A nitrous oxide (N.sub.2O) removal catalyst composite is provided, comprising a N.sub.2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H.sub.2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H.sub.2-TPR). Methods of making and using the same are also provided.

The present invention relates to a catalytic material for treating an exhaust gas produced by a natural gas engine, which catalytic material comprises a molecular sieve and a platinum group metal (PGM) supported on the molecular sieve, wherein the molecular sieve has a framework comprising silicon, oxygen, titanium and optionally germanium, and has a content of non-titanium heteroatom T-atoms of ≤ about 0.20 mol %, wherein the titanium is present in an amount of from 1 to 3 mol %. The present invention further relates to a catalyst article and to a compressed natural gas combustion and exhaust system.

Provided is an adsorbent for capturing carbon dioxide and a method for manufacturing same, and more particularly, to an adsorbent for capturing carbon dioxide, including a magnesium oxide/titanium dioxide composite having wide surface area, large pore volume and good CO.sub.2 adsorption performance, and a method for manufacturing same. According to the present invention, a novel MgO based composite metal oxide which may stably adsorb CO.sub.2 at a low temperature such as room temperature is provided. The adsorbent for capturing carbon dioxide, including a magnesium oxide/titanium dioxide composite has good thermal stability, and controls basic sites easily, and is used in various fields for capturing carbon dioxide. In addition, by controlling the molar ratio of the metal ions of the magnesium oxide/titanium dioxide composite and controlling morphology, an adsorbent for capturing carbon dioxide having large surface area and pore volume and strong basic sites may be provided.

The exhaust gas purification device includes a substrate, a first catalyst layer, and a second catalyst layer. The substrate includes an upstream end, a downstream end, and a porous partition wall defining a plurality of cells extending between the upstream end and the downstream end. The plurality of cells include an inlet cell opening at the upstream end and sealed at the downstream end, and an outlet cell adjacent to the inlet cell sealed at the upstream end and opening at the downstream end. The first catalyst layer is disposed on a surface of the partition wall in an upstream region. In a downstream region, the second catalyst layer is disposed inside the partition wall, and a second catalyst-containing wall including the partition wall and the second catalyst layer has a porosity of 35% or more.

Zeolites having highly dispersed bimetallic clusters, uniformly distributed in size and composition, encapsulated therein are disclosed. Metal encapsulation and alloying is conferred by introducing ligated metal cation precursors into zeolite synthesis gels, which are subsequently crystallized hydrothermally to form zeolites with metal cations occluded in the pores. The ligated cations are anchored to the zeolite framework via siloxane bridges which enforces their uniform dispersion throughout the zeolite crystals. Treatment of the crystallized zeolites in O.sub.2 and then H.sub.2 forms bimetallic clusters, which remain narrowly distributed in size and composition.

A honeycomb filter includes a pillar-shaped honeycomb structure having porous partition walls provided, surrounding a plurality of cells which serve as fluid through channels extending from an inflow end face to an outflow end face, and a porous plugging portion provided either at an end on the inflow end face or the outflow end face of the cells, wherein the plugging portion is composed of a porous material, the honeycomb structure has a central region and a circumferential region, and a ratio of an area of the circumferential region with respect to that of the central region ranges from 0.1 to 0.5, porosity of a central plugging portion in the central region is lower than that of a circumferential plugging portion in the circumferential region, and the porosity of the central plugging portions ranges from 60% to 68%, and that of the circumferential plugging portions ranges from 70% to 85%.

An exhaust system for an internal combustion engine, the exhaust system comprising, a lean NO.sub.x trap, and a wall flow monolithic substrate having a pre-coated porosity of 40% or greater, and comprising an oxidation catalytic zone, the oxidation catalytic zone comprising a platinum group metal loaded on a first support, the first support comprising at least one inorganic oxide and a zinc compound.

The present invention relates to cerium oxide particles that have excellent heat resistance under hydrothermal conditions at high temperature. The present invention also relates to a method for preparing such cerium oxide particles and to a catalytic composition comprising said cerium oxide.

An exhaust gas purification filter comprises a base material part, a catalyst layer, and sealing parts. The base material part comprises porous partition walls. The catalyst layer is supported on pore walls of the partition walls. The partition walls supporting the catalyst layer comprise 10% or less of pores having a pore diameter of 50 μm or more. In the pore diameter distribution in the partition walls supporting the catalyst layer, the pore diameter D50 at which the cumulative pore volume becomes 50% is 10 μm or more. The pore diameter D50, and the pore diameter D10 at which the cumulative pore volume becomes 10%, satisfy the relationship of the following Expression 1.

(D50−D10)/D50≤0.9  Expression 1

A catalyst fibrous structure having a catalyst metal carried on a fibrous structure, wherein (a) a Log differential micropore volume distribution curve thereof obtained by measurement using a mercury intrusion technique has a peak having a maximum micropore diameter in the range of from 0.1 μm to 100 μm; (b) a Log differential micropore volume at the peak is 0.5 mL/g or more; and (c) an amount of a catalyst metal compound and a binder carried per unit volume is 0.05 g/mL or more. A production method for producing a catalyst fibrous structure having: (1) mixing a catalyst metal compound or a catalyst precursor, and an inorganic binder and a solvent; (2) grinding the mixture to obtain a coating material of the catalyst metal compound or the catalyst precursor having a median particle diameter of 2 μm or less and a viscosity of from 10 mPa.Math.s to 200 mPa.Math.s; (3) impregnating a fibrous structure with the coating material to fill up voids of the fibrous structure with the coating material of the catalyst metal compound or the catalyst precursor; (4) heating and drying the fibrous structure, directly as it is, at a temperature not lower than the boiling point of the solvent; and (5) heating and calcination the dried fibrous structure at a temperature not lower than the dehydration temperature of the inorganic binder to obtain a catalyst fibrous structure.