B01J19/244

Method and device for the hydrolysis of a compound
10730033 · 2020-08-04 · ·

The subject matter of the invention is a device for the hydrolysis of at least one compound. The device comprises a first cylindrical section having a diameter D.sub.max, a central duct, an outer duct which surrounds the central duct coaxially, an outlet having a diameter D.sub.A, and a second section which tapers towards the outlet and into which the ducts issue. The second section has, in cross-section along a longitudinal axis A.sub.L of the device, a profile which is described by two radii R1 and R2 which merge tangentially into each other, where 0.2<R1/D.sub.A<4.0 and 0.3<R2/D.sub.A<5.0. The invention also relates to a method for the hydrolysis of at least one compound. In the method, the device is used to conduct water at least through the outer duct and to conduct the compound to be hydrolysed through the central duct and/or through at least one intermediate duct and to mix them with each other at least partially in the second section. The compound and the water are in liquid form.

UV-LED PHOTOREACTORS WITH CONTROLLED RADIATION AND HYDRODYNAMICS AND METHODS FOR FABRICATION AND USE OF SAME
20200230270 · 2020-07-23 · ·

One aspect described herein is a fluid treatment apparatus. The apparatus may comprise a body extending along a flow path between a first end and a second end opposite of the first end along the flow path, the first end comprising an inlet along the flow path, the second end comprising an outlet along the flow path; a flow channel extending inside the body along the flow path to direct a fluid from the inlet to the outlet; and a solid-state radiation source mountable in a cavity of the flow channel to emit radiation into the flow channel along the flow path, the solid-state radiation source comprising a thermally conductive portion positioned to be contacted by the fluid when the fluid is flowing from the inlet to the outlet and the solid-state radiation source is mounted in the cavity. Related apparatus, devices, and methods also are described.

METHOD FOR MANUFACTURING POLYMER AND FLOW-TYPE REACTION SYSTEM FOR MANUFACTURING POLYMER
20200223949 · 2020-07-16 · ·

A method for manufacturing a polymer by performing an anionic polymerization reaction by a flow-type reaction, including: introducing a liquid A containing an anionic polymerizable monomer, a liquid B containing an anionic polymerization initiator, and a polymerization terminator into different flow paths respectively and causing the liquids to flow in the respective flow paths; causing the liquid A and the liquid B to join together by using a multilayered cylindrical mixer; subjecting the anionic polymerizable monomer to anionic polymerization while a solution formed by the joining is flowing to downstream in the reaction flow path; and causing a polymerization reaction solution flowing in a reaction flow path and the polymerization terminator to join together such that the polymerization reaction is terminated; and a flow-type reaction system suitable for performing the manufacturing method.

MEMBRANE-BASED PROCESS FOR BUTANOLS PRODUCTION FROM MIXED BUTENES
20200189996 · 2020-06-18 ·

A method of separately producing tert-butanol and sec-butanol, comprising the steps of introducing a mixed butenes stream to a tube side of a reaction membrane unit, introducing a TBA reactor water feed to the tube side of the reaction membrane unit, introducing a sweep gas to a shell side of the reaction membrane unit, introducing an SBA reactor water feed to the shell side, allowing the mixed butenes stream to contact the tube side of a such that selective gases in the mixed butenes stream permeate through the membrane to the shell side, allowing the selective gases that permeate through the membrane to react with water to produce sec-butanol, allowing retentate gases that fail to permeate through the membrane to react with water to produce tert-butanol, collecting the tert-butanol in a TBA reactor effluent, and collecting the sec-butanol in a SBA reactor effluent.

Membrane-based process for butanols production from mixed butenes
10570071 · 2020-02-25 · ·

A method of separately producing tert-butanol and sec-butanol, comprising the steps of introducing a mixed butenes stream to a tube side of a reaction membrane unit, introducing a TBA reactor water feed to the tube side of the reaction membrane unit, introducing a sweep gas to a shell side of the reaction membrane unit, introducing an SBA reactor water feed to the shell side, allowing the mixed butenes stream to contact the tube side of a such that selective gases in the mixed butenes stream permeate through the membrane to the shell side, allowing the selective gases that permeate through the membrane to react with water to produce sec-butanol, allowing retentate gases that fail to permeate through the membrane to react with water to produce tert-butanol, collecting the tert-butanol in a TBA reactor effluent, and collecting the sec-butanol in a SBA reactor effluent.

APPARATUS FOR CONVERTING A FEED GAS INTO A PRODUCT GAS

Apparatus for converting feed gas (28) into a product gas (29), comprising at least one reactor (1) with a reaction chamber (15) bounded by the inner wall of an outer tube (4) closed at a first outer end and an inner tube (14) received coaxially in this outer tube (4) and provided at both its outer ends with openings, which reactor (1) is provided with an inlet chamber (11) and with an outlet chamber (10), wherein a first wall (31) of the outlet chamber (10) encloses the outer tube (4) and extends therefrom, and a second wall (12) of the outlet chamber (10) lying opposite the first wall (31) encloses the outer tube (4) and extends therefrom, and the inlet chamber (11) is bounded by the second wall (12) of the outlet chamber (10) and a third wall (47) which lies opposite this second wall (12), encloses the outer tube (4) and extends therefrom.

METHOD AND DEVICE FOR THE HYDROLYSIS OF A COMPOUND
20200030769 · 2020-01-30 ·

The subject matter of the invention is a device for the hydrolysis of at least one compound. The device comprises a first cylindrical section having a diameter D.sub.max, a central duct, an outer duct which surrounds the central duct coaxially, an outlet having a diameter D.sub.A, and a second section which tapers towards the outlet and into which the ducts issue. The second section has, in cross-section along a longitudinal axis A.sub.L of the device, a profile which is described by two radii R1 and R2 which merge tangentially into each other, where 0.2<R1/D.sub.A<4.0 and 0.3<R2/D.sub.A<5.0. The invention also relates to a method for the hydrolysis of at least one compound. In the method, the device is used to conduct water at least through the outer duct and to conduct the compound to be hydrolysed through the central duct and/or through at least one intermediate duct and to mix them with each other at least partially in the second section. The compound and the water are in liquid form.

Chemical reactor for use with overly reactive chemicals
10525434 · 2020-01-07 · ·

A chemical reactor for use in a chemical process wherein a reactant and/or a target product is prone to produce undesirable byproducts through secondary reactions. The reactor is configured with a first flow passage for passing a flow of an overly reactive reactant; a permeable first wall for controlled flow of the overly reactive reactant into a second flow passage providing a flow of a second reactant; a permeable second wall having a catalyst supported on an inner surface thereof for catalyzing reaction of the reactants flowing in the second flow passage; the permeable second wall passing through a flow containing the target product; and a non-permeable third wall defining a third flow passage for exiting the product mixture. The reactor can be employed in selective oxidation, oxidative dehydrogenation, and alkylation processes to reduce the formation of byproducts.

Reactor for carrying out a gas-liquid two-phase high-pressure reaction with a foaming medium

A reactor for performing a gas/liquid biphasic high-pressure reaction with a foaming medium, comprising an interior formed by a cylindrical, vertically oriented elongate shell, a bottom and a cap, wherein the interior is divided by internals into a backmixed zone and a zone of limited backmixing, wherein the backmixed zone and the zone of limited backmixing are consecutively traversable by the reaction mixture, wherein the backmixed zone comprises means for introducing gas and liquid and a gas outlet and also comprises at least one mixing apparatus selected from a stirrer, a jet nozzle and means for injecting the gas, and the zone of limited backmixing comprises a reaction product outlet, a first cylindrical internal element which in the interior extends in the longitudinal direction of the reactor and which delimits the zone of limited backmixing from the backmixed zone, backmixing-preventing second internal elements in the form of random packings, structured packings or liquid-permeable trays arranged in the zone of limited backmixing and a riser tube whose lower end is arranged within the backmixed zone and whose upper end opens into the zone of limited backmixing so that liquid from the backmixed zone can ascend into the zone of limited backmixing via the riser tube, wherein flow into the zone of limited backmixing enters from below. The reactor is configured such that the high-pressure reaction space is optimally utilized and contamination of workup steps or subsequent reactions arranged downstream of the high-pressure reaction with foam is substantially avoided. The invention further relates to a process for performing a continuous gas/liquid biphasic high-pressure reaction in the reactor.

A FURNACE SUITED FOR CHEMILUMINESCENT SULPHUR DETECTION
20190383748 · 2019-12-19 ·

The invention is directed to a furnace suited for oxidation of a gaseous starting mixture comprising one or more sulphur compounds to obtain an oxidized gas mixture and reduction of the oxidized gas mixture to obtain a gaseous mixture of reduced sulphur compounds comprising an interior furnace space, an inlet conduit for the gaseous starting mixture, an inlet for supply of an oxygen comprising gas, a ceramic comprising outlet conduit provided with an inlet opening for the mixture of reduced sulphur compounds, an inlet for hydrogen and heating means, wherein the inlet opening of the outlet conduit is comprised of more than one opening which openings fluidly connect the interior furnace space and the interior of the outlet conduit.