Catalysts, catalytic systems and related synthetic methods for in situ production of H.sub.2O.sub.2 and use thereof in reaction with oxidizable substrates.

Catalysts, catalytic systems and related synthetic methods for in situ production of H.sub.2O.sub.2 and use thereof in reaction with oxidizable substrates.

Porous metal oxide catalytic materials with planar morphologies which are derived from metal-organic framework (MOF) materials via thermal decomposition, oxidation pretreatment and pyrolysis processes. The porous metal oxides are mainly transition metal oxides, derived from MOFs containing the corresponding transition metal ions, such as Cu, Zn, Y, La, Ce, Ti, Zr, V, Cr, Mn, Fe, Co, and Ni ions. The transformation conditions from MOF materials to metal oxides, such as temperature, atmosphere and duration, are well defined to obtain metal oxides with controlled morphologies. Furthermore, the present subject matter relates to a low-temperature catalytic decomposition of volatile organic compounds (VOCs) with a wide concentration range on two-dimensional metal oxides.

Porous metal oxide catalytic materials with planar morphologies which are derived from metal-organic framework (MOF) materials via thermal decomposition, oxidation pretreatment and pyrolysis processes. The porous metal oxides are mainly transition metal oxides, derived from MOFs containing the corresponding transition metal ions, such as Cu, Zn, Y, La, Ce, Ti, Zr, V, Cr, Mn, Fe, Co, and Ni ions. The transformation conditions from MOF materials to metal oxides, such as temperature, atmosphere and duration, are well defined to obtain metal oxides with controlled morphologies. Furthermore, the present subject matter relates to a low-temperature catalytic decomposition of volatile organic compounds (VOCs) with a wide concentration range on two-dimensional metal oxides.

Methods for making a supported chromium catalyst are disclosed, and can comprise contacting a silica-coated alumina containing at least 30 wt. % silica with a chromium-containing compound in a liquid, drying, and calcining in an oxidizing atmosphere at a peak temperature of at least 650 C. to form the supported chromium catalyst. The supported chromium catalyst can contain from 0.01 to 20 wt. % chromium, and typically can have a pore volume from 0.5 to 2 mL/g and a BET surface area from 275 to 550 m.sup.2/g. The supported chromium catalyst subsequently can be used to polymerize olefins to produce, for example, ethylene-based homopolymers and copolymers having high molecular weights and broad molecular weight distributions.

Methods for making a supported chromium catalyst are disclosed, and can comprise contacting a silica-coated alumina containing at least 30 wt. % silica with a chromium-containing compound in a liquid, drying, and calcining in an oxidizing atmosphere at a peak temperature of at least 650 C. to form the supported chromium catalyst. The supported chromium catalyst can contain from 0.01 to 20 wt. % chromium, and typically can have a pore volume from 0.5 to 2 mL/g and a BET surface area from 275 to 550 m.sup.2/g. The supported chromium catalyst subsequently can be used to polymerize olefins to produce, for example, ethylene-based homopolymers and copolymers having high molecular weights and broad molecular weight distributions.

A dehydrochlorination process is disclosed. The process involves contacting R.sub.fCHClCH.sub.2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising R.sub.fCClCH.sub.2, wherein R.sub.f is a perfluorinated alkyl group.

A dehydrochlorination process is disclosed. The process involves contacting R.sub.fCHClCH.sub.2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising R.sub.fCClCH.sub.2, wherein R.sub.f is a perfluorinated alkyl group.

Disclosed are a catalyst for producing olefin and a preparation method thereof. The catalyst for producing olefin includes: a support including an alumina and a sub-support component; and a catalytic component comprising a metal component and an alkali metal impregnated on the support. The preparation method includes: providing a support comprising a sub-support component and an alumina; preparing pre-catalyst by dipping a metal component oxide in the support and calcining it; and dipping a metal component oxide and an alkali metal oxide in the pre-catalyst and calcining it.

Disclosed are a catalyst for producing olefin and a preparation method thereof. The catalyst for producing olefin includes: a support including an alumina and a sub-support component; and a catalytic component comprising a metal component and an alkali metal impregnated on the support. The preparation method includes: providing a support comprising a sub-support component and an alumina; preparing pre-catalyst by dipping a metal component oxide in the support and calcining it; and dipping a metal component oxide and an alkali metal oxide in the pre-catalyst and calcining it.