B01D2255/2068

Nano-rare earth oxide doped support for trapping of NOx and/or SOx

An inorganic oxide material doped with nano-rare earth oxide particles that is capable of trapping one or more of NO.sub.x or SO.sub.x at a temperature that is less than 400 C. The nano-rare earth oxide particles have a particle size that is less than 10 nanometers. The catalyst support can trap at least 0.5% NO.sub.2 at a temperature less than 350 C. and/or at least 0.4% SO.sub.2 at a temperature less than 325 C. The catalyst support can trap at least 0.5% NO.sub.2 and/or at least 0.2% SO.sub.2 at a temperature that is less than 250 C. after being aged at 800 C. for 16 hours in a 10% steam environment. The catalyst support exhibits at least a 25% increase in capacity for at least one of NO.sub.x or SO.sub.x trapping at a temperature that is less than 400 C. when compared to a conventional rare earth doped support in a 10% steam environment.

Exhaust purification filter

Provided is a GPF capable of exhibiting better than conventional three-way purification function. A gasoline particulate filter (GPF) that is provided in an exhaust pipe of an engine and that performs purification by capturing particulate matter (PM) in exhaust gas is provided with a filter substrate in which a plurality of cells extending from an exhaust gas inflow-side end face to an outflow-side end face are defined by porous partition walls and in which openings at the inflow-side end face and openings at the outflow-side end face of the cells are alternately sealed; and a three-way catalyst (TWC) supported by the partition wall. The three-way catalyst is the GPF comprising a catalytic metal containing at least Rh, and a composite oxide having an oxygen storage capacity and containing Nd and Pr in a crystal structure.

Base Metal Catalyst and Method of Using Same

A method for treating the waste stream from a purified terephthalic acid (PTA) process is provided. The method comprises contacting a waste stream containing carbon monoxide (CO), volatile organic compounds (VOCs), and methyl bromide with a catalyst comprising a first base metal catalyst supported on an oxygen donating support that is substantially free of alumina, and at least one second base metal catalyst.

OXYGEN STORAGE MATERIAL AND METHOD FOR PRODUCING THE SAME
20200114334 · 2020-04-16 ·

An oxygen storage material including a ceria-zirconia based composite oxide containing a composite oxide of ceria and zirconia, wherein the ceria-zirconia based composite oxide comprises at least one rare-earth element selected from the group consisting of lanthanum, yttrium, and neodymium, and an amount of the rare-earth element(s) contained in total is 1 to 10% by atom in terms of element relative to a total amount of cerium and zirconium in the ceria-zirconia based composite oxide, 60 to 85% by atom of the entire amount of the rare-earth element(s) is contained in a near-surface upper-layer region extending from a surface of each primary particle of the ceria-zirconia based composite oxide to a depth of 50 nm in the primary particle, and 15 to 40% by atom of the entire amount of the rare-earth element(s) is contained in a near-surface lower-layer region extending from a depth of 50 nm to a depth of 100 nm in the primary particle, a content ratio of cerium and zirconium in the ceria-zirconia based composite oxide is in a range of 40:60 to 60:40 in terms of an atomic ratio ([Ce]:[Z]), and the ceria-zirconia based composite oxide has an intensity ratio {I(14/29) value} between a diffraction line at 2=14.5 and a diffraction line at 2=29 which satisfies the following condition: I(14/29) value0.032,
where the intensity ratio {I(14/29) value} is determined from an X-ray diffraction pattern using CuK obtained by an X-ray diffraction measurement conducted after heating in air under a temperature condition of 1100 C. for 5 hours.

Exhaust gas purification device

An exhaust gas purification device which has improved exhaust gas purification performance. An exhaust gas purification device which includes a first catalyst layer that contains: a Pd-supporting catalyst which is obtained by having alumina carrier particles support Pd; a first Rh-supporting catalyst which is obtained by having first ceria-zirconia carrier particles support Rh; and second ceria-zirconia carrier particles. This exhaust gas purification device is configured such that: the ceria concentration in the first ceria-zirconia carrier particles is 30 wt % or less; and the amount of ceria in the second ceria-zirconia carrier particles is larger than the amount of ceria in the first ceria-zirconia carrier particles.

Catalyst Composition Comprising Magnetic Material Adapted for Inductive Heating
20240024860 · 2024-01-25 · ·

The invention provides a catalyst composition, including a mixture of catalytically active particles and a magnetic material, such as superparamagnetic iron oxide nanoparticles, capable of inductive heating in response to an applied alternating electromagnetic field. The catalytically active particles will typically include a base metal, platinum group metal, oxide of base metal or platinum group metal, or combination thereof, and will be adapted for use in various catalytic systems, such as diesel oxidation catalysts, catalyzed soot filters, lean NOx traps, selective catalytic reduction catalysts, ammonia oxidation catalysts, or three-way catalysts. The invention also includes a system and method for heating a catalyst material, which includes a catalyst article that includes the catalyst composition and a conductor for receiving current and generating an alternating electromagnetic field in response thereto, the conductor positioned such that the generated alternating electromagnetic field is applied to at least a portion of the magnetic material.

Low cost oxidation catalysts for VOC and halogenated VOC emission control
10569256 · 2020-02-25 · ·

The current embodiments relate to ruthenium-containing supported catalysts, including processes for their manufacture and use, which destroy, through catalytic oxidation, hazardous compounds contained in chemical industrial emissions and otherwise produced from industrial processes.

EXHAUST GAS PURIFYING FILTER AND PRODUCTION METHOD THEREOF
20200055039 · 2020-02-20 · ·

The present invention provides an exhaust gas purifying filter capable of efficiently burning and removing particulates captured by a partition wall, and a production method thereof. This exhaust gas purifying filter (CSF) of the present invention includes at least a honeycomb substrate having a porous partition wall configured to capture particulates (PM) such as soot in exhaust gas, and a catalyst carried by the honeycomb substrate and configured to burn and remove the particulates captured by the partition wall of the honeycomb substrate and deposited within cells, wherein the catalyst is carried concentrically in a shallow portion from the surface of the cell wall on the exhaust gas inflow side of the honeycomb substrate, and 65% or more of the total mass of the catalyst is present in a depth region from the surface of the cell wall of the honeycomb substrate up to 2/10 a with reference to the wall thickness a of the partition wall.

EXHAUST GAS PURIFICATION CATALYST AND EXHAUST GAS PURIFICATION METHOD USING THE SAME

In order to provide an exhaust gas purification catalyst capable of purifying hydrocarbons, carbon monoxide, and nitrogen oxides in exhaust gas at low temperatures, the exhaust gas purification catalyst according to the present invention includes: a region (2) containing palladium on a three-dimensional structure (1), and a first region (3) and a second region (4) provided on the region (2) in order from an inflow side of exhaust gas to an outflow side of exhaust gas. The concentration of neodymium contained in the first region (3) is higher than the concentration of neodymium contained in the second region (4).

Application of synergized-PGM with ultra-low PGM loadings as close-coupled three-way catalysts for internal combustion engines

Synergized platinum group metals (SPGM) with ultra-low PGM loadings employed as close-coupled (CC) three-way catalysts (TWC) systems with varied material compositions and configurations are disclosed. SPGM CC catalysts in which ZPGM compositions of binary or ternary spinel structures supported onto support oxides are coupled with commercialized PGM UF catalysts and tested under Federal Test Procedure FTP-75 within TGDI and PI engines. The performance of the TWC systems including SPGM CC (with ultra-low PGM loadings) catalyst and commercialized PGM UF catalyst is compared to the performance of commercialized PGM CC and PGM UF catalysts. The disclosed TWC systems indicate that SPGM CC TWC catalytic performance is comparable or even exceeds high PGM-based conventional TWC catalysts, with reduced tailpipe emissions.