A method of preparing a catalyst for oxidative dehydrogenation that includes coprecipitation and injecting inert gas or air at a specific time point to reduce the ratio of an inactive α-Fe.sub.2O.sub.3 crystal structure, thereby improving the activity of the catalyst. Also provided is a method of performing oxidative dehydrogenation using the catalyst. When oxidative dehydrogenation of butene is performed using the catalyst, side reaction may be reduced, and selectivity for butadiene may be improved, providing butadiene with high productivity.

A method of preparing a catalyst for oxidative dehydrogenation that includes coprecipitation and injecting inert gas or air at a specific time point to reduce the ratio of an inactive α-Fe.sub.2O.sub.3 crystal structure, thereby improving the activity of the catalyst. Also provided is a method of performing oxidative dehydrogenation using the catalyst. When oxidative dehydrogenation of butene is performed using the catalyst, side reaction may be reduced, and selectivity for butadiene may be improved, providing butadiene with high productivity.

The invention relates to a catalyst for preparation of butadiene by oxydehydrogenation of butene in a fluidized bed reactor, a method of preparing the same, and use of the same, wherein a method according to an embodiment of the invention comprises: reacting a metal precursor with an alkaline substance to obtain a slurry containing insoluble compound, followed by filtering and washing the slurry; adding a binder and deionized water, followed by agitation to regulate the solid content of the slurry to 10-50%; subjecting the slurry to spray drying granulation, wherein the temperature at the feed port is controlled between 200-400° C., and the temperature at the discharge port is controlled between 100-160° C., to obtain catalyst microspheres; and drying the catalyst microspheres at 80-200° C. for 1-24 h, and then calcining the catalyst microspheres at 500-900° C. for 4-24 h to obtain a catalyst having a general formula of FeXaYbZcOd, comprising Fe, Mg, Zn, Bi, Mo, Mn, Ni, Co, Ba, Ca, and other metals. The catalyst microspheres prepared according to the exemplary method exhibit high mobility, desirable particle size distribution, extremely high mechanical strength and catalytic activity, and are applicable to industrial production of butadiene by oxydehydrogenation of butene in a fluidized bed. When this catalyst is used to prepare butadiene by oxydehydrogenation of butene, the yield of butadiene is 76-86%, and the selectivity to butadiene is 94-97%.

The invention relates to a catalyst for preparation of butadiene by oxydehydrogenation of butene in a fluidized bed reactor, a method of preparing the same, and use of the same, wherein a method according to an embodiment of the invention comprises: reacting a metal precursor with an alkaline substance to obtain a slurry containing insoluble compound, followed by filtering and washing the slurry; adding a binder and deionized water, followed by agitation to regulate the solid content of the slurry to 10-50%; subjecting the slurry to spray drying granulation, wherein the temperature at the feed port is controlled between 200-400° C., and the temperature at the discharge port is controlled between 100-160° C., to obtain catalyst microspheres; and drying the catalyst microspheres at 80-200° C. for 1-24 h, and then calcining the catalyst microspheres at 500-900° C. for 4-24 h to obtain a catalyst having a general formula of FeXaYbZcOd, comprising Fe, Mg, Zn, Bi, Mo, Mn, Ni, Co, Ba, Ca, and other metals. The catalyst microspheres prepared according to the exemplary method exhibit high mobility, desirable particle size distribution, extremely high mechanical strength and catalytic activity, and are applicable to industrial production of butadiene by oxydehydrogenation of butene in a fluidized bed. When this catalyst is used to prepare butadiene by oxydehydrogenation of butene, the yield of butadiene is 76-86%, and the selectivity to butadiene is 94-97%.

A method for producing butadiene, the method including: a first synthesis step of bringing a mixed gas containing hydrogen and carbon monoxide into contact with a first catalyst to obtain a primary product containing ethanol as an intermediate; and a second synthesis step of bringing the primary product into contact with a second catalyst to obtain butadiene.

A method for producing butadiene, the method including: a first synthesis step of bringing a mixed gas containing hydrogen and carbon monoxide into contact with a first catalyst to obtain a primary product containing ethanol as an intermediate; and a second synthesis step of bringing the primary product into contact with a second catalyst to obtain butadiene.

Described is a process for producing 1-(4-isobutylphenyl)ethanol by reacting 1-(4-isobutyl-phenyl)ethanone with hydrogen in the presence of a catalyst composition comprising cop-per and one or more metals other than copper, and a use of a respective composition and/or of a pre-composition, the pre-composition comprising a mixture of oxides of copper and oxides of one or more metals other than copper, in a catalytic hydrogenation process for producing 1-(4-isobutylphenyl)ethanol from 1-(4-isobutylphenyl)ethanone.

Described is a process for producing 1-(4-isobutylphenyl)ethanol by reacting 1-(4-isobutyl-phenyl)ethanone with hydrogen in the presence of a catalyst composition comprising cop-per and one or more metals other than copper, and a use of a respective composition and/or of a pre-composition, the pre-composition comprising a mixture of oxides of copper and oxides of one or more metals other than copper, in a catalytic hydrogenation process for producing 1-(4-isobutylphenyl)ethanol from 1-(4-isobutylphenyl)ethanone.

The invention discloses a loaded multifunctional catalysis composite material, a preparation method thereof and an application of the composite material to catalytic removal of water pollutants. The preparation method includes the steps: preparing a zinc oxide nano-sheet loaded nickel foam (Ni@ZnO) composite material by an electro-deposition method; compounding molybdenum disulfide micro-nano particles on ZnO porous nano-sheets by an electro-deposition method to obtain Ni@ZnO/MoS.sub.2. The composite material Ni@ZnO/MoS.sub.2 combines the advantages of components such as nickel foam, the zinc oxide nano-sheets and molybdenum disulfide from the point of material performances, high catalytic degradation activity and recycled performances are achieved, photo-catalysis and electro-catalysis are combined from the point of material application, and the catalytic activity of the composite material is improved by the aid of synergistic effects of photo-catalysis and electro-catalysis.

The invention discloses a loaded multifunctional catalysis composite material, a preparation method thereof and an application of the composite material to catalytic removal of water pollutants. The preparation method includes the steps: preparing a zinc oxide nano-sheet loaded nickel foam (Ni@ZnO) composite material by an electro-deposition method; compounding molybdenum disulfide micro-nano particles on ZnO porous nano-sheets by an electro-deposition method to obtain Ni@ZnO/MoS.sub.2. The composite material Ni@ZnO/MoS.sub.2 combines the advantages of components such as nickel foam, the zinc oxide nano-sheets and molybdenum disulfide from the point of material performances, high catalytic degradation activity and recycled performances are achieved, photo-catalysis and electro-catalysis are combined from the point of material application, and the catalytic activity of the composite material is improved by the aid of synergistic effects of photo-catalysis and electro-catalysis.