A process and a process plant for production of elemental sulfur from a feedstock gas including from 15 vol % to 100 vol % H2S and a stream of sulfuric acid, the process including a) providing a Claus reaction furnace feed stream with a substoichiometric amount of oxygen, b) directing s to a reaction furnace operating at elevated temperature, c) cooling, d) directing to contact a material catalytically active in the Claus reaction, e) withdrawing a Claus tail gas and elemental sulfur, f) directing to a means for sulfur oxidation, g) directing to contact a material catalytically active in SO2 oxidation to SO3, h) converting to concentrated sulfuric acid, i) recycling to the Claus reaction furnace, wherein an amount of combustibles, in the Claus tail gas, is oxidized in the presence of a material catalytically active in sulfur oxidation, at an inlet temperature below 400° C.

The present invention proposes a plant (110) for producing reaction products. The plant (110) comprises at least a preheater (114). The plant (110) comprises at least one raw material supply (118) which is adapted for supplying at least one raw material to the preheater (114). The preheater (114) is adapted for preheating the raw material to a predetermined temperature. The plant (110) comprises at least one electrically heatable reactor (122). The electrically heatable reactor (122) is adapted for at least partially converting the preheated raw material into reaction products and byproducts. The plant (110) comprises at least one heat integration apparatus (132) which is adapted for at least partially supplying the byproducts to the preheater (114). The preheater (114) is adapted for at least partially utilizing energy required for preheating the raw material from the byproducts.

A method is described for shutting down a Fischer-Tropsch reactor fed with a reactant gas mixture comprising a synthesis gas and a recycle gas recovered from the Fischer-Tropsch reactor in a synthesis loop, said Fischer-Tropsch reactor containing a Fischer-Tropsch catalyst cooled indirectly by a coolant under pressure, comprising the steps of: (a) depressurising the coolant to cool the reactant gas mixture to quench Fischer-Tropsch reactions taking place in the Fischer-Tropsch reactor, (b) stopping the synthesis gas feed to the Fischer-Tropsch reactor, and (c) maintaining circulation of the recycle gas through the Fischer-Tropsch reactor during steps (a) and (b) to remove heat from the Fischer-Tropsch reactor. The method safely facilitates a more rapid return to operating conditions than a full shut-down.

Methods and systems for producing acetic acid, including glacial acetic acid. A first stream of a reactor fluid that includes methyl acetate, water, and a first amount of carbon monoxide may be forwarded from a reactor to a reactor cooler to form a cooled reactor fluid. The cooled reactor fluid may have a concentration of methyl acetate that is lower than the concentration of methyl acetate in the reactor fluid.

A polymerization process may include: polymerizing a monomer having 4 or less carbons and a comonomer having 6 or more carbons in the presence of an inert isomer/saturate of the comonomer to yield a product stream comprising a polymer, unreacted monomer, unreacted comonomer, and the inert isomer/saturate of the comonomer; separating the product stream into (a) a polymer stream and (b) an unreacted components stream; and separating the unreacted components stream in a distillation column into (a) an overhead stream comprising the unreacted monomer and (b) a bottoms stream comprising the comonomer and the inert isomer/saturate of the comonomer, wherein a concentration of C5− hydrocarbons in the overhead stream is higher than a concentration of the C5− hydrocarbons in the unreacted components stream, and wherein a concentration of C6+ hydrocarbons in the bottoms stream is higher than a concentration of the C6+ hydrocarbons in the unreacted components stream.

A process for increasing the softening point of asphalt using an eductor, preheated asphalt is mixed with an input gas in the eductor to form a gas/asphalt mixture. The gas/asphalt mixture is conducted to a heated and pressurized oxidizer vessel via piping connected to the discharge connection of the eductor, where the piping enables a bubble flow pattern to develop therein to enable reaction of the oxygen with the asphalt. The oxygen entrained asphalt mixture is discharged from an exit port of the piping in the oxidizer vessel. The resulting oxidized asphalt product stream has a softening temperature greater than the preheated asphalt feed. The process minimizes the off-gas produced to reduce the carbon footprint.

A submerged propylene hydration micro-interface strengthening reaction system and a method are proposed. The system includes a reactor, a first micro-interface generator and a second micro-interface generator. Through the micro-interface generators, the propylene is broken to form micron-scale bubbles, which are mixed with reactants and deionized water to form a gas-liquid emulsion, so as to increase a phase boundary area between gas and liquid phases, and achieve a strengthening mass transfer effect under a lower preset operating condition. The micro-scale bubbles can be fully mixed with the deionized water to from a gas-liquid emulsion. By fully mixing gas and liquid phases, it can ensure that the deionized water in the system is in full contact with propylene, and they are fully in contact with the catalyst, which effectively improves the efficiency of preparing isopropanol.

A process for producing alkoxylates features a high growth ratio without the need of interim storage of a pre-polymer produced in a first reactor. The process may involve reacting a monomeric educt in the presence of a catalyst and a starting material in a first reactor equipped with a first circulation loop and thereafter passing a pre-polymer that is produced of the first circulation loop to a second reactor equipped with a second circulation loop, where a desired polymer is produced. The first reactor may comprise a smaller volume than the second reactor. The growth ratio, defined as a final batch volume of the second reactor divided by a minimum initial volume of the starting material in the first reactor, is at least 80:1.

The present invention relates to an oligomerization process implemented in a gas/liquid reactor comprising a headspace recycle loop. The process more particularly relates to the oligomerization of ethylene to linear alpha-olefins such as 1-butene, 1-hexene, 1-octene or a mixture of linear alpha-olefins.

An integrated process for making styrene and propene oxide which comprises the steps: a) dehydrogenating ethylbenzene in the presence of a dehydrogenation catalyst; b) separating styrene and hydrogen from the reaction mixture of step a); c) producing hydrogen peroxide from hydrogen separated in step b) and oxygen; d) reacting propene with the hydrogen peroxide obtained in step c) in the presence of an epoxidation catalyst to provide a reaction mixture comprising propene oxide; and e) separating propene oxide from the reaction mixture obtained in step d).