A catalyst system and processes for combined aromatization and selective hydrogen combustion of oxygenated hydrocarbons are disclosed. The catalyst system contains at least one aromatization component and at least one selective hydrogen combustion component. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the aromatization component alone.

This invention relates to a method of chemical looping using non-stoichiometric materials with a variable degree of non-stoichiometry. One application of these methods is in the water gas shift reaction for H.sub.2 production. The methods of the invention can overcome limitations, e.g. those associated with chemical equilibria, which prevent chemical processes from proceeding with complete conversion of starting materials to products.

A hydrogen producing device is mounted at an exhaust gas port of a vehicle to receive exhaust gas and waste heat as a heat source necessary for a reforming reaction with a catalyst member in a reaction chamber. The hydrogen producing device includes a heating chamber in which the reaction chamber is received, a fuel introducing tube disposed to introduce fuel to the reaction chamber, an air introducing tube disposed in the heating chamber to exchange heat with a reaction air thereinto and introducing the reaction air into the reaction chamber for the reforming reaction, and a product discharging tube disposed to discharge a hydrogen-rich synthesis gas generated in the reaction chamber.

The invention relates to equalizing and distributing reactants more evenly across the interior space of a reactor vessel utilizing a combination equalizer and distributor at the inlet end that initially impedes with uneven flow rates of vapor and then directs the flow of vapor through a series of circumferential nozzles. The nozzles are physical spaced such that the first nozzle provides the reactants into the vessel to spread radially and broadly outwardly into the vessel and each successive circumferential nozzle to deliver reactants in a less broadly distribution or dispersion where the interior space is filled with reactants without broadly diverse velocities that may create hot spots within the catalyst bed.

A catalyst system and processes for combined aromatization and selective hydrogen combustion of oxygenated hydrocarbons are disclosed. The catalyst system contains at least one aromatization component and at least one selective hydrogen combustion component. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the aromatization component alone.

A method for conversion of greenhouse gases comprises: introducing a flow of a dehumidified gaseous source of carbon dioxide into a reaction vessel; introducing a flow of a dehumidified gaseous source of methane into the reaction vessel; and irradiating catalytic material in the reaction vessel with microwave energy. The irradiated catalytic material is heated and catalyzes an endothermic reaction of carbon dioxide and methane that produces hydrogen and carbon monoxide. At least a portion of heat required to maintain a temperature within the reaction vessel is supplied by the microwave energy. A mixture that includes carbon monoxide and hydrogen can undergo catalyzed reactions producing multiple-carbon reaction products in a lower-temperature portion of the reaction vessel.

The invention relates to equalizing and distributing vapor more evenly across the interior space of a reactor vessel utilizing an equalizing section and distributor section at the inlet end and a fixed valve tray at the bottom of the reactor to equalize and distribute the flow.

The invention relates to distributing reactants more evenly across the interior space of a reactor vessel utilizing a distributor at the inlet end that initially directs the flow of reactants through a series of circumferential nozzles. The nozzles are physical spaced such that the first nozzle provides the reactants into the vessel to spread radially and broadly outwardly into the vessel and each successive circumferential nozzle to deliver reactants in a less broadly distribution or dispersion where the interior space is filled with reactants without broadly diverse velocities that may create hot spots within the catalyst bed. The invention further includes a catalyst support tray having through holes that are sized and spaced to limit higher velocity regions within the catalyst bed and cause a more even distribution of the flow and thereby reduce hot spots within the catalyst bed.

Disclosed herein are methods and systems to isolate nitrogen from a mixture of gases. In an embodiment, a method of isolating nitrogen from a gaseous mixture involves contacting the gaseous mixture with a superparamagnetic catalyst to form a reaction mixture, and exposing the reaction mixture to a fluctuating magnetic field at ambient conditions.

The invention relates to distributing reactants more evenly across the interior space of a reactor vessel utilizing a distributor at the inlet end that initially directs the flow of reactants through a series of circumferential nozzles. The nozzles are physical spaced such that the first nozzle provides the reactants into the vessel to spread radially and broadly outwardly into the vessel and each successive circumferential nozzle to deliver reactants in a less broadly distribution or dispersion where the interior space is filled with reactants without broadly diverse velocities that may create hot spots within the catalyst bed. The invention further includes a catalyst support tray having through holes that are sized and spaced to limit higher velocity regions within the catalyst bed and cause a more even distribution of the flow and thereby reduce hot spots within the catalyst bed.