Provided herein are methods of preparing tetrahexahedra nanoparticles and methods of using the tetrahexahedra nanoparticles as an oxidative catalyst.

A system for determining isotopic composition of a gaseous sample. The system includes at least one gas chromatograph for separating the gaseous sample into gaseous components. Furthermore, the system includes a combustion furnace operatively coupled with the at least one gas chromatograph for oxidizing the gaseous components. Moreover, the system includes a water separator operatively coupled with the combustion furnace. Furthermore, the system includes an isotope-ratio mass spectrometer operatively coupled with the water separator. Moreover, the isotope-ratio mass spectrometer comprises an ion source for generating ion beams associated with each of the oxidized gaseous components and a mass analyser for receiving the generated ion beams from the ion source, wherein the mass analyser is operable to determine isotopic concentrations associated with each of the ion beams. Furthermore, the isotope-ratio mass spectrometer is operable to use the determined isotopic concentrations to determine the isotopic composition of the gaseous sample.

A method of coating an end surface of a monolithic substrate with a liquid is described and an apparatus therefor. The method comprises: (a) conveying a monolithic substrate to or toward a coating roller; and (b) applying a liquid onto an end surface of the monolithic substrate by contacting the end surface with the coating roller loaded with the liquid.

A method of coating an end surface of a monolithic substrate with a liquid is described and an apparatus therefor. The method comprises: (a) conveying a monolithic substrate to or toward a coating roller; and (b) applying a liquid onto an end surface of the monolithic substrate by contacting the end surface with the coating roller loaded with the liquid.

A honeycomb filter includes a pillar-shaped honeycomb structure body having a porous partition wall disposed to surround a plurality of cells and a plugging portion. The partition wall defining outflow cells includes an exhaust-gas purifying catalyst at least at a part of a region of 0 to 80% of a thickness of the partition wall and includes a portion that does not include the exhaust-gas purifying catalyst in a region of exceeding 80% and being 100% or less of the thickness of the partition wall, and the partition wall defining the inflow cells is not loaded with the exhaust-gas purifying catalyst on the surface, or is loaded with the exhaust-gas purifying catalyst so that a percentage of a ratio of an area of a range loaded with the exhaust-gas purifying catalyst to a surface area of the partition wall defining the inflow cells is 10% or less.

A supported catalyst used for synthesizing a polyether amine, and a manufacturing method of the catalyst. The catalyst comprises: a porous oxide as a support; Ni, Cu, Pd, and Rh as active components; and one or more of any of Zr, Cr, Mo, Fe, Zn, Sn, Bi, Ce, La, Hf, Sr, Sb, Mg, Be, Re, Ta, Ti, Sc, Ge and related metals as an auxiliary agent. The catalyst can be used in an amination reaction for a large molecular weight polyether polyol, and is particularly active and selective for an amination reaction of a low molecular weight polyether polyol. The catalyst has a simple and economic manufacturing technique and good potential for future applications.

A supported catalyst used for synthesizing a polyether amine, and a manufacturing method of the catalyst. The catalyst comprises: a porous oxide as a support; Ni, Cu, Pd, and Rh as active components; and one or more of any of Zr, Cr, Mo, Fe, Zn, Sn, Bi, Ce, La, Hf, Sr, Sb, Mg, Be, Re, Ta, Ti, Sc, Ge and related metals as an auxiliary agent. The catalyst can be used in an amination reaction for a large molecular weight polyether polyol, and is particularly active and selective for an amination reaction of a low molecular weight polyether polyol. The catalyst has a simple and economic manufacturing technique and good potential for future applications.

A method of operating a fuel cell having an anode, a cathode and a polymer electrolyte membrane disposed between the anode and the cathode, includes feeding the anode with an impure hydrogen stream having low levels of carbon monoxide up to 5 ppm, and wherein the anode includes an anode catalyst layer including a carbon monoxide tolerant catalyst material, wherein the catalyst material includes: (i) a binary alloy of PtX, wherein X is a metal selected from the group consisting of rhodium and osmium, and wherein the atomic percentage of platinum in the alloy is from 45 to 80 atomic % and the atomic percentage of X in the alloy is from 20 to 55 atomic %; and (ii) a support material on which the PtX alloy is dispersed; wherein the total loading of platinum group metals (PGM) in the anode catalyst layer is from 0.01 to 0.2 mgPGM/cm.sup.2.

The present invention relates to diesel oxidation catalyst compositions and catalyst articles, wherein the compositions and articles include a plurality of platinum group nanoparticles substantially in fully reduced form, wherein the nanoparticles have an average particle size of about 1 to about 10 nm and at least about 90% of the nanoparticles have a particle size of +/− about 2 nm of the average particle size. Such compositions can further include a refractory metal oxide material, wherein the nanoparticles and refractory metal oxide material can be combined within the same coating on a substrate or can be applied sequentially on a substrate. The nanoparticles can advantageously be substantially free of halides, alkali metals, alkaline earth metals, sulfur compounds, and boron compounds. Methods of preparing and using such compositions and catalyst articles (e.g., for the treatment of diesel exhaust gas streams) are also provided herein.

A catalyst composition and its use as a dehydrogenation catalyst to increase normal olefin selectivity and reduce undesirable aromatic selectivity. The reduction in aromatic production allows for the elimination of a unit to remove aromatic compounds. The catalyst has a layered composition comprising an inner core, an outer layer bonded to the inner core, the outer layer comprising one or more transition alumina with at least two diffraction angle peaks between 32.0 and 70.0 2, wherein a first diffraction angle peak in that range is at 32.70.4 2, a second diffraction angle peak is at 50.80.4 2, and having a thickness of less than about 100 microns and having uniformly dispersed thereon said platinum catalyst and at least one promoter metal and having a concentration of the platinum catalyst of from about 0.00006 to 0.0005 gram of the platinum group metal on an elemental basis per meter square surface area of the outer layer.