B01J23/22

Mesoporous metal titanates as multifunctional catalysts

The present disclosure relates to mesoporous metal titanate materials composition. Specifically, the present disclosure relates to a mesoporous metal titanate material composition that is active for multiple reactions, including aromatic alkylation, alkene coupling, alkene cyclization, alkyne oxidation, alcohol dehydrogenation reactions.

Combustion system

Provided is a combustion system using a catalyst having better denitration efficiency at low temperatures, during a selective catalytic reduction reaction in which ammonia is used as a reducing agent. This combustion system comprises: a combustion device that combusts fuel; an exhaust path through which flows exhaust gas generated from the combustion of fuel in the combustion device; a dust collection device that is arranged on the exhaust path and collects ash dust/dust in the exhaust gas; and a denitration device that is arranged on the exhaust path and removes nitrogen oxides from the exhaust gas by means of a denitration catalyst, wherein the denitration device is arranged downstream of the dust collection device on the exhaust path, and the denitration catalyst contains vanadium oxide including vanadium pentoxide and has a defect site in which an oxygen atom is deficient in a crystal structure of the vanadium pentoxide.

Combustion system

Provided is a combustion system using a catalyst having better denitration efficiency at low temperatures, during a selective catalytic reduction reaction in which ammonia is used as a reducing agent. This combustion system comprises: a combustion device that combusts fuel; an exhaust path through which flows exhaust gas generated from the combustion of fuel in the combustion device; a dust collection device that is arranged on the exhaust path and collects ash dust/dust in the exhaust gas; and a denitration device that is arranged on the exhaust path and removes nitrogen oxides from the exhaust gas by means of a denitration catalyst, wherein the denitration device is arranged downstream of the dust collection device on the exhaust path, and the denitration catalyst contains vanadium oxide including vanadium pentoxide and has a defect site in which an oxygen atom is deficient in a crystal structure of the vanadium pentoxide.

Emission control during catalyst regeneration
11806703 · 2023-11-07 · ·

Catalyst regeneration processes that include measures for controlling emissions generated during the regeneration are described. The present invention further relates to catalytic processes for producing various chlorinated aromatic compounds that include provisions for controlling emissions during catalyst regeneration.

Emission control during catalyst regeneration
11806703 · 2023-11-07 · ·

Catalyst regeneration processes that include measures for controlling emissions generated during the regeneration are described. The present invention further relates to catalytic processes for producing various chlorinated aromatic compounds that include provisions for controlling emissions during catalyst regeneration.

TITANIUM OXIDE PARTICLES, DISPERSION LIQUID THEREOF, PHOTOCATALYST THIN FILM, MEMBER HAVING PHOTOCATALYST THIN FILM ON SURFACE, AND METHOD FOR PRODUCING TITANIUM OXIDE PARTICLE DISPERSION LIQUID

Provided are titanium oxide particles having a higher photocatalytic activity, particularly a higher visible light activity as compared to the conventional ones; a dispersion liquid thereof; a photocatalyst thin film formed using such dispersion liquid; a member having such photocatalyst thin film on its surface; and a method for producing the titanium oxide particle dispersion liquid. The titanium oxide particles are those with (1) a tin component and a visible light activity-enhancing transition metal component being solid-dissolved in the particles; and with (2) an iron component, a titanium component and a silicon component being adhered to the surfaces of the particles. The titanium oxide particle dispersion liquid is one with the titanium oxide particles being dispersed in an aqueous dispersion medium.

TITANIUM OXIDE PARTICLES, DISPERSION LIQUID THEREOF, PHOTOCATALYST THIN FILM, MEMBER HAVING PHOTOCATALYST THIN FILM ON SURFACE, AND METHOD FOR PRODUCING TITANIUM OXIDE PARTICLE DISPERSION LIQUID

Provided are titanium oxide particles having a higher photocatalytic activity, particularly a higher visible light activity as compared to the conventional ones; a dispersion liquid thereof; a photocatalyst thin film formed using such dispersion liquid; a member having such photocatalyst thin film on its surface; and a method for producing the titanium oxide particle dispersion liquid. The titanium oxide particles are those with (1) a tin component and a visible light activity-enhancing transition metal component being solid-dissolved in the particles; and with (2) an iron component, a titanium component and a silicon component being adhered to the surfaces of the particles. The titanium oxide particle dispersion liquid is one with the titanium oxide particles being dispersed in an aqueous dispersion medium.

SELECTIVE CATALYTIC REDUCTION CATALYST AND CATALYTIC ARTICLE COMPRISING THE SAME
20230347288 · 2023-11-02 ·

The present invention relates to a selective catalytic reduction (SCR) catalyst comprising a support, vanadium and antimony, a catalytic article comprising the SCR catalyst, and an exhaust treatment system for an internal combustion engine comprising the SCR catalyst. In one embodiment, the invention provides an SCR catalyst for reduction of 5 nitrogen oxides, comprising: a support, and an active material on the support; wherein the support, calculated as its oxide, is present in the SCR catalyst in an amount of 40 to 99% by weight, relative to the total weight of the SCR catalyst; the active material comprises vanadium and antimony; the vanadium, calculated as V.sub.2O.sub.5, is present in the SCR catalyst in an amount of 1 to 15% by weight, relative to the total weight of the SCR catalyst; the 10 antimony, calculated as Sb.sub.2O.sub.3, is present in the SCR catalyst in an amount of 0.5 to 20% by weight, relative to the total weight of the SCR catalyst; wherein the SCR catalyst, after hydrothermally aged at 550° C. for 100 hours with 10% water, has a 200-300° C. denitrification efficiency of at least 60%, with 60,000h.sup.−1 space velocity and an ammonia to NOx molar ratio of 1:11

SELECTIVE CATALYTIC REDUCTION CATALYST AND CATALYTIC ARTICLE COMPRISING THE SAME
20230347288 · 2023-11-02 ·

The present invention relates to a selective catalytic reduction (SCR) catalyst comprising a support, vanadium and antimony, a catalytic article comprising the SCR catalyst, and an exhaust treatment system for an internal combustion engine comprising the SCR catalyst. In one embodiment, the invention provides an SCR catalyst for reduction of 5 nitrogen oxides, comprising: a support, and an active material on the support; wherein the support, calculated as its oxide, is present in the SCR catalyst in an amount of 40 to 99% by weight, relative to the total weight of the SCR catalyst; the active material comprises vanadium and antimony; the vanadium, calculated as V.sub.2O.sub.5, is present in the SCR catalyst in an amount of 1 to 15% by weight, relative to the total weight of the SCR catalyst; the 10 antimony, calculated as Sb.sub.2O.sub.3, is present in the SCR catalyst in an amount of 0.5 to 20% by weight, relative to the total weight of the SCR catalyst; wherein the SCR catalyst, after hydrothermally aged at 550° C. for 100 hours with 10% water, has a 200-300° C. denitrification efficiency of at least 60%, with 60,000h.sup.−1 space velocity and an ammonia to NOx molar ratio of 1:11

Vanadium-based catalyst composition for CO.SUB.2.-mediated oxidative dehydrogenation of propane

A method of making an active catalyst composition includes mixing at least one support with a vanadium oxide precursor and grinding thereby at least partially embedding the vanadium oxide precursor particles in different layers and surfaces of the at least one support to form a first precursor; mixing the first precursor and a first solvent to form a first mixture; grinding the first mixture and drying at a temperature of 60 to 105° C.; calcining the first mixture after the drying at a temperature of at least 300° C. thereby allowing the vanadium oxide precursor particles embedded in different layers and surfaces of the at least one support to decompose in situ to generate vanadium oxide (VO.sub.x) particles embedded in the at least one support and form the first vanadium catalyst; and mixing the first vanadium catalyst with a second vanadium catalyst to form the active catalyst composition.