Patent classifications
B01J23/80
CATALYTIC REACTOR SYSTEM AND CATALYST FOR CONVERSION OF CAPTURED C02 AND RENEWABLE H2 INTO LOW-CARBON SYNGAS
The present invention describes an improved catalytic reactor system with an improved catalyst that transforms CO.sub.2 and low carbon H.sub.2 into low-carbon syngas with greater than an 80% CO.sub.2 conversion efficiency, resulting in the reduction of plant capital and operating costs compared to processes described in the current art. The inside surface of the adiabatic catalytic reactors is lined with an insulating, non-reactive surface which does not react with the syngas and effect catalyst performance. The improved catalyst is robust, has a high CO.sub.2 conversion efficiency, and exhibits little or no degradation in performance over long periods of operation. The low-carbon syngas is used to produce low-carbon fuels (e.g., diesel fuel, jet fuel, gasoline, kerosene, others), chemicals, and other products resulting in a significant reduction in greenhouse gas emissions compared to fossil fuel derived products.
METHOD FOR PRODUCING GUERBET ALCOHOL
A method for producing a Guerbet alcohol, including reacting a raw material alcohol having 8 or more and 22 or less carbon atoms, in the presence of a catalyst (A) containing a first component, a second component, and a third component below: first component: copper, second component: one kind selected from the group consisting of cobalt, nickel, molybdenum, and rhenium, and third component: at least one kind selected from the group consisting of elements that are elements belonging to Groups 3 to 10 and 12 of the fourth period of the periodic table and elements belonging to Groups 3 to 7, 11, and 12 of the fifth and sixth periods of the periodic table, and are different from the element selected as the second component.
METHOD FOR PROCESSING WASTE USING LOW-TEMPERATURE PLASMA AND DEVICE THEREFOR
A device for processing waste is described herein that comprises an ion generator, a furnace chamber, a heat exchanger, a pollution control system, and a chimney. The ion generator converts atmospheric air into an ionized gas and the furnace chamber thermally decays the waste by combining the waste with a product of an interaction of the ionized gas and heat generated by the furnace chamber. The heat exchanger cools the excess gas. A wet scrubber system removes heavy metals and/or acid gases from the cooled excess gas to generate scrubbed excess gas, and a fixed bed coke system detoxifies the scrubbed excess gas by converting carbon monoxide, water, and steam in the scrubbed excess gas to carbon dioxide and hydrogen, and removing remaining acid gas, a remaining heavy metal, and/or a remaining dioxin from the scrubbed excess gas. The chimney transfers remaining scrubbed excess gas out of the device.
METHOD FOR PROCESSING WASTE USING LOW-TEMPERATURE PLASMA AND DEVICE THEREFOR
A device for processing waste is described herein that comprises an ion generator, a furnace chamber, a heat exchanger, a pollution control system, and a chimney. The ion generator converts atmospheric air into an ionized gas and the furnace chamber thermally decays the waste by combining the waste with a product of an interaction of the ionized gas and heat generated by the furnace chamber. The heat exchanger cools the excess gas. A wet scrubber system removes heavy metals and/or acid gases from the cooled excess gas to generate scrubbed excess gas, and a fixed bed coke system detoxifies the scrubbed excess gas by converting carbon monoxide, water, and steam in the scrubbed excess gas to carbon dioxide and hydrogen, and removing remaining acid gas, a remaining heavy metal, and/or a remaining dioxin from the scrubbed excess gas. The chimney transfers remaining scrubbed excess gas out of the device.
Methods for gas phase oxidative desulphurization of hydrocarbons using CuZnAl catalysts promoted with group VIB metals
A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide with a spinel formula, and crystals of ZnO, CuO, and at least one Group VIB metal oxide, and preferably, at least one acidic oxide of B, P. or Si, as well. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.
Methods for gas phase oxidative desulphurization of hydrocarbons using CuZnAl catalysts promoted with group VIB metals
A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide with a spinel formula, and crystals of ZnO, CuO, and at least one Group VIB metal oxide, and preferably, at least one acidic oxide of B, P. or Si, as well. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.
PRODUCTION OF LIQUEFIED PETROLEUM GAS (LPG) HYDROCARBONS FROM CARBON DIOXIDE-CONTAINING FEEDS
Pathways are disclosed for the production of liquefied petroleum gas (LPG) products comprising propane and/or butane, and in certain cases renewable products having non-petroleum derived carbon. In particular, a gaseous feed mixture comprising CO.sub.2 in combination with CH.sub.4 and/or H.sub.2 is converted by reforming and/or reverse water-gas shift (RWGS) reactions, further in combination with LPG synthesis. A preferred gaseous feed mixture comprises biogas or otherwise a mixture of CO.sub.2 and H.sub.2 that is not readily upgraded using conventional processes. Catalysts described herein have a high activity for reforming (including dry reforming) of CH.sub.4, as well as simultaneously catalyzing RWGS. These attributes improve the management of CO.sub.2 that is input to the disclosed processes, particularly in those utilizing recycle operation to increase overall CO.sub.2 conversion. Economics of small scale operations may be improved, if necessary, using an electrically heated reforming reactor in the first or initial reforming stage or RWGS stage.
Catalyst for oxidative dehydrogenation, method of preparing catalyst, and method of performing oxidative dehydrogenation using catalyst
Provided is a catalyst for oxidative dehydrogenation, a method of preparing the catalyst, and a method of performing oxidative dehydrogenation using the catalyst. The catalyst for oxidative dehydrogenation has improved durability and fillability by including a porous support coated with a metal oxide (AB.sub.2O.sub.4) according to Equation 1:
X wt %+Y wt %=100 wt %, <Equation 1> wherein X is a content of AB.sub.2O.sub.4 and is 5 or more and less than 30, and Y is a content of the porous support and is more than 70 and 95 or less,
wherein the metal oxide exhibits activity during oxidative dehydrogenation. Therefore, when the catalyst is used in oxidative dehydrogenation of butene, the conversion rate of butene and the selectivity and yield of butadiene may be greatly improved.
Catalyst for oxidative dehydrogenation, method of preparing catalyst, and method of performing oxidative dehydrogenation using catalyst
Provided is a catalyst for oxidative dehydrogenation, a method of preparing the catalyst, and a method of performing oxidative dehydrogenation using the catalyst. The catalyst for oxidative dehydrogenation has improved durability and fillability by including a porous support coated with a metal oxide (AB.sub.2O.sub.4) according to Equation 1:
X wt %+Y wt %=100 wt %, <Equation 1> wherein X is a content of AB.sub.2O.sub.4 and is 5 or more and less than 30, and Y is a content of the porous support and is more than 70 and 95 or less,
wherein the metal oxide exhibits activity during oxidative dehydrogenation. Therefore, when the catalyst is used in oxidative dehydrogenation of butene, the conversion rate of butene and the selectivity and yield of butadiene may be greatly improved.
Process for preparing a catalyst or a trapping mass from molten salts
Process for preparing a catalyst or a trapping mass comprising the following steps: bringing a porous oxide support into contact with a metal salt comprising at least one metal belonging to groups VIB, VIIB, VIIIB, IB or IIB, of which the melting point of said metal salt is between 20° C. and 150° C., for a period of between 5 minutes and 5 hours in order to form a solid mixture, the weight ratio of said metal salt to said porous oxide support being between 0.1 and 1; heating the solid mixture with stirring at a temperature between the melting point of said metal salt and 200° C. and for 5 minutes to 12 hours; calcining the solid obtained in the preceding step at a temperature above 200° C. and below or equal to 1100° C. under an inert atmosphere or under an oxygen-containing atmosphere.