The present invention disclosed an improved process for the preparation of bimetallic core-shell nanoparticles by using facile aqueous phase synthesis strategy and their application in catalysis such as selective hydrogenation of alkynes into alkenes or alkanes and CO hydrogenation to hydrocarbons.

A method for the manufacture of an oxygen reduction reaction (ORR) catalyst, the method comprising; providing a metal organic framework (MOF) material having a specific internal pore volume of 0.7 cm.sup.3g.sup.−1 or greater; providing a source of iron and/or cobalt; pyrolysing the MOF material together with the source of iron and/or cobalt to form the catalyst, wherein the MOF material comprises nitrogen and/or the MOF material is pyrolysed together with a source of nitrogen and the source of iron and/or cobalt is disclosed.

A catalyst comprising a noble metal disposed on a support. The noble metal is present in an amount ranging from 0.1 wt % to 10 wt % relative to the total weight of the catalyst. The support comprises at least 50 wt % silicon carbide relative to the total weight of the support. The silicon carbide has a surface area of at least 5 m.sup.2/g. A method for preparing methyl methacrylate from methacrolein and methanol using the catalyst is also disclosed.

Catalyst materials comprising iron and palladium are described. Also described are methods for preparing such materials. In addition, methods for remediating materials such as sediments and groundwater using the catalyst materials are described.

Present exemplary embodiments provide a nano-hybrid catalyst including: a two-dimensional platinum (Pt) nanodendrite sheet layer with a controlled crystal plane; and a NiFe layered double hydroxide nanosheet layer, in which the two-dimensional platinum (Pt) nanodendrite sheet layer with the controlled crystal plane and the NiFe layered double hydroxide nanosheet layer are alternately stacked, and a method for manufacturing the same.

A supported catalyst having rhodium particles with an average diameter of less than 1 nm disposed on a support material containing magnetic iron oxide (e.g. Fe.sub.3O.sub.4). A method of producing the supported catalyst and a process of reducing nitroarenes to corresponding aromatic amines employing the supported catalyst with a high product yield are also described. The supported catalyst may be recovered with ease using an external magnet and reused.

The disclosure provides a catalyst composition that includes a catalytic material and a magnetic ferrite compound. The magnetic ferrite compound can be pretreated, for example, by heating prior to incorporation within the catalyst composition. The magnetic ferrite compound may include iron, and one or more additional metals including zinc, cobalt, nickel, yttrium, manganese, copper, barium, strontium, scandium, and lanthanum. The disclosure also includes a system and method for heating the catalyst composition, which employs a conductor for receiving current and generating an alternating magnetic field in response thereto.

A metal-supported catalyst, battery electrode, and battery, each having excellent catalytic activity and durability. The metal-supported catalyst includes: a carbon carrier; and catalyst metal particles supported thereon, wherein, in a photoelectron spectrum obtained by X-ray photoelectron spectroscopy, the catalyst exhibits, as a peak derived from a is orbital of a nitrogen atom, a peak to be separated into peaks of first to sixth nitrogen atoms having peak tops in the following respective ranges: (1) 398.6±0.2 eV; (2) 399.5±0.3 eV; (3) 400.5±0.2 eV; (4) 401.3±0.3 eV; (5) 403.4±0.4 eV; and (6) 404.5±0.5 eV, wherein a ratio of a peak area of the second nitrogen atoms to a total peak area of the nitrogen atoms of the (1) to (6) is 0.03 or more, and wherein a ratio of a concentration of the second nitrogen atoms to a concentration of carbon atoms measured by the X-ray photoelectron spectroscopy is 0.0005 or more.

A metal-supported catalyst, a battery electrode, and a battery, each having both excellent catalytic activity and durability. The metal-supported catalyst includes: a carbon carrier; and platinum particles serving as catalyst metal particles supported on the carbon carrier, wherein the platinum particles contain pure platinum particles and platinum alloy particles, wherein a proportion of a weight of the pure platinum particles to a sum of the weight of the pure platinum particles and a weight of the platinum alloy particles is 15% or more and 61% or less, and wherein a ratio of a proportion of a nitrogen atom content to a carbon atom content measured by elemental analysis using a combustion method, to a proportion of a nitrogen atom content to a carbon atom content measured by X-ray photoelectron spectroscopy, is 1.05 or more.

A metal-supported catalyst, a battery electrode, and a battery, each having both excellent catalytic activity and durability. The metal-supported catalyst includes: a carbon carrier; and catalyst metal particles each containing a noble metal supported on the carbon carrier, wherein a volume of first pores each having a diameter of 0.5 nm or more and 2.0 nm or less per unit weight of the carbon carrier is 0.20 (cm.sup.3/g-carrier) or more, wherein a volume of second pores each having a diameter of more than 2.0 nm and 4.0 nm or less per unit weight of the carbon carrier is 0.20 (cm.sup.3/g-carrier) or more, and wherein a ratio of a content (wt %) of the noble metal measured by X-ray photoelectron spectroscopy, to a content (wt %) of the noble metal measured by inductively coupled plasma mass spectrometry, is 0.35 or more and 0.75 or less.