The present disclosure features a method of making an engine aftertreatment catalyst, where the engine aftertreatment catalyst includes a metal oxide, a metal zeolite, and/or vanadium oxide when the metal oxide is different from vanadium oxide, each of which can be independently surface-modified with a surface modifier. The method includes providing a solution including an organic solvent and an organometallic compound; mixing the solution with a metal oxide, a metal zeolite, and/or a vanadium oxide to provide a mixture; drying the mixture; and calcining the mixture to provide a surface-modified metal oxide catalyst, a surface-modified metal zeolite catalyst, and/or a surface-modified vanadium oxide catalyst. The organometallic compound can be, for example, a metal alkoxide, a metal carboxylate, a metal acetylacetonate, and/or a metal organic acid ester.

An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising a first platinum group metal (PGM), a first support material and a NO.sub.x storage component; a second washcoat region comprising platinum (Pt), manganese (Mn) and a second support material; and a substrate having an inlet end and an outlet end.

A porous honeycomb structure including multiple co-catalyst particles and multiple inorganic binder particles of smaller particle diameter than the co-catalyst particles. Each co-catalyst particle is comprised of a ceria-zirconia solid solution. The inorganic binder particles reside between the co-catalyst particles. In the honeycomb structure, an exposure fraction of the co-catalyst particles from the inorganic binder particles on a cross-section of the honeycomb structure is within a range of 3 to 10%.

A method of processing a mixture of heated vapors, at least two of which substantially differ in polarity from each other, the method comprising directing said mixture of heated vapors at a temperature of at least 150 C. through a hydrophobic or hydrophilic mesoporous membrane comprising a mesoporous coating of hydrophobized or hydrophilized metal oxide nanoparticles, respectively, wherein the hydrophobic mesoporous membrane permits passage of one or more hydrophobic heated vapors and blocks passage of one or more hydrophilic heated vapors, and wherein the hydrophilic mesoporous membrane permits passage of one or more hydrophilic heated vapors and blocks passage of one or more hydrophobic heated vapors. The method is particularly directed to embodiments where the heated vapors emanate from a pyrolysis process. An apparatus for achieving the above-described method is also described.

A catalyst for exhaust gas purification includes a carrier and a platinum group element supported on the carrier. The carrier includes a modified aluminum borate which contains an aluminum borate and at least one of oxides of an element selected from the group consisting of Zr, Si, Fe, and Ti. The modified aluminum borate contains the oxide in a concentration of 0.06% to 18% by mass relative to the mass of the modified aluminum borate.

The invention relates to a wall flow filter for removing particulate matter from the exhaust of internal combustion engines, comprising a wall flow filter substrate having a length L, and a coating F, the wall flow filter substrate being provided with channels E and A which run parallel between a first end and a second end of the wall flow filter substrate, separated by porous walls, and forming surfaces O.sub.E and O.sub.A. Channels O.sub.E are closed at the second end and channels A are closed at the first end. Coating F is disposed in the porous walls and/or on surfaces O.sub.E, but not on surfaces O.sub.A, and comprises a particulate metal compound and no precious metal, characterised in that the particulate metal compound catalyses the oxidation of soot.

A composition of formula

Ce.sub.1-a-b-cN.sub.aM.sub.bD.sub.cO.sub.xI

wherein M stands for one or more elements from the group of alkaline metals, except sodium, N is Bi and/or Sb, D is present, or is not present, and if present is selected from one or more of Mg, Ca, Sr, Ba; Y, La, Pr, Nd, Sm, Gd, Er; Fe, Zr, Nb, Al; a is a number within the range of 0<a0.9, b is a number within the range of 0<b0.3, c is a number within the range of 0<c0.2, a plus b plus c is <1, and x is a number within the range of 1.2x2, and its use for exhaust gas aftertreatment systems of Diesel engines, gasoline combustion engines, lean burn engines and power plants.

An exhaust aftertreatment system for purifying exhaust gases from a compression-ignition engine includes a first exhaust aftertreatment device including an oxidation catalyst and a particulate filter element fluidly coupled to an exhaust outlet of the engine. A second exhaust aftertreatment device includes an ammonia-selective catalytic reduction catalyst fluidly coupled to a downstream outlet of the first exhaust aftertreatment device. A reductant injection system is configured to inject urea reductant into the exhaust gas feedstream between the first exhaust aftertreatment device and the second exhaust aftertreatment device.

Provided are a catalyst for internal combustion engine exhaust gas purification, including a first catalyst component region (a) having a catalyst component layer containing Rh at a concentration of 0.1 to 3.0 g/L at a length of 3 to 30 mm on an upstream side, a second catalyst component region (b) having a catalyst component layer containing Pd at a concentration of 1.0 to 20.0 g/L at a length of 10 to 100 mm on a downstream side, and a third catalyst region (c) mainly containing rhodium at a concentration of 0.05 to 1.0 g/L and an oxygen storage material at a concentration of 30 to 150 g/L at a length of 25 to 150 mm, if necessary, on a monolithic support along a flow of the exhaust gas as a noble metal catalyst active component, and a system for purifying internal combustion engine exhaust gas using the catalyst. These suppress formation and discharge of N.sub.2O at the time of purification of exhaust gas, and make purification of NOx and HC possible with a small amount of a noble metal from the time of cold starting.

An exhaust gas treatment system for an internal combustion engine includes an exhaust gas pathway configured to receive exhaust gas from the internal combustion engine, a first ammonia injector configured to inject ammonia into the exhaust gas pathway at a first rate, and a first treatment element positioned downstream of the first ammonia injector. A second ammonia injector is positioned downstream of the first treatment element. The second ammonia injector is configured to inject ammonia into the exhaust gas pathway at a second rate. A controller is configured to estimate an amount of particulate present in the exhaust gas and adjust at least one of the first rate or the second rate based on the estimate.