Patent classifications
B01D2255/20723
NOx reduction catalyst for exhaust gas and method for producing same
To provide a catalyst having excellent performance and durability by improving a NOx reduction ratio at 350 C. or higher without deteriorating excellent durability of a TiVMoP catalyst in view of problems of conventional art. A NOx reduction catalyst for exhaust gas, which is composed of a catalyst composition that comprises titanium (Ti), an oxide of phosphorous, molybdenum (Mo) and/or tungsten (W), oxide of vanadium (V), and high-silica zeolite that has an SiO.sub.2/Al.sub.2O.sub.3 ratio of not less than 20 is obtained by kneading in the presence of water, drying and calcining (1) titanium oxide, and phosphoric acid or an ammonium salt of phosphoric acid in an amount of more than 1% by weight and not more than 15% by weight relative to the titanium oxide in terms of H.sub.3PO.sub.4, (2) an oxo acid or oxo acid salt of molybdenum (Mo) and/or tungsten (W) and an oxo acid salt of vanadium (V) or vanadyl salt respectively in an amount of more than 0% by atom and not more than 8% by atom relative to the titanium oxide and (3) high-silica zeolite in an amount of more than 0% by weight and not more than 20% by weight relative to the titanium oxide.
OXYGEN STORAGE MATERIALS
The present invention is concerned with oxygen storage materials. In particular an oxygen storage material (OSM) is proposed which comprises a certain mixed oxide as the oxygen storage component. The oxygen storage material can be used in conventional manner in three-way catalysts or NOx-storage catalysts for example.
CATALYTIC CONVERTER
In order to specify a catalytic converter, especially SCR catalytic converter, with maximum catalytic activity, this catalytic converter has at least one catalytically active component and additionally at least one porous inorganic filler component having meso- or macroporosity. The organic porous filler component has a proportion of about 5 to 50% by weight. More particularly, a diatomaceous earth or a pillared clay material is used as the porous inorganic filler component.
CATALYTIC PARTIAL WALL-FLOW FILTER
A catalytic partial wall-flow filter suitable for use in an exhaust gas treatment system, a method of making the catalytic partial wall-flow filter, and a method of using the catalytic partial wall-flow filter to remediate engine exhaust streams are disclosed. The filter comprises a partial wall-flow filter substrate having an inlet end, an outlet end, and a plurality of porous walls forming channels from the inlet end to the outlet end, wherein some of the channels are plugged channels and some are unplugged flow-through channels. A selective catalytic reduction (SCR) catalyst is coated on the porous walls.
Catalytic system comprising antimony-containing catalyst
A catalyst system for purifying an exhaust gas, comprising one or more antimony-containing regions comprising an antimony-containing catalyst, particularly antimony-containing SCR catalyst, and one or more antimony-trapping regions comprising a molecular sieve which is optionally metal-promoted, wherein at least one of the antimony-trapping regions is located downstream of the one or more antimony-containing regions in a flow direction of the exhaust gas, and also a method for treatment of an exhaust gas containing nitrogen oxides.
Device system and method having sintering flue gas CO catalytic heat exchange and medium-and-low-temperature SCR denitration connected in series
Disclosed in the present invention are a device system and method having sintering flue gas CO catalytic heat exchange and medium-and-low-temperature SCR denitration connected in series. In the device system, a CO catalytic heat storage and exchange device is arranged to completely replace an original heat exchanger arranged after a raw desulfurized flue gas pipe. The method comprises respectively carrying out first CO catalytic conversion and second CO catalytic conversion on sintering flue gas and denitrated flue gas by means of the CO catalytic heat storage and exchange device, thereby increasing CO conversion efficiency and reducing overall resistance of the system. In addition, the present invention takes both CO pollution control and carbon emission reduction into consideration and thus has good economic benefits and a good application prospect.
DENITRATION CATALYST STRUCTURE
A denitration catalyst structure includes: a rectangular frame body having a gas inlet and a gas outlet; a plurality of plate-like catalytic elements each of which has a gas inlet-side edge, a gas outlet-side edge, and two side edges and contains a catalytic component; and a plate-like draft stopper having a gas inlet-side edge, a gas outlet-side edge, and two side edges. The plurality of plate-like catalytic elements are stacked and housed in the frame body with the side edges aligned, with a space between the stacked plate-like catalytic elements and between an inner surface of the frame body and the side edges of each plate-like catalytic element to allow a gas to pass from the gas inlet to the gas outlet through the space. The plate-like draft stopper is arranged between the inner surface of the frame body and the side edges of each plate-like catalytic element.
METHOD FOR MANUFACTURING HIGH-EFFICIENCY DENITRATION CATALYSTS, METHOD FOR MODIFYING THE SURFACE OF PTFE FIBERS BY MIXING SOLID PARTICLES, AND METHOD FOR MANUFACTURING PTFE CATALYST FILTER
Disclosed are a method of manufacturing a high-efficiency denitrification catalyst by adjusting components constituting a denitrification catalyst and a ratio between respective components, a method of modifying the surface of PTFE fibers by extruding, rolling, stretching and slitting a PTFE billet manufactured using mixed solid particles, and a method of producing a PTFE catalyst filter by the methods.
Two-dimensional catalytic materials derived from metal-organic frameworks for VOC remediation
Porous metal oxide catalytic materials with planar morphologies which are derived from metal-organic framework (MOF) materials via thermal decomposition, oxidation pretreatment and pyrolysis processes. The porous metal oxides are mainly transition metal oxides, derived from MOFs containing the corresponding transition metal ions, such as Cu, Zn, Y, La, Ce, Ti, Zr, V, Cr, Mn, Fe, Co, and Ni ions. The transformation conditions from MOF materials to metal oxides, such as temperature, atmosphere and duration, are well defined to obtain metal oxides with controlled morphologies. Furthermore, the present subject matter relates to a low-temperature catalytic decomposition of volatile organic compounds (VOCs) with a wide concentration range on two-dimensional metal oxides.
SCR catalyst compositions and SCR catalytic articles comprising said catalyst compositions
The present invention disclose catalyst compositions for the selective catalytic reduction of nitrogen oxides, consisting of at least one oxide of vanadium in an amount of 2.0 to 4.0 wt.-%, calculated as V.sub.2O.sub.5 and based on the total weight of the catalyst composition, at least one oxide of tungsten in an amount of 2.5 to 7.2 wt.-%, calculated as WO.sub.3 and based on the total weight of the catalyst composition, at least one oxide of antimony in an amount of 0.6 to 3.4 wt.-%, calculated as Sb.sub.2O.sub.5 and based on the total weight of the catalyst composition, at least one oxide of zirconium in an amount of 0 to 1.0 wt.-%, calculated as ZrO.sub.2 and based on the total weight of the catalyst, and at least one oxide of titanium in an amount of 84.6 to 94.9 wt.-% calculated as TiO.sub.2 and based on the total weight of the catalyst, wherein the weight ratio of the oxides of vanadium, tungsten, antimony, titanium and optionally zirconium, calculated as V.sub.2O.sub.5, WO.sub.3, Sb.sub.2O.sub.5, TiO.sub.2 and optionally ZrC.sub.2, respectively, add up to 100 wt.-%. Furthermore, SCR catalytic articles are disclosed wherein an SCR catalyst composition according to the invention is affixed in the form of a coating. Suitable catalyst carriers are corrugated substrates and cordierite monoliths. The SCR catalytic articles can be used in a method for the reduction of nitrogen oxides in exhaust gases of lean-burn internal combustion engines, and they can furthermore be comprised in an exhaust gas purification system for the treatment of diesel exhaust gas.