Patent classifications
B01J23/50
METHOD OF VISIBLE-LIGHT PHOTOCATALYSIS COMBINED WITH CLO2 OXIDATION FOR HIGHLY EFFICIENT REMOVAL OF ORGANIC POLLUTANTS IN WASTEWATER
A method of visible-light photocatalysis combined with ClO.sub.2 oxidation for high efficient removal of organic pollutants in the wastewater, includes that i) the pH of the organic wastewater is adjusted to a constant value; the visible light photocatalysts are added to wastewater with full stirring to reach the adsorption equilibrium; (ii) turning on the Xenon lamp and adjust the distance between the light source and the liquid surface; chlorite is added to the system to reach a concentration and the reaction remained at a constant temperature with adequate stirring to achieve the degradation of organic pollutants.
Hydraulic muscle from hollow wrapped carbon nanotube yarn
A hydraulic muscle comprises a hollow carbon nanotube (CNT) yarn tube comprising: a plurality of CNT sheets twisted and wrapped in form of a hollow tube; and a binding agent infiltrated in the plurality of CNT sheets that binds the plurality of the CNT sheets together. A method of manufacturing a hydraulic muscle comprises: twisting and wrapping a plurality of carbon nanotube (CNT) sheets around a core fiber; infiltrating a binding agent in between the plurality of CNT sheets, wherein the binding agent binds the plurality of the CNT sheets together; and removing the core fiber from the plurality of CNT sheets.
Hydraulic muscle from hollow wrapped carbon nanotube yarn
A hydraulic muscle comprises a hollow carbon nanotube (CNT) yarn tube comprising: a plurality of CNT sheets twisted and wrapped in form of a hollow tube; and a binding agent infiltrated in the plurality of CNT sheets that binds the plurality of the CNT sheets together. A method of manufacturing a hydraulic muscle comprises: twisting and wrapping a plurality of carbon nanotube (CNT) sheets around a core fiber; infiltrating a binding agent in between the plurality of CNT sheets, wherein the binding agent binds the plurality of the CNT sheets together; and removing the core fiber from the plurality of CNT sheets.
Catalyst supports—composition and process of manufacture
A catalyst support comprising at least 95% silicon carbide, having surface areas of ≤10 m.sup.2/g and pore volumes of ≤1 cc/g. A method of producing a catalyst support, the method including mixing SiC particles of 0.1-20 microns, SiO.sub.2 and carbonaceous materials to form an extrusion, under inert atmospheres, heating the extrusion at temperatures of greater than 1400° C., and removing residual carbon from the heated support under temperatures below 1000° C. A catalyst on a carrier, comprising a carrier support having at least about 95% SiC, with a silver solution impregnated thereon comprising silver oxide, ethylenediamine, oxalic acid, monoethanolamine and cesium hydroxide. A process for oxidation reactions (e.g., for the production of ethylene oxide, or oxidation reactions using propane or methane), or for endothermic reactions (e.g., dehydrogenation of paraffins, of ethyl benzene, or cracking and hydrocracking hydrocarbons).
Catalyst supports—composition and process of manufacture
A catalyst support comprising at least 95% silicon carbide, having surface areas of ≤10 m.sup.2/g and pore volumes of ≤1 cc/g. A method of producing a catalyst support, the method including mixing SiC particles of 0.1-20 microns, SiO.sub.2 and carbonaceous materials to form an extrusion, under inert atmospheres, heating the extrusion at temperatures of greater than 1400° C., and removing residual carbon from the heated support under temperatures below 1000° C. A catalyst on a carrier, comprising a carrier support having at least about 95% SiC, with a silver solution impregnated thereon comprising silver oxide, ethylenediamine, oxalic acid, monoethanolamine and cesium hydroxide. A process for oxidation reactions (e.g., for the production of ethylene oxide, or oxidation reactions using propane or methane), or for endothermic reactions (e.g., dehydrogenation of paraffins, of ethyl benzene, or cracking and hydrocracking hydrocarbons).
Selective hydrogenation methods
The present disclosure relates to methods for selectively hydrogenating acetylene, to methods for starting up a selective hydrogenation reactor, and to hydrogenation catalysts useful in such methods. In one aspect, the disclosure provides a method for selectively hydrogenating acetylene, the method comprising contacting a catalyst composition with a process gas. The catalyst composition comprises a porous support, palladium, and one or more ionic liquids. The process gas includes ethylene, present in the process gas in an amount of at least 20 mol. %; acetylene, present in the process gas in an amount of at least 1 ppm; and 0 to 190 ppm or at least 600 ppm carbon monoxide. At least 90% of the acetylene present in the process gas is hydrogenated, and the selective hydrogenation is conducted without thermal runaway.
Selective hydrogenation methods
The present disclosure relates to methods for selectively hydrogenating acetylene, to methods for starting up a selective hydrogenation reactor, and to hydrogenation catalysts useful in such methods. In one aspect, the disclosure provides a method for selectively hydrogenating acetylene, the method comprising contacting a catalyst composition with a process gas. The catalyst composition comprises a porous support, palladium, and one or more ionic liquids. The process gas includes ethylene, present in the process gas in an amount of at least 20 mol. %; acetylene, present in the process gas in an amount of at least 1 ppm; and 0 to 190 ppm or at least 600 ppm carbon monoxide. At least 90% of the acetylene present in the process gas is hydrogenated, and the selective hydrogenation is conducted without thermal runaway.
Process for preparing a pre-reforming catalyst having resistance to deactivation by passage of steam in the absence of a reducing agent, and a pre-reforming catalyst
The present invention relates to a process for preparing a pre-reforming catalyst having resistance to deactivation by passage of steam in the absence of a reducing agent comprising ruthenium and an alumina support. Furthermore, the Ru/alumina catalyst according to the present invention becomes much more resistant to deposition of coke with the addition of Ag.
Process for preparing a pre-reforming catalyst having resistance to deactivation by passage of steam in the absence of a reducing agent, and a pre-reforming catalyst
The present invention relates to a process for preparing a pre-reforming catalyst having resistance to deactivation by passage of steam in the absence of a reducing agent comprising ruthenium and an alumina support. Furthermore, the Ru/alumina catalyst according to the present invention becomes much more resistant to deposition of coke with the addition of Ag.
Composite body having nanoparticles uniformly dispersed in nano-sized pores in support, and method for producing same
Provided are a composite in which metal nanoparticles are evenly dispersed and adsorbed to pores of a support, and a method of preparing the same. An amorphous nanostructure formed of inorganic polymers having a transition metal and a halogen element as a main chain via hydrogen bonding is used as a chemical template for forming the metal nanoparticles. The formed metal nanoparticles are evenly dispersed and adsorbed to the support with pores.