B01J23/745

PLANT LEAVES-DERIVED CARBON MATERIAL DOPED WITH TWO METALS AND PREPARATION AND USE THEREOF
20230069145 · 2023-03-02 ·

A plant leaves-derived carbon material doped with two metals and preparation and use thereof are provided, the carbon material prepared by carbonizing, in an inert atmosphere, plant leaves which have absorbed ions of two metals M1 and M2. The metal M1 is Co, Mn, or Fe. The metal M2 is Ni, Cu, or Zn. The carbon material can be used as an efficient, green, and safe catalyst for the selective oxidation of cycloalkanes to produce cycloalkanols and cycloalkanones, and enable an increased selectivity of the target products (thus less by-products), a low yield of cycloalkyl peroxides, reduced reaction temperature, low environmental impact, and safe production.

PLANT LEAVES-DERIVED CARBON MATERIAL DOPED WITH TWO METALS AND PREPARATION AND USE THEREOF
20230069145 · 2023-03-02 ·

A plant leaves-derived carbon material doped with two metals and preparation and use thereof are provided, the carbon material prepared by carbonizing, in an inert atmosphere, plant leaves which have absorbed ions of two metals M1 and M2. The metal M1 is Co, Mn, or Fe. The metal M2 is Ni, Cu, or Zn. The carbon material can be used as an efficient, green, and safe catalyst for the selective oxidation of cycloalkanes to produce cycloalkanols and cycloalkanones, and enable an increased selectivity of the target products (thus less by-products), a low yield of cycloalkyl peroxides, reduced reaction temperature, low environmental impact, and safe production.

Morphologically controlled synthesis of ferric oxide nano/micro particles

A thermal method of forming ferric oxide nano/microparticles with predominant morphology is described using different solvents. Methods of using the Fe.sub.3O.sub.4 nano/microparticles as catalysts in the reduction of nitro compounds with sodium borohydride to the corresponding amines and decomposition of ammonium salts.

Morphologically controlled synthesis of ferric oxide nano/micro particles

A thermal method of forming ferric oxide nano/microparticles with predominant morphology is described using different solvents. Methods of using the Fe.sub.3O.sub.4 nano/microparticles as catalysts in the reduction of nitro compounds with sodium borohydride to the corresponding amines and decomposition of ammonium salts.

Single-atom catalyst for activation of persulfate to generate pure singlet oxygen as well as preparation method and application thereof

The present disclosure belongs to the field of single-atom catalytic degradation of refractory organic pollutants, and provides a single-atom catalyst for activation of persulfate to generate pure singlet oxygen (1O2) as well as a preparation method and an application thereof. The single-atom catalyst of the present disclosure includes supports and single iron atoms loaded on the support; the supports are graphitic carbon nitride nanosheets; the single iron atoms are bound to the supports in the form of a Fe—N4 coordination structure. The present disclosure employs graphitic carbon nitride nanosheets as the supports, so that the single iron atoms have a uniform surrounding environment and the persulfate is only converted into 1O2 when being activated; 1O2 has good selectivity and anti-interference ability, so the single-atom catalyst provided in the present disclosure may have excellent selectivity and anti-interference performance in the degradation of organic pollutants.

Single-atom catalyst for activation of persulfate to generate pure singlet oxygen as well as preparation method and application thereof

The present disclosure belongs to the field of single-atom catalytic degradation of refractory organic pollutants, and provides a single-atom catalyst for activation of persulfate to generate pure singlet oxygen (1O2) as well as a preparation method and an application thereof. The single-atom catalyst of the present disclosure includes supports and single iron atoms loaded on the support; the supports are graphitic carbon nitride nanosheets; the single iron atoms are bound to the supports in the form of a Fe—N4 coordination structure. The present disclosure employs graphitic carbon nitride nanosheets as the supports, so that the single iron atoms have a uniform surrounding environment and the persulfate is only converted into 1O2 when being activated; 1O2 has good selectivity and anti-interference ability, so the single-atom catalyst provided in the present disclosure may have excellent selectivity and anti-interference performance in the degradation of organic pollutants.

Multimetallic catalysts for methanation of carbon dioxide and dry reforming of methane

Processes for forming multimetallic catalysts by grafting nickel precursors to metal oxide supports. Dry reforming reaction catalysts having nickel and promotors grafted to metal oxides supports. Methanation reaction catalysts having nickel and promotors grafted to metal oxides supports.

Multimetallic catalysts for methanation of carbon dioxide and dry reforming of methane

Processes for forming multimetallic catalysts by grafting nickel precursors to metal oxide supports. Dry reforming reaction catalysts having nickel and promotors grafted to metal oxides supports. Methanation reaction catalysts having nickel and promotors grafted to metal oxides supports.

Process for preparing a catalyst or a trapping mass from molten salts

Process for preparing a catalyst or a trapping mass comprising the following steps: bringing a porous oxide support into contact with a metal salt comprising at least one metal belonging to groups VIB, VIIB, VIIIB, IB or IIB, of which the melting point of said metal salt is between 20° C. and 150° C., for a period of between 5 minutes and 5 hours in order to form a solid mixture, the weight ratio of said metal salt to said porous oxide support being between 0.1 and 1; heating the solid mixture with stirring at a temperature between the melting point of said metal salt and 200° C. and for 5 minutes to 12 hours; calcining the solid obtained in the preceding step at a temperature above 200° C. and below or equal to 1100° C. under an inert atmosphere or under an oxygen-containing atmosphere.

Process for preparing a catalyst or a trapping mass from molten salts

Process for preparing a catalyst or a trapping mass comprising the following steps: bringing a porous oxide support into contact with a metal salt comprising at least one metal belonging to groups VIB, VIIB, VIIIB, IB or IIB, of which the melting point of said metal salt is between 20° C. and 150° C., for a period of between 5 minutes and 5 hours in order to form a solid mixture, the weight ratio of said metal salt to said porous oxide support being between 0.1 and 1; heating the solid mixture with stirring at a temperature between the melting point of said metal salt and 200° C. and for 5 minutes to 12 hours; calcining the solid obtained in the preceding step at a temperature above 200° C. and below or equal to 1100° C. under an inert atmosphere or under an oxygen-containing atmosphere.