The present invention relates to a method of producing adipic acid, including a step (hydrogenation step) of reacting 3-hydroxyadipic acid-3,6-lactone with hydrogen in an aqueous solvent in a presence of a hydrogenation catalyst. The hydrogenation catalyst preferably includes one kind or two or more kinds of transition metal elements selected from the group consisting of palladium, platinum, ruthenium, rhodium, rhenium, nickel, cobalt, iron, iridium, osmium, copper, and chromium.

The present invention relates to a method of producing adipic acid, including a step (hydrogenation step) of reacting 3-hydroxyadipic acid-3,6-lactone with hydrogen in an aqueous solvent in a presence of a hydrogenation catalyst. The hydrogenation catalyst preferably includes one kind or two or more kinds of transition metal elements selected from the group consisting of palladium, platinum, ruthenium, rhodium, rhenium, nickel, cobalt, iron, iridium, osmium, copper, and chromium.

Supported catalyst for use in a process for the synthesis of methanol, characterized in that the supported catalyst comprises indium oxide in the form of In.sub.2O.sub.3 and at least one noble metal being palladium, Pd, wherein both indium oxide and at least one noble metal are deposited on a support remarkable in that the supported catalyst is a calcined supported catalyst comprising from 0.01 to 10.0 wt. % of palladium and zirconium dioxide (ZrO.sub.2) in an amount of at least 50 wt. % on the total weight of said supported catalyst.

Supported catalyst for use in a process for the synthesis of methanol, characterized in that the supported catalyst comprises indium oxide in the form of In.sub.2O.sub.3 and at least one noble metal being palladium, Pd, wherein both indium oxide and at least one noble metal are deposited on a support remarkable in that the supported catalyst is a calcined supported catalyst comprising from 0.01 to 10.0 wt. % of palladium and zirconium dioxide (ZrO.sub.2) in an amount of at least 50 wt. % on the total weight of said supported catalyst.

The invention provides an oxygen storage material having high oxygen storage capacity and high thermal durability. The oxygen storage material of the invention has some of the La sites of La.sub.2CuO.sub.4 with a K.sub.2NiF.sub.4-type crystal structure replaced by Ce. The oxygen storage material may have the composition La.sub.(2.00-x)Ce.sub.xCuO.sub.4 (0.20≥×>0.00). The oxygen storage material may also have a precious metal supported. The precious metal may be Pt, Pd or Rh. The exhaust gas purification catalyst is an exhaust gas purification catalyst comprising an oxygen storage material according to the invention.

The invention provides an oxygen storage material having high oxygen storage capacity and high thermal durability. The oxygen storage material of the invention has some of the La sites of La.sub.2CuO.sub.4 with a K.sub.2NiF.sub.4-type crystal structure replaced by Ce. The oxygen storage material may have the composition La.sub.(2.00-x)Ce.sub.xCuO.sub.4 (0.20≥×>0.00). The oxygen storage material may also have a precious metal supported. The precious metal may be Pt, Pd or Rh. The exhaust gas purification catalyst is an exhaust gas purification catalyst comprising an oxygen storage material according to the invention.

A spray pyrolysis system and method are described for manufacture of mixed metal oxide compositions, e.g., mixed metal oxide catalyst compositions having utility for gas processing applications such as hydrogenation, dehydrogenation, reduction, and oxidation. Mixed metal oxide automotive exhaust catalyst compositions produced by such system and method achieve a substantial reduction in temperatures required for removal of automotive exhaust pollutant species, as compared to catalyst produced by conventional batch precipitation techniques. The spray pyrolysis system and method enable catalytic metal(s) to be integrally incorporated in the mixed metal oxide composition, thereby obviating a separate catalytic metal impregnation operation.

The present disclosure provides a preparation method of a monometallic or bimetallic nanoparticle-supported catalyst. The synthesis of metal nanoparticles with different shapes, sizes, and atomic structures is affected by nucleation and growth rates. In the present disclosure, by changing a ratio of strong and weak reducing agents, a suitable double reducing agent is provided for metal nanoparticles with different reduction potentials, where the strong reducing agent is used for rapid nucleation and the weak reducing agent is used for the growth of metal nanoparticles. Accordingly, modulation and control of the nucleation and growth rates can be realized during the synthesis of nanoparticles. In addition, through multiple actions of a combination of reducing agents with different reduction intensities, monometallic/bimetallic nanoparticles of different sizes, shapes, and atomic structures are controllably prepared, which are then supported with a carrier to obtain the monometallic or bimetallic nanoparticle-supported catalyst.

The present disclosure provides a preparation method of a monometallic or bimetallic nanoparticle-supported catalyst. The synthesis of metal nanoparticles with different shapes, sizes, and atomic structures is affected by nucleation and growth rates. In the present disclosure, by changing a ratio of strong and weak reducing agents, a suitable double reducing agent is provided for metal nanoparticles with different reduction potentials, where the strong reducing agent is used for rapid nucleation and the weak reducing agent is used for the growth of metal nanoparticles. Accordingly, modulation and control of the nucleation and growth rates can be realized during the synthesis of nanoparticles. In addition, through multiple actions of a combination of reducing agents with different reduction intensities, monometallic/bimetallic nanoparticles of different sizes, shapes, and atomic structures are controllably prepared, which are then supported with a carrier to obtain the monometallic or bimetallic nanoparticle-supported catalyst.

A method of manufacturing a catalyst intermediate is provided. The method comprises: providing a slurry comprising a hydrous oxide of one or more of aluminium, cerium and zirconium; and contacting the slurry comprising a hydrous oxide with platinum group metal (PGM) ions to provide a PGM-containing slurry.