The invention relates to a process for recovering hydrogen (b) from crude gas (a) from a coke oven (110) in which the crude gas (a) produced in the coke oven (110) is initially compressed and in which impurities are subsequently removed from the crude gas (a) by pressure swing adsorption, wherein oxygen is depleted from the crude gas (a) using nonthermal plasma prior to the pressure swing adsorption, and to a plant for recovering hydrogen from crude gas.

This invention relates to an aqueous dispersion of particles, the dispersion having a particle content of 10-70 wt %, and the particles comprising, on an oxide basis: (a) 10-98 wt % in total of ZrO.sub.2+HfO.sub.2, and (b) 2-90 wt % in total of AI.sub.2O.sub.3, CeO.sub.2, La.sub.2O.sub.3, Nd.sub.2O.sub.3, Pr.sub.6O.sub.11, Y.sub.2O.sub.3, or a transition metal oxide, wherein the dispersion has a Z-average particle size of 100-350 nm and the particles have a crystallite size of 1-9 nm. The invention also relates to a substrate coated with the aqueous dispersion of particles.

The invention relates to a catalytic converter for removing carbon monoxide, hydrocarbons and nitrogen oxides from the exhaust gas of internal combustion engines operated with stoichiometric air-fuel mixture, which catalytic converter comprises a substrate of the length L and a catalytic coating, characterized in that the coating is located on the walls of the substrate and extends, proceeding from one end of the substrate, over a length corresponding to at least 50% of L and comprises active aluminum oxide, two cerium/zirconium/rare-earth-metal mixed oxides different from each other, and at least one platinum group metal.

Described herein are catalytic converter substrates or cores based on triply periodic minimal surfaces (TPMS) geometries, along with methods of making and using the same.

An exhaust gas purification catalyst is provided which can be more enhanced in NOx purification performance. An exhaust gas purification catalyst including a substrate, a NOx storage layer located over the substrate, an oxidation catalyst layer located over a part of the NOx storage layer, the part being located upstream in an exhaust gas flow direction, and a reduction catalyst layer located over a part of the NOx storage layer, the part being located downstream in an exhaust gas flow direction, wherein the NOx storage layer includes an oxidation catalyst including Pd or Pd and Pt, and a NOx storage material including at least one element selected from the group consisting of an alkali metal, an alkali earth metal and a rare-earth element, the oxidation catalyst layer includes an oxidation catalyst including Pt or Pt and Pd, the reduction catalyst layer includes a reduction catalyst including Rh, and a total content rate (mol %) of Pt and Pd based on a total content rate (100 mol %) of metal element(s) in the oxidation catalyst layer is higher than a total content rate (mol %) of Pt and Pd based on a total content rate (100 mol %) of metal elements in the NOx storage layer.

An organic substance decomposition catalyst that contains a perovskite-type complex oxide denoted by a formula A.sub.xB.sub.yM.sub.zO.sub.w, where A includes Ba, B includes Zr, M represents Mn and Co, a composition ratio of Mn to Co is represented by Mn:Co=z1:z2, z=z1+z2, y+z=1.000, 0.100≤z1+z2≤0.200, 0.00<z1/(z1+z2)<0.75, and w represents a positive value satisfying electrical neutrality.

A catalyst for gasoline engine exhaust gas after-treatment, comprising Pt and optionally at least one other platinum group metal on a hydrothermal stable support material which is coated onto a gasoline particulate filter. The catalyst oxidizes particulate matter trapped in the gasoline particulate filter under low temperature and abates NO.sub.x, CO and HC. Also a process for preparing the catalyst is disclosed, and a method for after-treatment of gasoline engine exhaust gas using the catalyst is disclosed.

An organic material decomposition catalyst that contains BaCO.sub.3 and a perovskite composite oxide represented by A.sub.xB.sub.yM.sub.zO.sub.w, wherein A contains Ba, B contains Zr, and M denotes Mn. A peak intensity I(BaCO.sub.3(111)) of BaCO.sub.3(111) of the BaCO.sub.3 and a peak intensity I(BaZrO.sub.3(110)) of a perovskite composite oxide A.sub.xB.sub.yM.sub.zO.sub.w(110) of the perovskite composite oxide represented by A.sub.xB.sub.yM.sub.zO.sub.w, each determined by X-ray diffractometry of the organic material decomposition catalyst, have a ratio I(BaCO.sub.3(111))/I(BaZrO.sub.3(110)) in a range of 0.022 to 0.052. In another aspect, in the perovskite composite oxide represented by A.sub.xB.sub.yM.sub.zO.sub.w, 1.01≤x≤1.06, 0.1≤z≤0.125, and y+z=1 are satisfied, w denotes a positive value that satisfies electroneutrality, and the organic material decomposition catalyst has a specific surface area in the range of 12.3 to 16.9 m.sup.2/g.

A catalyst article and its use in an exhaust system for internal combustion engines is disclosed. The catalyst article comprises a substrate which is a wall-flow filter, a first catalyst composition, and a second catalyst composition. The first and second catalyst compositions each independently comprise an oxygen storage component (OSC) derived from a CeZr mixed oxide sol having a D90 of less than 1.3 micron and a particulate inorganic oxide having a D90 of from 1 to 20 microns.

Herein disclosed are compositions for passive NOx adsorption and oxidation that include at least a manganese-based oxide and one or more promoter materials and methods for making and using said compositions. The promotor materials may include a rare earth, transition, or main group metal. The compositions may be used in NOx emission control system and adsorbs NOx compounds at low temperatures and then release NOx at higher temperatures, where the NOx can be oxidized, without the hybridized MnOX composition breaking down. The compositions are capable of maintaining a sufficiently large surface area at high temperatures found in the emissions gas streams of internal combustion engines necessary for the complete elimination of NOx.