The catalyst productivity of a polyolefin catalyst in the methods disclosed herein may be increased by increasing the concentration of an induced condensing agent (ICA) in the reactor system. The effect the increased ICA concentration may have on a melt index may be counteracted, if necessary, in various ways.

A new process for the decomposition of hydrocarbon feed stream(s) that achieves the conversion of a hydrocarbon feed stream to hydrogen and filamentous carbon, with minimal resulting production of carbon oxides is described herein. In this invention it is proposed to achieve the hydrocarbon conversion by the use of dual fluidized bed reaction zones, fluidly connected, for (i). hydrocarbon reaction (the reactor) and (ii). catalyst regeneration and heating (the regenerator) and to use a transition metal supported catalyst to achieve high hydrocarbon conversion and to produce high quality filamentous carbon.

The number of small gels that form in polyolefin thin films may be reduced by altering certain production parameters of the polyolefin. In some instances, the number of small gels may be influenced by the melt index of the polyolefin. However, in many instances, melt index is a critical part of the polyolefin product specification and, therefore, is not manipulated. Two parameters that may be manipulated to mitigate small gel count while maintaining the melt index are polyolefin residence time in the reactor and ICA concentration in the reactor.

Polyolefin polymerization performed by contacting in a reactor an olefin monomer and optionally a comonomer with a catalyst system in the presence of induced condensing agents (ICA) and optionally hydrogen. The ICA may include two or more ICA components where the composition of the ICA (i.e., the concentration of each ICA component) may affect the polyolefin production rate. Changes to the relative concentration of the two or more ICA components may be according to ICA equivalency factors that allow for increasing the polyolefin production rate while maintain a sticking temperature, increasing polyolefin production rate while increasing the dew point approach temperature of the ICA, or a combination thereof.

A process and apparatus comprise a reaction chamber that includes an aspect ratio between about 0.7 and 1.3 for establishing a dense catalyst bed in the reaction chamber while minimizing hot residence time of the product gas in a range that will not deteriorate product selectivity. We have found the dense catalyst bed is necessary to ensure sufficient contact between catalyst and feed gas.

The present disclosure relates to fluid bed processes that utilize silica particles as a fluidization aid. The process comprises reacting one or more reactants in a reactor comprising a fluid bed to form a product. The fluid bed comprises a catalyst composition comprising a catalyst and an inert additive composition comprising silica particles from 0.5 wt % to 30 wt %, based on the total weight of the catalyst composition. The silica particles are discrete, inert particles that are mixed with the catalyst in the fluid bed.

A method is disclosed in which a gas of hydrogen and nitrogen, or hydrogen and ammonia, or hydrogen, nitrogen, and ammonia, is introduced to a fluidized bed. The gas flows through the fluidized bed, and titanium dioxide particles are introduced to the fluidized bed to form a fluid mixture of the particles and gas in the fluidized bed. The particles are reacted with the gas in the fluid mixture to form particles including titanium dioxide and nitrogen. The particles can be disposed along an air flow path in operative communication with a light source for air treatment.

The invention concerns a fluid distribution device (1) comprising: at least one inlet tube (2) comprising openings (7) and having a first and a second end (3, 4); a cap (5) comprising a principal body (6) with a lenticular shape and with a circular section elongated by a skirt (8) extending in the direction of the second end (4) towards the first end (3) of the inlet tube (2), said cap (5) having an outer surface and an inner surface, the cap being integral with the second end (4) of the tube via the inner surface and the principal body (6) being provided with a plurality of holes (10);
and in which the cap (5) comprises at least one deflection means (14) disposed on its outer surface and configured to direct or maintain the gas towards or at the periphery of said cap (5).

Processes of catalytically pyrolyzing solid hydrocarbonaceous materials in a downflow fluid bed reactor and regenerating the catalyst in an upflow fluidized bed reactor are described. Systems and compositions useful in the catalytic pyrolysis of plastics are also described.

A method for the conversion of a carbonaceous material. The method comprising the steps of providing a carbonaceous material, providing a hot powder material and contacting the carbonaceous material and the powder material in an atmosphere configured to no more than partially oxidize carbon to CO.sub.2. The carbonaceous material is at least a partial converted into volatiles. The volatiles are separated from the additional components by specific gravity.