Patent classifications
B01D2255/20761
Tail gas treatment catalyst, preparation method therefor and use thereof
Disclosed in the present invention is a tail gas treatment catalyst. The catalyst consists of a carrier, a first catalyst, and a second catalyst. The first catalyst and the second catalyst are provided on both ends of the carrier. The first catalyst can purify pollutants in tail gas. The second catalyst can purify a byproduct, ammonia, obtained by the purification by the first catalyst and pollutants that are not completely purified by the first catalyst. The second catalyst is of a double-layer structure; the lower layer consists of an oxygen storage material, aluminum oxide, and a second active component; the second active component is a composition of Pt and Pd, or a composition of Ce, Fe, Ni and Cu; the upper layer consists of a molecular sieve and a third active component; the third active component is Cu or a composition of Cu and Fe. The tail gas treatment catalyst of the present invention has high purification treatment efficiency, and can significantly reduce the emissions of CH.sub.4, CO, and NO.sub.x in the tail gas, especially reduce the content of the byproduct, NH.sub.3, so that the tail gas can meet China VI emission standards.
Iron-loaded small pore aluminosilicate zeolites and method of making metal loaded small pore aluminosilicate zeolites
The present invention provides an iron-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms and having the framework type CHA, AEI, AFX, ERI or LTA, wherein the iron (Fe) is present in a range of from about 0.5 to about 5.0 wt. % based on the total weight of the iron-loaded aluminosilicate zeolite, wherein an ultraviolet-visible absorbance spectrum of the iron-loaded synthetic aluminosilicate zeolite comprises a band at approximately 280 nm, wherein a ratio of an integral, peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for the band at approximately 280 nm to an integral peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for a band at approximately 340 nm is >about 2. The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.
Zeolite with reduced extra-framework aluminum
The present disclosure generally provides a catalyst composition comprising a zeolite containing iron and/or copper with a reduced amount of extra-framework aluminum. The catalyst composition is useful to catalyze the reduction of nitrogen oxides in exhaust gas in the presence of a reductant.
EXHAUST TREATMENT SYSTEM FOR AMMONIA-FUELED VEHICLES
The present disclosure is directed to an emission treatment system for NO.sub.x abatement in an exhaust stream of an ammonia-fueled engine, the emission treatment system including a selective catalytic reduction (SCR) catalyst disposed on a substrate in fluid communication with the exhaust stream, an oxidation catalyst disposed on a substrate positioned either upstream or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, and optionally, one or more adsorption components disposed on a substrate positioned upstream and/or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, the adsorption component chosen from low temperature NO.sub.x adsorbers (LT-NA), low temperature ammonia adsorbers (LT-AA), low temperature water vapor adsorbers (LT-WA), and combinations thereof. The disclosure further provides a related method of treatment of an exhaust gas.
WIRELESS RECHARGEABLE AND PORTABLE ANTI-MICROBIAL RESPIRATOR
The present invention provides a wireless rechargeable and portable anti-microbial respirator. The respirator includes a face-piece with an air inlet and an air outlet; a first belt and a second belt, the first belt is connected to ends of the face-piece, and the second belt is configured to wrap around the waist of a user; a flexible outlet tube, where the first end of the flexible outlet tube is connected to the air outlet of the face-piece; a flexible intake tube, where the first end of the flexible intake tube is connected to the air inlet of the face-piece; and a filtration system fixed onto the second belt. The key features of the respirator in the present invention include highly antibacterial and antiviral, long duration, reusable, self-cleaning and self-disinfecting, lightweight and portable, wireless power transfer, and great airflow and comfortable breathing.
Exhaust gas sample collector and mixer for aftertreatment system
An exhaust gas treatment system includes an exhaust gas pathway configured to receive exhaust gas from an internal combustion engine. The exhaust gas treatment system further includes a treatment element configured to reduce an emissions component of the exhaust gas, and a sample collector positioned within the exhaust gas pathway downstream of the treatment element. The sample collector includes a plurality of inlet openings spaced about a periphery of the exhaust gas pathway and configured to receive a sample of exhaust gas from the exhaust gas pathway, and an outlet in fluid communication with the plurality of inlet openings. A sensor located at the outlet of the sample collector is configured to measure a characteristic of the sample.
Activated carbon and catalyst filter
Embodiments of the invention include a filtration element. In an embodiment, the invention includes a filtration element for an airplane cabin that includes a first media portion upstream from a second media portion. The first media portion can include activated carbon. The second media portion can include a catalyst material. Other embodiments are also included herein.
Process for preparing a catalyst or a trapping mass from molten salts
Process for preparing a catalyst or a trapping mass comprising the following steps: bringing a porous oxide support into contact with a metal salt comprising at least one metal belonging to groups VIB, VIIB, VIIIB, IB or IIB, of which the melting point of said metal salt is between 20° C. and 150° C., for a period of between 5 minutes and 5 hours in order to form a solid mixture, the weight ratio of said metal salt to said porous oxide support being between 0.1 and 1; heating the solid mixture with stirring at a temperature between the melting point of said metal salt and 200° C. and for 5 minutes to 12 hours; calcining the solid obtained in the preceding step at a temperature above 200° C. and below or equal to 1100° C. under an inert atmosphere or under an oxygen-containing atmosphere.
In-situ copper ion-exchange on pre-exchanged copper zeolitic material
A process for preparing a catalyst comprising a zeolitic material comprising copper, the process comprising (i) preparing an aqueous mixture comprising water, a zeolitic material comprising copper, a source of copper other than the zeolitic material comprising copper, and a non-zeolitic oxidic material selected from the group consisting of alumina, silica, titania, zirconia, ceria, a mixed oxide comprising one or more of Al, Si, Ti, Zr, and Ce and a mixture of two or more thereof; (ii) disposing the mixture obtained in (i) on the surface of the internal walls of a substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the substrate extending therethrough; and optionally drying the substrate comprising the mixture disposed thereon; (iii) calcining the substrate obtained in (ii).
NOVEL ZONED CATALYSTS FOR CNG ENGINE EXHAUST GAS TREATMENTS WITH IMPROVED AMMONIA EMISSION CONTROL
A three-way catalyst article, and its use in an exhaust system for compressed natural gas engines, is disclosed. The catalyst article for treating exhaust gas from compressed natural gas (CNG) engine comprising: a substrate comprising an inlet end, an outlet end with an axial length L; a first catalytic region beginning at the outlet end and extending for less than the axial length L, wherein the first catalytic region comprises a first zeolite; and a second catalytic region beginning at the inlet end, wherein the second catalytic region comprises a second platinum group metal (PGM) component, a second oxygen storage capacity (OSC) material, and a second inorganic oxide; wherein the second PGM component is selected from the group consisting of palladium, platinum, rhodium or a combination thereof.