The invention discloses a preparation method and application of a denitration catalyst with wide operating temperature for flue gas, which utilizes an organic vanadium compound as a vanadium precursor, and titanium dioxide powder or titanium tungsten powder as a carrier, and is prepared by mechanical ball milling method and heat treatment to obtain a catalyst, which denitration of fixed source flue gas under wide temperature range. Compared with the existing arts, the present invention includes minor modifications to the traditional vanadium tungsten titanium catalyst system and adopts the mechanical ball milling method, the activity and resistance to sulfur and water poisoning are improved significantly, thus providing a preparation technology of SCR denitration powder catalyst which is green, highly efficient, low cost and simple in operation. Through the interaction of the organic vanadium precursor with the carrier, the vanadium surface atom concentration of the catalyst is higher, the species of polymeric vanadium is more, and the vanadium oxide is more easily reduced, thereby obtaining higher denitrification activity at low temperature. The denitration catalyst of the present invention has relatively higher activity at 200-450° C. while having good resistance to sulfur and water poisoning.

The present disclosure provides msect-4 molecular sieves with OFF and ERI topologies, a preparation method therefor, and applications thereof. An eight-membered ring small pore molecular sieve used as a raw material is dispersed in an aqueous phase. Following that, caustic potash, an aluminum source, and an organic structure-directing agent (OSDA) are added. The pH value is then adjusted to be greater than 10, and a silicon source is introduced to attain the desired silicon-aluminum ratio, followed by stirring reaction, aging, crystallization, filtration, washing, ammonia exchange reaction, drying, and calcination. The msect-4 molecular sieves with OFF and ERI topologies, the preparation method therefor, and applications exhibit excellent hydrothermal stability, a plurality of adsorption sites exposed by a regular bone-like structure, and a large specific surface area. Consequently, this molecular sieves find applicability across various technical fields including selective catalytic reduction, passive adsorption, and catalytic cracking, and has broad application prospects.

The present invention pertains to a catalyst for use in the selective catalytic reduction (SCR) of nitrogen oxides comprising a monolithic substrate and a coating A, which comprises an oxidic metal carrier comprising an oxide of titanium and a catalytic metal oxide which comprises an oxide of vanadium wherein the mass ratio vanadium/titanium is 0.07 to 0.26.

Some non-limiting embodiments of the present disclosure relate to a method of regenerating at least one filter medium, the method comprising flowing a flue gas stream through or by the at least one filter medium at a first temperature and increasing the temperature of the flue gas stream from the first temperature to a second temperature that exceeds the first temperature. Some non-limiting embodiments of the present disclosure relate to a method of cleaning a flue gas stream, the method comprising maintaining the NO.sub.x removal efficiency by increasing the temperature of the flue gas stream from the first temperature to a second temperature that exceeds the first temperature.

A method for production of vanadium catalysts, including steps of 1) providing a mixture comprising a TiO.sub.2-based support and a composite oxide containing vanadium and antimony; 2) preparing a slurry containing the mixture obtained from step 1), and additive comprising at least one species selected from the group consisting of Si, Al, Zr, Ti, W and Mo, and a solvent; and 3) applying the slurry onto a substrate or processing the slurry into shaped bodies. The vanadium catalysts obtained/obtainable from the method, and use thereof for abatement of nitrogen oxides (NOx).

A method for purifying combustion exhaust gas, comprising: placing a denitration catalyst in gas stream to remove nitrogen oxides from a combustion exhaust gas, wherein the denitration catalyst comprises a shaped product comprising a catalyst component and having microcracks on the surface of the shaped-product, and 80% to 100% of the microcracks on the number basis have an angle of a longitudinal direction of the microcracks with respect to a main direction of the gas stream within ±30 degrees.

The present invention relates to a hollow filter candle (1) which has, via impregnation of the inside with a catalyst solution, a concentration gradient of catalyst metals from the inside to the outside across the wall thickness thereof. The present invention furthermore relates to a method for producing a filter candle (1) according to the invention and the use of the filter candle (1) according to the invention for exhaust gas cleaning, in particular in waste incineration plants.

The present disclosure relates to a carbon dioxide capture device comprising a first reactor and a second reactor both of which show a (photo)anode containing or connected to oxygen evolution and/or carbon dioxide evolution catalyst(s) and a (photo)cathode containing or connected to an oxygen reduction catalyst, wherein the first reactor comprises an anion exchange membrane placed between the porous (photo)anode and porous (photo)cathode, and the second reactor comprises a proton exchange membrane placed between the porous (photo)anode and porous (photo)cathode. On the porous (photo)cathode side of the first reactor there is a fluid inlet able to carry carbon dioxide, air and water, and on the side of the porous (photo)cathode of the second reactor there is a fluid outlet able to carry carbon dioxide and water.

Proposed inventions are a recipe of denitrification-oxidation complex catalyst containing an SCR catalyst and an oxidation catalyst to simultaneously remove nitrogen oxides, carbon monoxide, hydrocarbons, and ammonia, a manufacturing method thereof, an exhaust gas treatment method using the denitrification-oxidation complex catalyst, and an SCR denitrification system including the denitrification-oxidation complex catalyst. The denitrification-oxidation complex catalyst simultaneously removes nitrogen oxides, carbon monoxide, hydrocarbons, and ammonia and exhibits an increased catalytic effect compared to the cases where the denitrification catalyst used alone and the denitrification and the oxidation catalyst ratios are and not properly balanced. When the denitrification-oxidation complex catalyst is applied to an SCR denitrification system, the structure is simplified, space is saved, cost is reduced, and catalyst maintenance is easy.

The present invention relates to a catalyst, preferably for the selective catalytic reduction of NOx, for the oxidation of ammonia, for the oxidation of NO and for the oxidation of a hydrocarbon, the catalyst comprising a washcoat comprising one or more layers, the washcoat being disposed on a substrate, wherein the washcoat comprises a platinum group metal supported on a metal oxide support material, and one or more of an oxidic compound of V, an oxidic compound of W and a zeolitic material comprising one or more of Cu and Fe.