The present disclosure relates to a pressure swing adsorption apparatus for hydrogen purification from decomposed ammonia gas and a hydrogen purification method using the same, and more particularly, the pressure swing adsorption apparatus of the present disclosure includes a plurality of adsorption towers including a pretreatment unit and a hydrogen purification unit wherein the adsorption towers of the pretreatment unit and the hydrogen purification unit are packed with different adsorbents, thereby achieving high purity hydrogen purification from mixed hydrogen gas produced after ammonia decomposition, making it easy to replace the adsorbent for ammonia removal, minimizing the likelihood that the lifetime of the adsorbent in the hydrogen purification unit is drastically reduced by a very small amount of ammonia, and actively responding to a large change in ammonia concentration in the raw material.

Additionally, a hydrogen purification method using the pressure swing adsorption apparatus of the present disclosure physically adsorbs and removes impurities such as moisture (H.sub.2O), ammonia (NH.sub.3) and nitrogen (N.sub.2) included in mixed hydrogen gas produced after ammonia decomposition below extremely small amounts, thereby achieving high purity hydrogen purification with improved selective adsorption of moisture, ammonia and nitrogen and maximized hydrogen recovery rate and productivity. In addition, since the temperature swing adsorption process is not introduced, there is no need for a heat source for regeneration, thereby reducing the driving cost.

An improved DAC unit and process containing an adsorber structure comprising an array of adsorber elements with a support layer and on both sides thereof at least one sorbent layer and at least one protective layer comprising a microporous material disposed around the support layer and the sorbent layer, wherein the protective layer has greater hydrophobicity than the sorbent material, wherein the adsorber elements are parallel to each other and spaced apart forming parallel fluid passages for flow-through of ambient atmospheric air and/or desorbing media, the method comprising the following sequential and repeating steps: (a) adsorption by flow-through; (b) isolating said sorbent; (c) injecting a stream of desorbing media through said parallel fluid passages and inducing an increase of the temperature; (d) extracting desorbed carbon dioxide from the unit and separating it from desorbing media; (e) bringing the sorbent material to ambient temperature conditions.

A method for continuous pressure swing adsorption separation of a pressurized feed gas stream, including separating hydrocarbons heavier than methane from the pressurized feed gas stream by applying an adsorbent porous material to produce at least two product streams, a first product stream being substantially pure methane suitable for transport by natural gas pipeline, and a second product stream being substantially comprised of components with a greater molecular weight than methane.

Methods and systems for continuous pressure swing adsorption separation of a pressurized feed gas stream, the method including separating hydrocarbons heavier than methane from the pressurized feed gas stream to produce at least two product streams, a first product stream being substantially pure methane, and a second product stream being substantially comprised of components with a greater molecular weight than methane.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve performing the swing adsorption process in a swing adsorption process skid. The process may be utilized for swing adsorption processes, such as TSA and/or PSA, which are utilized to remove one or more contaminants from a gaseous feed stream.

A scrubbing solution for removing contaminants, including particularly hydrogen sulfide, from a fluid. The scrubbing solution includes at least one scrubbing reagent which has a primary or secondary amine and an acid, which may be phosphoric acid. The fluid being scrubbed is passed through the scrubbing solution. The contaminants react with the scrubbing reagent securing them in the scrubbing solution. The fluid being scrubbed and the scrubbing solution are then separated. The scrubbing solution is heated and, if the scrubbing solution is under pressure, the pressure is reduced. The acid facilitates thorough removal of the contaminants, and especially the hydrogen sulfide, from the scrubbing solution. The scrubbing solution is then ready for reuse. Because the scrubbing solution is rendered substantially free of hydrogen sulfides, it can absorb other sulfide contaminants that might not otherwise be absorbed.

Disclosed is a method for recovering a volatile organic compound (VOC) using pressure swing adsorption carried out with two beds that includes feeding the VOC to the first bed for adsorption and, while the VOC is being adsorbed by the adsorbent material in the first bed, simultaneously extracting the VOC adsorbed by the adsorbent material in the second bed through executing a desorption step by reducing the pressure of the second bed to cause desorption of the VOC in the adsorbent material of the second bed, executing a reflux step by transferring gas to the second bed and removing the transferred gas from the second bed, and executing a repressurization step by increasing pressure of the second bed to a pressure suitable for adsorption of the VOC by the adsorbent material in the second bed.

According to an exemplary embodiment of the present invention, a pressure swing adsorption process of a hydrogen production system is provided.

The hydrogen production system comprises a desulfurization process for removing sulfur components from raw natural gas; a reforming reaction process for producing a reformed gas containing hydrogen generated by the reaction of natural gas through the desulfurization process and steam; and a pressure swing adsorption process of concentrating the hydrogen using a pressure swing adsorption from the reformed gas.

In a desorption step of the pressure swing adsorption process, a cocurrent depressurization and a countercurrent depressurization are simultaneously performed.

An ammonia-producing system comprises a reactor that catalytically converts nitrogen and hydrogen feed gases to ammonia to form a reaction mixture of the ammonia, unreacted nitrogen gas, and unreacted hydrogen gas. A feed system feeds the nitrogen and hydrogen gases to the reactor at a reaction pressure of from about 9 to about 100 atmospheres. A reactor control system controls the temperature during conversion of the nitrogen and hydrogen to ammonia by maintaining a reaction temperature of from about 330 C. to about 550 C. An absorbent selectively absorbs at least a portion of the ammonia from the reaction mixture, and an absorbent control system controls one or both of a temperature and pressure at the absorbent during selective absorption of the ammonia from the reaction mixture. A recycle line downstream of the absorbent recycles the unreacted nitrogen and unreacted hydrogen to the reactor.

Methods and systems for continuous pressure swing adsorption separation of a pressurized feed gas stream, the method including separating hydrocarbons heavier than methane from the pressurized feed gas stream to produce at least two product streams, a first product stream being substantially pure methane, and a second product stream being substantially comprised of components with a greater molecular weight than methane.