Provided is a photocatalytic composition comprising zinc (Zn) doped titanium dioxide (TiO.sub.2) nanoparticles, wherein the ratio of titanium dioxide nanoparticles to zinc is from about 5 to about 150. The photocatalytic composition absorbs electromagnetic radiation in a wavelength range from about 200 nm to about 500 nm, and the absorbance of light of wavelengths longer than about 450 nm is less than 50% the absorbance of light of wavelengths shorter than about 350 nm.

A core-shell nanoparticle is provided that includes a core comprising a first isotope of an element; an isolation layer surrounding the core; and a shell layer surrounding the isolation layer, wherein the shell layer comprises a second isotope of the element, with the first isotope being different than the second isotope. Methods are also provided for forming such core-shell nanoparticles.

A core-shell nanoparticle is provided that includes a core comprising a first isotope of an element; an isolation layer surrounding the core; and a shell layer surrounding the isolation layer, wherein the shell layer comprises a second isotope of the element, with the first isotope being different than the second isotope. Methods are also provided for forming such core-shell nanoparticles.

Photocatalysts and methods of using photocatalysts for producing hydrogen and oxygen from water are disclosed. The photocatalysts include an iodide modified photoactive material having an electrically conductive material attached to the iodide ions.

A refrigerator includes a main body having a storage room formed therein, a door that opens and closes the storage room, a filter module, and a cool air circulation fan that circulates cool air through the filter module. The filter module includes a metal photocatalyst filter and a UV LED module for radiating UV rays to the metal photocatalyst filter. The metal photocatalyst filter has photocatalysts made of one of ZnTiO.sub.2, CuTiO.sub.2, AgTiO.sub.2 or FeTiO.sub.2 coated on a filter base. The filter module may allow the entire storage room to be uniformly subject to antibiosis and sterilization at a relatively low cost.

A refrigerator includes a main body having a storage room formed therein, a door that opens and closes the storage room, a filter module, and a cool air circulation fan that circulates cool air through the filter module. The filter module includes a metal photocatalyst filter and a UV LED module for radiating UV rays to the metal photocatalyst filter. The metal photocatalyst filter has photocatalysts made of one of ZnTiO.sub.2, CuTiO.sub.2, AgTiO.sub.2 or FeTiO.sub.2 coated on a filter base. The filter module may allow the entire storage room to be uniformly subject to antibiosis and sterilization at a relatively low cost.

A photocatalytic composition is disclosed that includes a silver halide in combination with one or more rare earth elements. The composition may be used for the photocatalytic degradation of pollutants.

The present invention relates to a photocatalyst device obtained by thin film making on solid surfaces, wherein the device comprises of titania, optionally in the form of composite with noble or transition metal(s) or metal oxides. This device (FIG. 1) is evaluated in direct sunlight for hydrogen generation (FIG. 4) and oxidation of alcohols (Table 3) using aqueous alcohol solution through water splitting and simultaneously oxidizing alcohol to oxygenated products.

The present invention relates to a photocatalyst device obtained by thin film making on solid surfaces, wherein the device comprises of titania, optionally in the form of composite with noble or transition metal(s) or metal oxides. This device (FIG. 1) is evaluated in direct sunlight for hydrogen generation (FIG. 4) and oxidation of alcohols (Table 3) using aqueous alcohol solution through water splitting and simultaneously oxidizing alcohol to oxygenated products.

The present invention relates to a method for producing graphene on a face-centered cubic metal catalyst having a plane oriented in one direction, and more particularly to a method of producing graphene on a metal catalyst having the (100) or (111) crystal structure and a method of producing graphene using a catalyst metal foil having a single orientation, obtained by electroplating a metal catalyst by a pulse wave current and annealing the metal catalyst. The invention also relates to a method of producing graphene using a metal catalyst, and more particularly to a method of producing graphene, comprising the steps of: alloying a metal catalyst with an alloying element; forming step structures on the metal catalyst substrate in an atmosphere of a gas having a molecular weight of carbon; and supplying hydrocarbon and hydrogen gases to the substrate. On unidirectionally oriented metal catalyst prepared according to the present invention, graphene can be grown uniformly and epitaxially. Moreover, a method for producing graphene according to the present invention can form monolayer graphene by epitaxially growing graphene while increasing the growth rate of graphene.