Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membranes can comprise a gas permeable support layer, an inorganic layer disposed on the support, the inorganic layer comprising a plurality of discreet nanoparticles having an average particle size of less than 1 micron, and a selective polymer layer disposed on the inorganic layer, the selective polymer layer comprising a selective polymer having a CO.sub.2:N.sub.2 selectivity of at least 10 at 57° C. In some embodiments, the membrane can be selectively permeable to an acidic gas. The membranes can be used, for example, to separate gaseous mixtures, such as flue gas.

Systems and Methods to produce a lime hydrate sorbent composition formed of highly reactive lime hydrate (HRH) by adding compounds to the slaking water in a method that would produce a non-HRH, which will typically be a lime hydrate having citric acid reactivity as discussed above of more than ten seconds, to make the non-HRH an HRH, which is having a citric acid reactivity of less than or equal to ten seconds.

Disclosed is the use of a composite for extracting one or more metal or contaminating chemical species from an aerial or aqueous medium by selective binding, the composite including at least one porous template functionalized by at least one polymer, the polymer including one of the following chemical functions: primary, secondary or tertiary amine, amide, nitrile, pyridine, pyrole, thiol, thiolether, thiophene, thiadiazole, alcohol/hydroxyl, phenol, catechol, pyragalol, carboxylic acid, aldehyde, ester, acyl, crown ether, phosphate, phosphoryl, epoxide, halogen, haloalkane.

Calcium hydroxide-containing compositions can be manufactured by slaking quicklime, and subsequently drying and milling the slaked product. The resulting calcium hydroxide-containing composition can have a size, steepness, pore volume, and/or other features that render the compositions suitable for treatment of exhaust gases and/or removal of contaminants. In some embodiments, the calcium hydroxide-containing compositions can include a D.sub.10 from about 0.5 microns to about 4 microns, a D.sub.90 less than about 30 microns, and a ratio of D.sub.90 to D.sub.10 less than 20, wherein individual particles include a surface area greater than or equal to about 25 m.sup.2/g.

An exhaust gas processing system including a process chamber in which an exhaust gas is produced; an exhaust gas measurer receiving the exhaust gas and measuring a concentration of the exhaust gas; a solid producing gas processor receiving the exhaust gas and removing a solid producing gas contained in the exhaust gas; a gas supply supplying dilution and cooling gases to the solid producing gas processor; a processed gas measurer receiving, as a processed gas, the exhaust gas free of the solid producing gas and measuring a temperature of the processed gas and ingredients of the processed gas; and a controller receiving results of measurement of the concentration of the exhaust gas from the exhaust gas measurer and results of measurement of the temperature of the processed gas and the ingredients of the processed gas from the exhaust gas measurer and controlling the gas supply based on the measurement results.

A gas treatment method includes an absorption step in which a gas to be treated containing an acidic compound, such as carbon dioxide, is brought into contact, in an absorber, with a treatment liquid that absorbs the acidic compound; and a regeneration step in which the treatment liquid, having the acidic compound absorbed therein, is sent to a regenerator, and the treatment liquid is then heated to separate the acidic compound from the treatment liquid. In the regeneration step, a gas almost insoluble to the treatment liquid, such as hydrogen gas, is brought into contact with the treatment liquid.

An apparatus is disclosed including a desulfurization device which removes sulfur oxides contained in boiler flue gas, a spray drying device which sprays desulfurization waste water discharged from the desulfurization device and which dries the waste water by introducing a drying gas, a flue gas supplying line L.sub.13 which returns, to a main flue L.sub.11, flue gas obtained after the desulfurization waste water is evaporated and dried, an alkaline agent supplying unit which adds an alkaline agent to a desulfurization waste water line L.sub.21, and a pH meter which measures the pH in the desulfurization waste water at locations before and after the alkaline agent supplying unit in the desulfurization waste water line L.sub.21, wherein the alkaline agent is added in accordance with a measurement result of a measured pH to cause the desulfurization waste water added with the alkaline agent to have a pH fall within a predetermined pH.

Methods and systems for producing aromatics and light olefins from a mixed plastics stream are described. The method may include feeding a plastic feedstock to a dechlorination operation to melt the plastic feedstock to release HCl and generate a liquid plastic stream; feeding the liquid plastic stream to a pyrolysis reactor, the pyrolysis reactor to generate hydrocarbon vapors; feeding the hydrocarbon vapors to an acid gas removal reactor with a solid inorganic alkali salt disposed within the reaction vessel to remove residual HCl and sulfur-containing compounds from the hydrocarbon vapors to generate a plastic derived oil; and feeding the plastic derived oil to a steam enhanced catalytic cracking reactor to generate a product stream comprising light olefins having a carbon number of C.sub.2-C.sub.4 and aromatics. The associated system for processing mixed plastics into aromatics and light olefins is also described.

A regenerator vessel for adsorbing halogen-containing material from a regenerator vent gas stream has a plurality of catalyst nozzles disposed at a top portion of the regenerator vessel. A first gas outlet is associated with a chlorination zone, and a second gas outlet associated with a combustion zone. A drying zone is in fluid communication with an air heater and the drying zone located in a bottom portion of the regenerator vessel. The first gas outlet is configured to withdraw a first gas stream from the chlorination zone and the second gas outlet is configured to withdraw a second gas stream from the combustion zone. The top portion of the regenerator vessel has an adsorption zone having a vent gas inlet port, a vent gas outlet port, and a portion of an annular catalyst bed.

The present invention provides a new hydrogen chloride removing agent that exhibits a good hydrogen chloride removal effect at a relatively low temperature. The present invention preferably provides a new hydrogen chloride removing agent for removing hydrogen chloride contained in a hydrogen-chloride-containing gas, such as a pyrolysis gas, a combustion exhaust gas, a dry distillation gas, etc., especially hydrogen chloride contained in a biomass pyrolysis gas. The present invention relates to a hydrogen chloride removing agent characterized by containing a mixture of a calcium carbonate and an imogolite and/or a synthetic imogolite, and relates to a method for removing, by using said hydrogen chloride removing agent, hydrogen chloride contained in a hydrogen-chloride-containing gas, especially hydrogen chloride contained in a biomass pyrolysis gas.