The present disclosure relates to a substrate containing passive NO.sub.x adsorption (PNA) materials for treatment of gases, and washcoats for use in preparing such a substrate. Also provided are methods of preparation of the PNA materials, as well as methods of preparation of the substrate containing the PNA materials. More specifically, the present disclosure relates to a coated substrate containing PNA materials for PNA systems, useful in the treatment of exhaust gases. Also disclosed are exhaust treatment systems, and vehicles, such as diesel or gasoline vehicles, particularly light-duty diesel or gasoline vehicles, using catalytic converters and exhaust treatment systems using the coated substrates.

There are provided an exhaust gas-purifying three-way catalyst having a large palladium surface area and excellent in heat resistance and three-way purification performance, easy to produce, and also excellent in productivity, and a method for producing the same, an exhaust gas-purifying catalytic converter, and the like. An exhaust gas-purifying three-way catalyst comprising at least at least one selected from the group consisting of base material particles (A) of a Nd-solid dissolved zirconia-based complex oxide comprising Nd and Zr as constituent metal elements in the following mass proportions in terms of oxides, and base material particles (B) of a La-solid dissolved zirconia-based complex oxide comprising La and Zr, and optionally Nd, as constituent metal elements in the following mass proportions in terms of oxides; and Pd catalyst particles supported on the at least one selected from the group consisting of the base material particles (A) and the base material particles (B), under a reducing atmosphere:

TABLE-US-00001 (Nd-solid dissolved zirconia-based complex oxide) ZrO.sub.2 50 to 75% by mass Nd.sub.2O.sub.3 25 to 50% by mass (La-solid dissolved zirconia-based complex oxide) ZrO.sub.2 50 to 80% by mass La.sub.2O.sub.3 20 to 50% by mass Nd.sub.2O.sub.3 0 to 20% by mass

with a total amount of La.sub.2O.sub.3 and Nd.sub.2O.sub.3 being 20 to 50% by mass.

The present application is directed to a method for the conversion of nitrous acid to dinitrogen gas. In particular, the present application relates to a method for the conversion of nitrous acid to dinitrogen gas by contacting the nitrous acid with an amine-functionalized metal organic framework.

An exhaust purification system includes an LAF sensor provided in an exhaust pipe and generates a signal corresponding to an air-fuel ratio of exhaust gas. An upstream catalytic converter is downstream of the LAF sensor and has a catalyst to purify the exhaust gas. An O2 sensor is downstream of the upstream catalytic converter, and generates a signal corresponding to the air-fuel ratio of the exhaust gas. A GPF is downstream of a the O2 sensor and purifies the exhaust gas. An ECU controls an air-fuel mixture in an engine using output signal KACT of the LAF sensor and an output signal VO2 of the O2 sensor such that the air-fuel ratio of exhaust gas flowing into the GPF converges to a target value near the stoichiometric ratio. The GPF has a filter substrate and a downstream TWC supported by a partition of the filter substrate.

The present disclosure is directed to producing zeolite structures, especially Zeolite SSZ-39, using organic structure directing agents (OSDAs). In particular, the OSDAs comprise isomeric mixtures of N,N-dialkyl piperidinium cations.

An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising platinum (Pt), manganese (Mn) and a first support material; a second washcoat region comprising a platinum group metal (PGM) and a second support material; and a substrate having an inlet end and an outlet end; wherein the second washcoat region is arranged to contact the exhaust gas at the outlet end of the substrate and after contact of the exhaust gas with the first washcoat region.

Methods and systems are provided for a diesel oxidation catalyst. In one example, the diesel oxidation catalyst comprises a washcoat with different catalytically active portions for reacting with one or more of carbon containing compounds and NO.sub.x. The diesel oxidation catalyst is located upstream of a particulate filter in an exhaust passage.

An exhaust system for a compression ignition engine comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from the compression ignition engine, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component; and a substrate, wherein the platinum group metal (PGM) component, the alkaline earth metal component and the support material are disposed on the substrate.

A composition including cerium and zirconium oxides, including at least 30 wt.-% cerium oxide is desired. Following calcination at a temperature of 900 DEG C. for 4 hours, the composition has two populations of pores, the diameters of the first population being centered around a value of between 5 nm and 15 nm for a composition including 30% to 65% cerium oxide or between 10 nm and 20 nm for more than 65% cerium oxide and the diameter of the second population being centered around a value of between 45 nm and 65 nm for 30% to 65% cerium oxide or between 60 nm and 100 nm for more than 65% cerium oxide.

A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; and a first catalytic region on the substrate; wherein the first catalytic region comprises a first PGM component and a first alumina, wherein the first alumina is doped with a first dopant of at least 5 wt. %, and wherein the first dopant is selected from the group consisting of Zr, Ta, Mo, W, Ti, Nb, and a combination thereof.