Patent classifications
B01J23/30
Catalyst for use in the selective catalytic reduction (SCR) of nitrogen oxides
The present invention pertains to a catalyst for use in the selective catalytic reduction (SCR) of nitrogen oxides comprising: • a monolithic substrate and • a coating A which comprises an oxidic metal carrier comprising an oxide of titanium and a catalytic metal oxide which comprises an oxide of vanadium wherein the mass ratio vanadium/titanium is 0.07 to 0.26.
Process for producing oxide catalysts
An object of the present invention is to provide a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutene, which enables a catalyst demonstrating favorable yield to be stably produced. According to the present invention, there is provided a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutane, comprising the steps of: (i) preparing a catalyst raw material mixture containing Mo, V and Nb and satisfying the relationships of 0.1≦a≦1 and 0.01≦b≦1 when atomic ratios of V and Nb to one atom of Mo are defined as a and b, respectively; (ii) drying the catalyst raw material mixture; and (iii) calcining a particle, in which a content of the particle having a particle diameter of 25 μm or less is 20% by mass or less and a mean particle diameter is from 35 to 70 μm, in an inert gas atmosphere.
Process for producing oxide catalysts
An object of the present invention is to provide a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutene, which enables a catalyst demonstrating favorable yield to be stably produced. According to the present invention, there is provided a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutane, comprising the steps of: (i) preparing a catalyst raw material mixture containing Mo, V and Nb and satisfying the relationships of 0.1≦a≦1 and 0.01≦b≦1 when atomic ratios of V and Nb to one atom of Mo are defined as a and b, respectively; (ii) drying the catalyst raw material mixture; and (iii) calcining a particle, in which a content of the particle having a particle diameter of 25 μm or less is 20% by mass or less and a mean particle diameter is from 35 to 70 μm, in an inert gas atmosphere.
HIGH-PERFORMANCE POLYOXOMETALATE CATALYST AND METHOD OF PREPARING THE SAME
The present invention relates to a high-performance polyoxometalate catalyst and a method of preparing the same. More particularly, the present invention provides a high-performance polyoxometalate catalyst, the activity and selectivity of which may be improved by controlling the content of vanadium and the like and which has superior reproducibility and may unsaturated carboxylic acid from unsaturated aldehyde in a high yield for a long time, a method of preparing the same, and the like.
HIGH-PERFORMANCE POLYOXOMETALATE CATALYST AND METHOD OF PREPARING THE SAME
The present invention relates to a high-performance polyoxometalate catalyst and a method of preparing the same. More particularly, the present invention provides a high-performance polyoxometalate catalyst, the activity and selectivity of which may be improved by controlling the content of vanadium and the like and which has superior reproducibility and may unsaturated carboxylic acid from unsaturated aldehyde in a high yield for a long time, a method of preparing the same, and the like.
PHOTOCATALYST FUNCTIONAL FILM AND METHOD FOR PRODUCING THE SAME
A photocatalytic functional film has a structure of a substrate, a barrier layer and a photocatalytic layer stacked one on another. The barrier layer is an amorphous TiO.sub.2 film, the photocatalyst layer comprises an amorphous TiO.sub.2 film, and particles of visible light responsive photocatalytic material formed on the surface of the amorphous TiO.sub.2 film. A method for producing a photocatalytic functional film includes: adding an alcohol solvent and an acid to a titanium precursor to obtain a TiO.sub.2 amorphous sol by dehydration and de-alcoholization reaction; applying and drying the TiO.sub.2 amorphous sol on a substrate to form a barrier layer; and applying and drying a composition formed by mixing particles of visible light responsive photocatalyst material with the TiO.sub.2 amorphous sol on the barrier layer, to form a photocatalyst layer.
CATALYSTS AND METHODS FOR PRODUCING PROPYLENE FROM ETHYLENE AND BUTENE
The present disclosure relates to chemical catalysts and methods that may be used for the production and/or interconversion of olefins. In some embodiments, methods for producing propylene from ethylene and butene comprising, (a) obtaining a catalyst composition comprising an isomerization catalyst and a disproportionation catalyst, wherein the weight ratio of the isomerization catalyst to the disproportionation catalyst is from 10:1 to 1:10; and (b) reacting butene with ethylene at a temperature from about 500° F. (260° C.) to about 650° F. (350° C.) in the presence of the catalyst composition under conditions sufficient to produce propylene are provided.
Process for dehydrating methanol to dimethyl ether
A process for dehydrating methanol to dimethyl ether using a Brønsted acid catalyst which is a 1-dimensional or a 3-dimensional aluminosilicate zeolite or a heteropolyacid, and a promoter of Formula I C.sub.nH.sub.(2n+1)CO.sub.2CH.sub.3 wherein n=1 to 11 or Formula II C.sub.mH.sub.2m(CO.sub.2CH.sub.3).sub.2 wherein m=2 to 7 and the molar ratio of promoter to methanol is maintained at less than 1.
Process for dehydrating methanol to dimethyl ether
A process for dehydrating methanol to dimethyl ether using a Brønsted acid catalyst which is a 1-dimensional or a 3-dimensional aluminosilicate zeolite or a heteropolyacid, and a promoter of Formula I C.sub.nH.sub.(2n+1)CO.sub.2CH.sub.3 wherein n=1 to 11 or Formula II C.sub.mH.sub.2m(CO.sub.2CH.sub.3).sub.2 wherein m=2 to 7 and the molar ratio of promoter to methanol is maintained at less than 1.
Method for producing 2-furaldehyde
An object of the present invention is to provide a method for suppressing the corrosion of a reactor and reducing waste in the production of 2-furaldehyde from a sugar raw material containing a hexose as a constituent component, and another object of the invention is to provide an industrially advantageous method for producing 2-furaldehyde, which suppresses a decrease in the activity of a catalyst in a case of using an acid catalyst and provides a higher yield. The present invention relates to a method for producing 2-furaldehyde comprising heating a sugar raw material containing a hexose as a constituent component in an aprotic polar solvent in the presence of a solid acid catalyst.