B01D2259/40088

Adsorptive xenon recovery process from a gas or liquid stream at cryogenic temperature

The present invention relates to an adsorption process for xenon recovery from a cryogenic liquid or gas stream wherein a bed of adsorbent is contacted with a xenon-containing liquid or gas stream selectively adsorbing the xenon from said stream. The adsorption bed is operated to at least near full breakthrough with xenon to enable a deep rejection of other stream components, prior to regeneration using the temperature swing method. After the stripping step, the xenon adsorbent bed is drained to clear out the liquid residue left in the nonselective void space and the xenon molecules in those void spaces is recycled upstream to the ASU distillation column for increasing xenon recovery. The xenon adsorbent bed is optionally purged with oxygen, followed by purging with gaseous argon at cryogenic temperature (≤160 K) to displace the oxygen co-adsorbed on the AgX adsorbent due to higher selectivity of argon over oxygen on the AgX adsorbent. By the end of this step, the xenon adsorbent bed is filled with argon and xenon. Then the entire adsorbent bed is heated indirectly without utilizing any of the purge gas for direct heating. Operating the adsorption bed to near full breakthrough with xenon and displacing the adsorbed oxygen and other residues with argon, prior to regeneration, along with indirect heating of the bed, enables production of a high purity product ≥40 vol % xenon from the adsorption bed and further enables safely heating without any purge gas and ease for downstream product collection, even in cases where hydrocarbons are co-present in the feed stream.

Method for regenerating a pre-purification vessel

A system and method of regenerating a pre-purification vessel is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit that uses an oxygen-enriched purge gas stream for regeneration of the pre-purification unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the water, carbon dioxide and other impurities from a feed air stream, optionally including hydrogen and carbon monoxide impurities. The method of regenerating a pre-purification vessel preferably involves regenerating the pre-purification vessel with an oxygen-enriched purge gas after depressurization of the vessel and thereafter partially repressurizing the pre-purification vessel with an auxiliary purge gas thereby diluting the oxygen concentration of the gases contained in the pre-purification vessel and optionally depressurizing the partially repressurized vessel.

Porous ceramics for additive manufacturing, filtration, and membrane applications

In accordance with one aspect of the presently disclosed inventive concepts, a porous ceramic structure includes a three-dimensional printed structure having predefined features, where the three-dimensional structure has a geometric shape. The average length of the features may be at least 10 microns. The three-dimensional structure includes a ceramic material having an open cell structure with a plurality of pores, where the pores form continuous channels through the ceramic material from one side of the ceramic material to an opposite side of the ceramic material.

Cucurbituril-polyethylenimine-silica complex, preparation method thereof and carbon dioxide absorbent comprising same

The present disclosure relates to a cucurbituril-polyethylenimine-silica complex, a method for preparing the same and a carbon dioxide absorbent containing the same. According to the present disclosure, a cucurbituril-polyethylenimine-silica complex may be prepared by forming a complex wherein a cucurbituril is bound to polyethylenimine and including the same inside silica, and it may be used as a carbon dioxide absorbent with superior thermal stability and prevented formation of urea.

Vapor capture element for an air intake system of an internal combustion engine

An air intake system for an internal combustion engine is described, and includes a vapor capture element disposed in an interior portion of an air intake system. The vapor capture element includes a flexible Metal Organic Framework (MOF) material, wherein the flexible MOF material is reversibly controllable to a first state and to a second state in response to a control stimulus. The flexible MOF material is configured to adsorb hydrocarbon vapor when controlled to the first state and configured to desorb the hydrocarbon vapor when controlled to the second state.

FOOD CONTAINER FOR PRESERVING FRESHNESS OF FOOD ITEMS
20230202736 · 2023-06-29 ·

The invention discloses a food container for preserving freshness of food, comprising a container body having a cavity adapted for containing food items; a lid detachably secured on the container body to close the cavity of the container; and one or more food preserving elements capable of absorbing food spoiling gas to preserve freshness of the food items. The one or more food preserving elements are disposed inside the cavity and/or into a material of the food container to preserve the food items for an extended period of time and remove odors.

HYDROCARBON ADSORBENT WITH METAL-IMPREGNATED ZEOLITE PARTICLE HAVING REGULAR MESOPORE AND MANUFACTURING METHOD THEREFOR

The present invention relates to a hydrocarbon adsorbent with metal-impregnated zeolite particles having regular mesopores and a manufacturing method therefor. The hydrocarbon adsorbent includes a metal cation and a metal oxide that are impregnated in zeolite particles, in particular, the zeolite particles include regularly formed mesopores having a size of 2 to 10. By adjusting a Si/Al ratio and mesoporosity of the mesopores, a hydrocarbon adsorbent may have increased adsorption capacity for hydrocarbons in a cold-start section and can rapidly oxidize the hydrocarbon upon desorption thereof, thereby reducing the discharge of exhaust gas produced in automobiles and industries.

ADSORPTIVE SEPARATION APPARATUS
20230191317 · 2023-06-22 ·

An adsorptive separation apparatus comprises an upper air pipe, a lower air pipe, an adsorption pipe assembly located between the upper air pipe and the lower air pipe, an oil-water separation seat located at an end of the lower air pipe, and an oil-water separator arranged in the oil-water separation seat. An inner cavity is formed in the oil-water separation seat, and an air intake port is provided on the outer side surface of the oil-water separation seat. The inner cavity is in communication with the air intake port and the lower air pipe. The oil-water separator is located in the inner cavity. The oil-water separator comprises a separator housing and multiple layers of wire meshes filled inside the separator housing. Multiple through holes are formed on the separator housing.

PROCESSES, APPARATUSES, AND SYSTEMS FOR DIRECT AIR CARBON CAPTURE UTILIZING WASTE HEAT AND EXHAUST AIR
20230191316 · 2023-06-22 ·

Disclosed are processes, apparatuses, and systems for Direct Air Carbon Capture (DACC). An example process involves using a stream of exhaust air flowing from an air cooled heat exchanger to drive a DACC unit. Another example process involves conveying waste heat recovered from an industrial source to the DACC unit. The waste heat may be used to remove captured CO2 from a capture device of the DACC unit and/or for regeneration of the capture device.

CO2 CAPTURE FROM DILUTE SOURCES

Systems and methods are provided for separation of CO.sub.2 from dilute source streams. The systems and methods for the separation can include use of contactors that correspond radial flow adsorbent modules that can allow for efficient contact of CO.sub.2-containing gas with adsorbent beds while also facilitating use of heat transfer fluids in the vicinity of the adsorbent beds to reduce or minimize temperature variations. In particular, the radial flow adsorbent beds can be alternated with regions of axial flow heat transfer conduits to provide thermal management. The radial flow structure for the adsorbent beds combined with axial flow conduits for heat transfer fluids can allow for sufficient temperature control to either a) reduce or minimize temperature variations within the adsorbent beds or b) facilitate performing the separation using temperature as a swing variable for controlling the working capacity of the adsorbent.