Methods and systems for capture of CO.sub.2 from a hydrated gaseous stream are described. Systems can be utilized for direct air capture of CO.sub.2 and incorporate a low energy temperature-vacuum swing adsorption (TVSA) process. A TVSA process can include a multi-step CO.sub.2 capture bed regeneration process that includes depressurization of the bed, heating of the bed, venting and purging of the bed, and cooling of the bed. Multiple beds can be cycled between CO.sub.2 capture and regeneration, during which captured CO.sub.2 is recovered. Off-gas from a CO.sub.2 capture bed can be used in regenerating a parallel bed for increased efficiency.

A method for controlling an adsorption phase of a gas generator, said generator comprising an adsorbent medium capable of selectively adsorbing a first gaseous component from an inlet gas flow comprising a gaseous mixture, and allowing an outlet gas flow mainly comprising a second gaseous component, said method comprising: directing the inlet gas flow through an inlet of said gas generator; measuring the outlet gas flow; determining the concentration of said second gaseous component at the outlet of said vessel; wherein the method further comprises: calculating the capacity of the generator; comparing the measured outlet gas flow with the calculated capacity; maintaining the generator in adsorption phase for a predetermined time interval, s; subjecting the generator to a regenerating cycle after said predetermined time interval.

Methods and systems for continuous pressure swing adsorption separation of a pressurized feed gas stream, the method including separating hydrocarbons heavier than methane from the pressurized feed gas stream to produce at least two product streams, a first product stream being substantially pure methane, and a second product stream being substantially comprised of components with a greater molecular weight than methane.

Method for operating an adsorber arrangement comprising a first and a second adsorber device, arranged in parallel between an upstream process device providing a process gas and a downstream process device receiving a purified process gas. The method comprising during a process of purifying the process gas with the first adsorber device, cooling the second adsorber device by passing a portion of purified process gas, received from the first adsorber device, through the second adsorber device; and directing the process gas portion that has passed through the second adsorber device to the upstream process device. Then, the first and the second adsorber devices are sequentially coupled, such that process gas from the upstream process device passes through the second adsorber device for cooling the second adsorber device, and then through the first adsorber device. Finally, purified process gas is received at the downstream process device from the first adsorber device.

An ammonia-producing system comprises a reactor that catalytically converts nitrogen and hydrogen feed gases to ammonia to form a reaction mixture of the ammonia, unreacted nitrogen gas, and unreacted hydrogen gas. A feed system feeds the nitrogen and hydrogen gases to the reactor at a reaction pressure of from about 9 to about 100 atmospheres. A reactor control system controls the temperature during conversion of the nitrogen and hydrogen to ammonia by maintaining a reaction temperature of from about 330 C. to about 550 C. An absorbent selectively absorbs at least a portion of the ammonia from the reaction mixture, and an absorbent control system controls one or both of a temperature and pressure at the absorbent during selective absorption of the ammonia from the reaction mixture. A recycle line downstream of the absorbent recycles the unreacted nitrogen and unreacted hydrogen to the reactor.

Methods and systems for continuous pressure swing adsorption separation of a pressurized feed gas stream, the method including separating hydrocarbons heavier than methane from the pressurized feed gas stream to produce at least two product streams, a first product stream being substantially pure methane, and a second product stream being substantially comprised of components with a greater molecular weight than methane.

An oxygen separator for generating an oxygen-enriched gas from an oxygen comprising gas, said oxygen separator comprising: a) an oxygen separator device comprising i) a sorbent material for sorbing at least one component of the oxygen comprising gas; and ii) at least two controllable interfaces, comprising a first controllable interface and a second controllable interface, for controlling the communication of gas between the inside and the outside of the oxygen separator device, b) a processor for controlling the oxygen separator such that a plurality of phases are sequentially carried, amongst them a purging phase; wherein the processor is configured to control the at least two controllable interfaces such that a flow of gas is generated between the first controllable interface and the second controllable interface during at least the purging phase, wherein the second controllable interface is located and/or controlled such that it controls the fluidic coupling between the inside of the oxygen separator device and a volume of non-oxygen-enriched gas during the purging phase.

A three-product PSA system which produces three product streams from a feed gas mixture comprising a light key component, at least one heavy key component, and at least one intermediate key component is described. The three-product PSA system produces a high pressure product stream enriched in the light key component, a low pressure tail gas stream enriched in the at least one heavy key component, and an intermediate pressure vent gas stream enriched in the at least one intermediate key component.

A method for controlling an adsorption phase of a gas generator, said generator comprising an adsorbent medium capable of selectively adsorbing a first gaseous component from an inlet gas flow comprising a gaseous mixture, and allowing an outlet gas flow mainly comprising a second gaseous component, said method comprising: directing the inlet gas flow through an inlet of said gas generator; measuring the outlet gas flow; determining the concentration of said second gaseous component at the outlet of said vessel; wherein the method further comprises: calculating the capacity of the generator; comparing the measured outlet gas flow with the calculated capacity; maintaining the generator in adsorption phase for a predetermined time interval, s; subjecting the generator to a regenerating cycle after said predetermined time interval.

The present invention relates to a process cycle that allows for the stable production of mid-range purity oxygen from air, using traditional system designs. Typical cycles have a limited production benefit when generating O.sub.2 at lower than 90% purity, however they suffer a production loss at higher purity. The process cycles of the invention are capable of producing significantly more contained O.sub.2 at a lower purity. In addition to enhanced production capacity, lower power consumed per mass of product and more stable product purity and flow are realized by the process of the invention compared to traditional alternatives.