Sorbent compositions, comprising a solid sorbent, a dispersive agent, and optionally a capture agent for enhanced wet-Flue Gas Desulfurization (wFGD) or wet scrubber unit function in a flue gas pollutant control stream is disclosed. The sorbent composition may include a sorbent with a dispersive agent, designed to enhance the dispersion of the sorbent in an aqueous sorption liquid of a wet scrubber unit, and therefore may be especially useful in EGU or industrial boiler flue gas streams that include one or more wet scrubber units. The sorbent composition may also include a capture agent useful in sequestering mercury and bromine, as well as other contaminants that may include arsenic, selenium and nitrates.

A sorbent in the form of a layered, non-porous perovskite is provided, wherein the sorbent can include parallel, alternating layers of an organic layer, including an ordered array of organic moieties capable of reacting with a gaseous halogen, and an inorganic layer, including a metal-halide sheet. Furthermore, each organic layer can be sandwiched between inorganic layers. Methods for capturing one or more halogens from a gas stream are also provided, wherein the methods can include contacting a gas stream with a sorbent in the form of a layered, non-porous perovskite, wherein the sorbent can include parallel, alternating layers of an organic layer, including an ordered array of organic moieties capable of reacting with a gaseous halogen, and an inorganic layer, including a metal-halide sheet. One or more halogens in the gas stream can react with either alkyne groups or alkene groups found in the organic layer of the sorbent.

The invention relates to a process for removal of bromine, bromine- and/or iodine-containing silicon compounds from compositions of chlorosilanes containing bromine, bromine- and/or iodine-containing silicon compounds, wherein the composition is subjected to a nonthermal plasma and subsequently the chlorosilanes may be separated from the bromine- and/or iodine-containing compounds present by distillation.

The present application provides a method of treating flue gas in a duct with an injection system, the flue gas comprising an acid gas and/or one or more metal components, the injection system comprising at least one injection nozzle in communication with an air supply and a supply of sorbent; wherein the method comprises supplying air and sorbent through the nozzle to the duct such that the penetration of the sorbent into the duct is represented by the formula: Y=(D.sub.na(p.sub.nV.sub.n.sup.2/p.sub.fV.sub.f.sup.2).sup.0.5(x/D.sub.n).sup.0.33)/D.sub.f where Y is the fraction of duct penetration depth of the sorbent when the duct length is x, D.sub.n is the diameter of the nozzle, D.sub.f is the depth of the duct, p.sub.n and p.sub.f are the densities of the air supply and flue gas, respectively V.sub.n and V.sub.f are the velocities of the air exiting the nozzle and the flue gas, respectively, and where a is between 0.3 and 1.0 and where Y is between 0.3 and 0.8.

The invention relates to a method for treating emergency spill or leak of halogen which is bromine or chlorine, comprising contacting an aqueous solution of quaternary ammonium halide with the halogen.

Sorbent compositions, comprising a solid sorbent, a dispersive agent, and optionally a capture agent for enhanced wet-Flue Gas Desulfurization (wFGD) or wet scrubber unit function in a flue gas pollutant control stream is disclosed. The sorbent composition may include a sorbent with a dispersive agent, designed to enhance the dispersion of the sorbent in an aqueous sorption liquid of a wet scrubber unit, and therefore may be especially useful in EGU or industrial boiler flue gas streams that include one or more wet scrubber units. The sorbent composition may also include a capture agent useful in sequestering mercury and bromine, as well as other contaminants that may include arsenic, selenium and nitrates.

There is provided a halon purification method capable of simply, safely, and efficiently removing mixed bromine molecules to obtain high purity halon. The halon purification method is a method for removing bromine molecules from crude halon containing halon and the bromine molecules, and the method includes: a contact step of bringing the crude halon into contact with an absorbing liquid containing an aqueous solution containing metal iodide to obtain a mixed liquid containing the crude halon and the absorbing liquid; and a separation step of separating the halon from the mixed liquid to obtain the halon and the absorbing liquid having absorbed the bromine molecules.

A process for recovering by-products of a substituted aromatic hydrocarbon oxidation reaction, comprising cooling one or more of a vapor stream directed to a high-pressure absorber (380), a solvent-rich scrubbing stream (381) directed to a high-pressure absorber (380), and a water-rich liquid stream (383) directed to a solvent recovery zone, by heat exchange with a cooled spent scrubbing liquid withdrawn from a low-pressure scrubber (430).