The present disclosure provides the exhaust gas purification catalyst with the improved purification performance under the high Ga condition and the transient state in which an A/F repeats rich and lean phases. The present disclosure relates to an exhaust gas purification catalyst comprising a catalyst coating layer on a substrate, the catalyst coating layer containing a noble metal, a composite oxide containing cerium oxide and zirconium oxide, and a composite oxide containing aluminum oxide, wherein in the catalyst coating layer: an average thickness of the coating layer is in a range from 20 μm to 100 μm; a porosity measured by a weight-in-water method is in a range from 50% by volume to 80% by volume; and high-aspect-ratio pores having an aspect ratio of 5 or more account for 0.5% by volume to 50% by volume of a whole volume of voids, the high-aspect-ratio pore having an equivalent circle diameter in a range from 2 μm to 50 μm in a cross-sectional image of a catalyst coating layer cross section perpendicular to an exhaust gas flow direction of the substrate and having an average aspect ratio in a range from 10 to 50, and wherein the noble metal is supported on peripheries of the voids, the composite oxide containing the cerium oxide and the zirconium oxide, and the composite oxide containing the aluminum oxide.

The present disclosure generally relates to emission control catalyst articles comprising a platinum group metal (PGM) enriched zone, methods of making such emission control catalyst articles, and methods of using such emission control catalyst articles.

The present invention relates to an exhaust gas treatment system for treating exhaust gas from a lean burn combustion engine, wherein said exhaust gas comprises hydrocarbons and NOx, the exhaust gas treatment system comprising: (i) a means for injecting hydrocarbons into an exhaust gas stream; (ii) a diesel oxidation catalyst (DOC) comprising a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises one or more platinum group metals, wherein the one or more platinum group metals comprise platinum; (iii) a means for injecting a nitrogenous reducing agent into an exhaust gas stream; and (iv) a multifunctional catalyst (MFC) comprising an oxidation catalyst, and a selective catalytic reduction (SCR) catalyst for the selective catalytic reduction of NOx, wherein the MFC comprises a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises the oxidation catalyst and the SCR catalyst, wherein the oxidation catalyst comprises one or more platinum group metals, wherein the one or more platinum group metals comprise palladium and/or platinum, and wherein the SCR catalyst comprises a zeolitic material loaded with copper and/or iron; wherein the means for injecting hydrocarbons, the DOC, the means for injecting a nitrogenous reducing agent, and the MFC are located in sequential order in a conduit for exhaust gas, wherein the means for injecting hydrocarbons into an exhaust gas stream is located upstream of the DOC, wherein the DOC is located upstream of the MFC, and wherein the means for injecting a nitrogenous reducing agent into the exhaust gas stream is located between the DOC and the MFC. Furthermore, the present invention relates to a method for the treatment of exhaust gas using the exhaust gas treatment system according to the present invention, and to a method for the preparation of an exhaust gas treatment system according to the present invention.

Provided are catalyst particles for treating vehicle exhaust gas, containing semiconductor nanoparticles supported by noble metals.

The present invention relates to a selective catalytic reduction catalyst for the treatment of an exhaust gas of a diesel engine comprising: a flow-through substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the flow through substrate extending therethrough; a coating disposed on the surface of the internal walls of the substrate, wherein the coating comprises a non-zeolitic oxidic material comprising manganese and one or more of the metals of the groups 4 to 11 and 13 of the periodic table, and further comprises one or more of a vanadium oxide and a zeolitic material comprising one or more of copper and iron.

The structured catalyst for oxidation for exhaust gas purification includes a support having a porous structure constituted by a zeolite-type compound, and at least one type of oxidation catalyst that is present in the support and selected from the group consisting of metal and metal oxide, the support having channels that communicate with each other, and the oxidation catalyst being present in at least the channels of the support.

The present invention relates to a catalyst comprising a carrier substrate of length L and at least two washcoat layers A and B wherein washcoat layer A comprises alumina; ceria; an alkaline earth compound and/or an alkali compound; platinum, palladium or platinum and palladium; washcoat layer B comprises a zeolite and palladium, wherein the palladium is present as palladium cation in the zeolite structure or is wholly or partially present as palladium metal and/or as palladium oxide in the zeolite structure and/or on the surface of the zeolite structure; and
wherein washcoat layer A is arranged below washcoat layer B.

Proposed is a pretreatment desulfurization method for marine fuel oil. The method includes a step of preparing a pretreatment desulfurization agent including (a) at least one oxide selected from the group consisting of SiO2, Al2O3, Fe2O3, TiO2, MgO, MnO, CaO, Na2O, K2O, and P2O3, (b) at least one metal selected from the group consisting of Li, Cr, Co, Ni, Cu, Zn, Ga, Sr, Cd, and Pb, and (c) at least one liquid composition selected from the group consisting of sodium tetraborate (Na2B4O7.10H2O), sodium hydroxide (NaOH), sodium silicate (Na2SiO3). and hydrogen peroxide (H2O2). The method also includes a step of feeding the pretreatment desulfurization agent to a fuel supply line through which marine fuel oil is supplied to a marine engine at a certain ratio so that a fluid mixture containing the marine fuel oil and the pretreatment desulfurization agent is supplied to the marine engine, thereby adsorbing and removing sulfur oxides during combustion of the fluid mixture.

Disclosed is a methane oxidation catalyst, and methods of use, the catalyst having a support comprising alumina doped with lanthanum and comprising platinum and palladium as the principle active phases. The platinum and palladium are present in the catalyst in a weight ratio of between 0.20:1.0 and 0.75:1.0, at an amount effective 5 for producing a product gas having reduced levels of methane as compared to a source gas prior to catalysis. Selected catalysts disclosed herein exhibit a capacity for sulfur and water resistance.

A process for the production of a catalyst comprising the steps of: dissolving the requisite quantities of copper nitrate and nickel nitrate in de-ionised water to provide a sub-0.30 molar aqueous solution of copper nitrate and nickel nitrate together in the ratio required; providing an ammoniacal solution by adding concentrated aqueous solution of ammonia in a quantity equal to between six and ten times the quantity required to realise both a 1:6 molar ratio for Cu.sup.2+ to ammonia and a 1:6 molar ratio for Ni.sup.2+ to ammonia; loading gamma alumina with 1 to 30% w/w of copper and nickel in a weight ratio of nickel to copper of 1:5 to 2:1 by suspending the requisite quantity of gamma alumina in said ammoniacal solution to achieve the required loading of copper and nickel; stirring the resulting gamma alumina suspension for at least 4 h at room temperature; then the volatile components evaporate under ambient conditions leaving dry loaded gamma alumina, which is calcined at a temperature of at least 260° C. for at least 30 min with a constant heating up rate; a catalyst or catalyst mixture, the catalyst or each catalyst in the catalyst mixture being obtainable by the above-mentioned process; and the use of the catalyst or catalyst mixture for the conversion of exhaust gases from an internal combustion engine into carbon dioxide, water and nitrogen.