A filtration article comprises inorganic deposits at inlet sides of porous ceramic base portions of a filter body; and a catalytic material, disposed at outlet sides of porous ceramic base portions of walls. Interposing regions are located between wall inlet sides and outlet sides. A majority or all of the inorganic deposits are spaced away from a majority of the catalytic material by interposing regions. Also a method comprising applying catalytic material at outlet sides such that a desired amount is disposed on, in, or on and in the walls, without catalytic material reaching inlet sides to yield a catalytically dense region, and exposing the filter body to a surface treatment to deposit inorganic deposits at inlet sides to yield an inorganic deposit region, wherein a majority of the catalytic material is spaced away from a majority or all inorganic deposits at a given axial location by interposing regions.

A filtration article comprises inorganic deposits at inlet sides of porous ceramic base portions of a filter body; and a catalytic material, disposed at outlet sides of porous ceramic base portions of walls. Interposing regions are located between wall inlet sides and outlet sides. A majority or all of the inorganic deposits are spaced away from a majority of the catalytic material by interposing regions. Also a method comprising applying catalytic material at outlet sides such that a desired amount is disposed on, in, or on and in the walls, without catalytic material reaching inlet sides to yield a catalytically dense region, and exposing the filter body to a surface treatment to deposit inorganic deposits at inlet sides to yield an inorganic deposit region, wherein a majority of the catalytic material is spaced away from a majority or all inorganic deposits at a given axial location by interposing regions.

The present invention provides a catalyst defined in part by a conductive substrate; a film overlaying a surface of the substrate; and a plurality of metal clusters supported by the layer, wherein each cluster comprises between 8 and 11 atoms. Further provided is a catalyst defined in part by a conductive substrate; a layer overlaying a surface of the substrate; and a plurality of metal clusters supported by the layer, wherein each cluster comprises at least two metals.

A composite photocatalyst, a manufacturing method thereof, the kits including the composite photocatalyst, and a bactericide photocatalyst. A composite photocatalyst includes photocatalyst nanocrystals and platinum nanocrystals. The photocatalyst nanocrystals include a compound represented by the following chemical formula (1):
A.sup.2+(B.sup.3+).sub.2X.sub.4chemical formula (1), wherein A.sup.2+ represents Zn.sup.2+, Cu.sup.2+, Fe.sup.2+, Mn.sup.2+, Ni.sup.2+, Co.sup.2+ or Ag.sub.2.sup.2+; B.sup.3+ represents Fe.sup.3+, Mn.sup.3+ or Cr.sup.3+; and X represents O.sup.2.

An exhaust emission control apparatus for an engine includes an ECU. The ECU is configured to: execute particulate matter removal control by controlling the engine such that a temperature of a particulate filter is increased to a predetermined PM removal temperature in order to reduce an amount of particulate matter collected in the particulate filter; and when the ECU determines that the amount of particulate matter collected in the particulate filter is smaller than or equal to a predetermined set collection amount, execute ash desorption control by controlling the engine such that the temperature of the particulate filter is increased to a predetermined ash desorption temperature and is kept at the ash desorption temperature or higher in order to reduce an amount of ash deposited in the particulate filter. The ash desorption temperature is a temperature suitable for converting the ash into calcium oxide.

A method for making a high activity ortho-para hydrogen conversion catalyst is set forth wherein a solution of ruthenium cation is mixed with a solution of a poorly coordinating anion such as aluminate to form a precipitate and the precipitate-containing solution is adjusted to a pH of 7 before recovering the catalyst. A product of this process and a method of using such product is disclosed.

A catalyst for catalytic reactors of which the outer shape is a helix with n blades, where n is greater than or equal to 1, wherein the stack void fraction percentage is between 75% and 85% and the surface area/volume ratio is greater than 1000 square meters/square meters.

The present invention relates to a process for preparing a catalyst, at least comprising the steps of adding a protecting agent to an aqueous solution of a metal precursor to give a mixture (M1), adding a reducing agent to mixture (M1) to give a mixture (M2), adding a support material to mixture (M2) to give a mixture (M3), adjusting the pH of mixture (M3), and separating the solid and liquid phase of mixture (M3). Furthermore, the present invention relates to the catalyst as such and its use as diesel oxidation catalyst.

There is provided a technique that suppresses a variation in particle diameter of a metal catalyst in the process of supporting the metal catalyst on a carrier. A CNT substrate having carbon nanotubes (CNTs) as the carrier arrayed thereon is placed in a processing chamber. Carbon dioxide is supplied to the processing chamber. After the carbon dioxide in the processing chamber is made supercritical, a complex solution in which a platinum complex is dissolved is supplied to the processing chamber. A sample temperature denoting temperature of the CNTs is controlled to be higher than an ambient temperature in the processing chamber. The CNT substrate is heated, such that a temperature difference between the ambient temperature and the sample temperature repeats increasing and decreasing. After the state of the supercritical fluid is changed to a non-supercritical state, the CNT substrate is heated, so as to cause the metal catalyst to deposit on the surface of the CNTs.

There is provided a technique that suppresses a variation in particle diameter of a metal catalyst in the process of supporting the metal catalyst on a carrier. A CNT substrate having carbon nanotubes (CNTs) as the carrier arrayed thereon is placed in a processing chamber. Carbon dioxide is supplied to the processing chamber. After the carbon dioxide in the processing chamber is made supercritical, a complex solution in which a platinum complex is dissolved is supplied to the processing chamber. A sample temperature denoting temperature of the CNTs is controlled to be higher than an ambient temperature in the processing chamber. The CNT substrate is heated, such that a temperature difference between the ambient temperature and the sample temperature repeats increasing and decreasing. After the state of the supercritical fluid is changed to a non-supercritical state, the CNT substrate is heated, so as to cause the metal catalyst to deposit on the surface of the CNTs.