-derived support material. The methane abatement unit also includes a MOC bed fluidly coupled to and positioned downstream from the guard bed. The MOC bed includes a MOC and may remove CH.sub.4 from the intermediate exhaust gas to generate a treated exhaust gas having less than approximately 200 parts per million volume (ppmv) CH.sub.4.
METAL OXIDE-BASED SCR CATALYST COMPOSITION
The present disclosure provides SCR catalyst compositions capable of reducing nitrogen oxide (NO.sub.x) emissions in engine exhaust. The catalyst compositions include a reducible metal oxide support containing ceria, one or more transition metal oxides as a redox promotor; and an oxide of niobium, tungsten, silicon, molybdenum, or a combination thereof as an acidic promotor. The redox promotor and the acid promotor are both supported on the reducible metal oxide support. Further provided are SCR catalyst articles coated with such compositions, processes for preparing such catalyst compositions and articles, an exhaust gas treatment system including such catalyst articles, and methods for reducing NO.sub.x in an exhaust gas stream using such catalyst articles and systems.
Cerium- and zirconium-based mixed oxide
The invention relates to a mixed oxide composed of zirconium, cerium, lanthanum and at least one rare earth oxide other than cerium and lanthanum, having a specific porosity and a high specific surface area; to the method for preparing same and to the use thereof in catalysis.
Exhaust gas purification system for a gasoline engine
Subject of the invention is an exhaust gas purification system for a gasoline engine, comprising in consecutive order the following devices: a first three-way-catalyst (TWC1), a gasoline particulate filter (GPF) and a second three-way-catalyst (TWC2), wherein the oxygen storage capacity (OSC) of the TWC2 is greater than the OSC of the GPF, wherein the OSC is determined in mg/l of the volume of the device. The invention also relates to methods in which the system is used and uses of the system.
HIGHLY CHLORINE- AND WATER-RESISTANT CATALYST, PREPARATION METHOD THEREFOR AND USE THEREOF
A preparation method for a highly chlorine- and water-resistant catalyst is provided. A mixture of at least one of SnO.sub.2, GeO.sub.2, and MoO.sub.2 with CeO.sub.2 is used as a catalyst support, face-centered cubic ruthenium oxide is used as an active component, and the catalyst with excellent chlorine- and water-resistance is prepared through selective adsorption regulation, which can realize safe and efficient purification of chlorine-containing organic waste gas at temperatures below 250° C.