The present invention discloses catalyst and method for producing light olefins directly from synthesis gas by a one-step process, and particularly relates to method and catalyst for directly converting synthesis gas into light olefins by a one-step process. The provided catalysts are composite materials formed of multicomponent metal oxide composites and inorganic solid acids with hierarchical pore structures. The inorganic solid acids have a hierarchical pore structure having micropores, mesopores and macropores. The metal composites can be mixed with or dispersed on surfaces or in pore channels of the inorganic solid acid and can catalyze the synthesis gas conversion to a C.sub.2-C.sub.4 light hydrocarbon product containing two to four carbon atoms. The single pass conversion of CO is 10%-60%. The selectivity of light hydrocarbon in all hydrocarbon products can be up to 60%-95%, wherein the selectivity of light olefins (C.sub.2.sup.C.sub.4.sup.) is 50%-85%.

A method of preparing a catalyst comprising a) contacting a non-aqueous solvent, a carboxylic acid, and a chromium-containing compound to form an acidic mixture; b) contacting a titanium-containing compound with the acidic mixture to form a titanium treatment solution; c) contacting a pre-formed silica-support comprising from about 0.1 wt. % to about 20 wt. % water with the titanium treatment solution to form a pre-catalyst; and d) thermally treating the pre-catalyst to form the catalyst. A method of preparing a catalyst comprising a) contacting a non-aqueous solvent and a carboxylic acid to form an acidic mixture; b) contacting a titanium-containing compound with the acidic mixture to form a titanium treatment solution; c) contacting a pre-formed chrominated silica-support comprising from about 0.1 wt. % to about 20 wt. % water with the titanium treatment solution to form a pre-catalyst; and d) thermally treating the pre-catalyst to form the catalyst.

A manufacturing method of 1-chloro-3,3,3-trifluoropropene (1233zd) is provided. This manufacturing method includes a reaction in which a halogenated hydrocarbon compound having a carbon number of 3 and represented by a general formula (1) is heated:

CF.sub.aCl.sub.3-aCH.sub.2CHF.sub.bCl.sub.2-b(1)

In the formula, a is an integer from 0 to 2, b is 1 or 2 when a=0, b is 0 or 1 when a=1, and b is 0 when a=2.

Reaction device which makes possible the oligomerization of olefins to give linear olefins and preferably linear -olefins, comprising a gas/liquid reactor and a reactor of plug-flow type. The reaction device is also employed in an oligomerization process.

Reaction device which makes possible the oligomerization of olefins to give linear olefins and preferably linear -olefins, comprising a gas/liquid reactor and a reactor of plug-flow type. The reaction device is also employed in an oligomerization process.

The present invention relates to a core-shell composite catalyst, wherein the core is a spinel-structure XY.sub.aO.sub.b catalyst, wherein X and Y, being different from each other, are metal elements selected from main group II, transition elements and main group III of the Periodic Table of Elements; a is a number between 1-15, preferably between 1-5; b is the number of oxygen atoms required to satisfy the valence of the elements; the shell is a molecular sieve catalyst, preferably selected from one or more of ZSM-5, ZSM-11, ZSM-35 and MOR, more preferably selected from ZSM-5 and ZSM-11. When the core-shell composite catalyst is used for preparing p-xylene directly from syngas in one step, the process is simple and easy to operate; the selectivity toward p-xylene in xylene products is high; the conversion of syngas is high; and the service life of the catalyst is long. In addition, the present invention also relates to the preparation method of core-shell composite catalyst, and use thereof as the catalyst in the one-step preparation of p-xylene from syngas.

The present invention relates to a core-shell composite catalyst, wherein the core is a spinel-structure XY.sub.aO.sub.b catalyst, wherein X and Y, being different from each other, are metal elements selected from main group II, transition elements and main group III of the Periodic Table of Elements; a is a number between 1-15, preferably between 1-5; b is the number of oxygen atoms required to satisfy the valence of the elements; the shell is a molecular sieve catalyst, preferably selected from one or more of ZSM-5, ZSM-11, ZSM-35 and MOR, more preferably selected from ZSM-5 and ZSM-11. When the core-shell composite catalyst is used for preparing p-xylene directly from syngas in one step, the process is simple and easy to operate; the selectivity toward p-xylene in xylene products is high; the conversion of syngas is high; and the service life of the catalyst is long. In addition, the present invention also relates to the preparation method of core-shell composite catalyst, and use thereof as the catalyst in the one-step preparation of p-xylene from syngas.

A method of manufacturing a catalyst material includes the steps of: providing a body having an open-porous foam structure and comprising at least a first metal or alloy; providing particles, each of which particles comprising at least a second metal or alloy; distributing the particles on the body; forming a structural connection between each of at least a subset of the particles and the body; and forming an oxide film on at least the subset of the particles and the body, wherein the oxide film has a catalytically active surface.

A method of manufacturing a catalyst material includes the steps of: providing a body having an open-porous foam structure and comprising at least a first metal or alloy; providing particles, each of which particles comprising at least a second metal or alloy; distributing the particles on the body; forming a structural connection between each of at least a subset of the particles and the body; and forming an oxide film on at least the subset of the particles and the body, wherein the oxide film has a catalytically active surface.

A hybrid catalyst including a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of aluminum and gallium, and a microporous catalyst component that is a molecular sieve having 8-MR pore openings. The metal oxide catalyst component includes anatomic ratio of chromium:zinc (Cr:Zn) from 0.35 to 1.00, and the at least one additional metal is present in an amount from 25.0 at % to 40.0 at %. A process for preparing C2 and C3 olefins comprising: a) introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor; and b) converting the feed stream into a product stream comprising C2 and C3 olefins in the reaction zone in the presence of said hybrid catalyst.