B01J23/34

Mixed metal oxide catalyst useful for paraffin dehydrogenation

The invention relates to a catalyst composition suitable for the dehydrogenation of paraffins having 2-8 carbon atoms comprising zinc oxide and titanium dioxide, optionally further comprising oxides of cerium (Ce), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), lanthanum (La), neodymium (Nd), praseodymium (Pr), samarium (Sm), terbium (Tb), ytterbium (Yb), yttrium (Y), tungsten (W) and Zirconium (Zr) or mixtures thereof, wherein said catalyst composition is substantially free of chromium and platinum. The catalysts possess unique combinations of activity, selectivity, and stability. Methods for preparing improved dehydrogenation catalysts and a process for dehydrogenating paraffins having 2-8 carbon atoms, comprising contacting the mixed metal oxide catalyst with paraffins are also described. The catalyst may also be disposed on a porous support in an attrition-resistant form and used in a fluidized bed reactor.

Mixed metal oxide catalyst useful for paraffin dehydrogenation

The invention relates to a catalyst composition suitable for the dehydrogenation of paraffins having 2-8 carbon atoms comprising zinc oxide and titanium dioxide, optionally further comprising oxides of cerium (Ce), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), lanthanum (La), neodymium (Nd), praseodymium (Pr), samarium (Sm), terbium (Tb), ytterbium (Yb), yttrium (Y), tungsten (W) and Zirconium (Zr) or mixtures thereof, wherein said catalyst composition is substantially free of chromium and platinum. The catalysts possess unique combinations of activity, selectivity, and stability. Methods for preparing improved dehydrogenation catalysts and a process for dehydrogenating paraffins having 2-8 carbon atoms, comprising contacting the mixed metal oxide catalyst with paraffins are also described. The catalyst may also be disposed on a porous support in an attrition-resistant form and used in a fluidized bed reactor.

METHOD FOR MANUFACTURING LITHIUM ION BATTERIES
20230131454 · 2023-04-27 ·

A method for manufacturing a lithium ion battery with a capacitance greater than 1 mA h, including the deposition of at least one dense layer, which can be an anode and/or a cathode and/or an electrolyte, by a method of depositing a dense layer. The method includes: supplying a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer on the substrate using the suspension; drying the layer thus obtained; densifying the dried layer by mechanical compression and/or heat treatment. The method of depositing being characterised in that the suspension of non-agglomerated nanoparticles of material P includes nanoparticles of material P having a size distribution, said size being characterised by the value of D50 thereof, such that: the distribution includes nanoparticles of material P of a first size D1 between 20 nm and 50 nm, and nanoparticles of material P of a second size D2 characterised by a value D50 at least five times less than that of D1, or the distribution has a mean size of nanoparticles of material P less than 50 nm, and a standard deviation to mean size ratio greater than 0.6.

APPARATUS FOR INACTIVATION OF AIRBORNE PATHOGENS

An apparatus and method for inactivation of airborne pathogens to include a reactor space with an intake opening, an exhaust opening, and an airflow path disposed between the intake and exhaust openings for air to continuously transit throughout the reactor space. The apparatus also includes at least one of (i) a corona discharge unit with a pressure swing adsorption unit, or (ii) a UV-C germicidal lamp to generate a sufficient concentration of ozone and UV light to inactive pathogens. The apparatus also includes a catalyst disposed within the path of the airflow to convert ozone to oxygen following the inactivation step and an adsorbent to remove nitrogen oxides from the air. The apparatus also includes sensors for measuring ozone and nitrogen oxides concentrations at the exhaust opening.

APPARATUS FOR INACTIVATION OF AIRBORNE PATHOGENS

An apparatus and method for inactivation of airborne pathogens to include a reactor space with an intake opening, an exhaust opening, and an airflow path disposed between the intake and exhaust openings for air to continuously transit throughout the reactor space. The apparatus also includes at least one of (i) a corona discharge unit with a pressure swing adsorption unit, or (ii) a UV-C germicidal lamp to generate a sufficient concentration of ozone and UV light to inactive pathogens. The apparatus also includes a catalyst disposed within the path of the airflow to convert ozone to oxygen following the inactivation step and an adsorbent to remove nitrogen oxides from the air. The apparatus also includes sensors for measuring ozone and nitrogen oxides concentrations at the exhaust opening.

Composition

A composition consisting essentially of a perovskite crystalline structure includes ions of a first metal M1 which occupies an A-site of the perovskite crystalline structure and ions of a second metal M2 which occupies a B-site of the perovskite crystalline structure. M2 has two oxidation states capable of forming a redox couple suitable for reversibly catalyzing an oxygen reduction reaction (ORR) and an oxygen evolution reaction (OER). The composition also includes ions of a third metal M3 at least a portion of which substitutes for M1 in the A-site of the perovskite crystalline structure, and at least a portion of which optionally also substitutes for M2 in the B-site of the perovskite crystalline structure. At least some of the ions of M3 have a different oxidation state to the ions of M1. The composition also includes atoms of an element X, which is a chalcogen.

Exhaust gas purging composition

A composition for exhaust gas purification containing Y—Mn—O and Al.sub.2O.sub.3 and having a specific surface area (SSA) retention satisfying inequality (1) SSA retention (%) >−61.54×(Y—Mn—O ratio)+75.55 and inequality (2) SSA retention (%) >45 (2), where SSA retention is represented by (SSA after aging)/(initial SSA)×100 (%). The SSA after aging and the initial SSA are as defined in the description. The Y—Mn—O ratio is a mass ratio of Y—Mn—O to the sum of Y—Mn—O and Al.sub.2O.sub.3 in the composition for exhaust gas purification, being represented by Y—Mn—O/(Y—Mn—O+Al.sub.2O.sub.3).

Exhaust gas purging composition

A composition for exhaust gas purification containing Y—Mn—O and Al.sub.2O.sub.3 and having a specific surface area (SSA) retention satisfying inequality (1) SSA retention (%) >−61.54×(Y—Mn—O ratio)+75.55 and inequality (2) SSA retention (%) >45 (2), where SSA retention is represented by (SSA after aging)/(initial SSA)×100 (%). The SSA after aging and the initial SSA are as defined in the description. The Y—Mn—O ratio is a mass ratio of Y—Mn—O to the sum of Y—Mn—O and Al.sub.2O.sub.3 in the composition for exhaust gas purification, being represented by Y—Mn—O/(Y—Mn—O+Al.sub.2O.sub.3).

Molten salt catalytic compositions and methods for the cracking of carbon-containing feedstocks

A catalyst composition includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for the catalytic cracking of hydrocarbons includes contacting in a reactor system a carbon-containing feedstock with at least one catalyst in the presence of oxygen to generate olefinic and/or aromatic compounds; and collecting the olefinic and/or aromatic compounds; wherein: the at least one catalyst includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for preparing the catalyst includes mixing metal catalyst precursors selected from transition metal compounds and rare-earth metal compounds and a eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides and heating it. A use of the catalyst in the catalytic cracking process of hydrocarbons.

Apparatus for inactivation of airborne pathogens

An apparatus and method for inactivation of airborne pathogens to include a reactor space with an intake opening, an exhaust opening, and an airflow path disposed between the intake and exhaust openings for air to continuously transit throughout the reactor space. The apparatus also includes at least one of (i) a corona discharge unit with a pressure swing adsorption unit, or (ii) a UV-C germicidal lamp to generate a sufficient concentration of ozone and UV light to inactive pathogens. The apparatus also includes a catalyst disposed within the path of the airflow to convert ozone to oxygen following the inactivation step and an adsorbent to remove nitrogen oxides from the air. The apparatus also includes sensors for measuring ozone and nitrogen oxides concentrations at the exhaust opening.