Methods, compositions, and articles of manufacture for alkane activation with single- or bi-metallic catalysts on crystalline mixed oxide supports.

The present invention aims to provide a catalyst that makes it possible to reduce an amount of solid electrolyte mixed and improve initial performance of a fuel cell, and also a method for producing the catalyst. The present invention relates to a catalyst for a solid polymer fuel cell, which has sulfo groups (SO.sub.3H) on catalyst particles. In TEM-EDX analysis, a ratio (I.sub.S/I.sub.Pt) of a sulfur peak intensity (I.sub.S) to a platinum peak intensity (I.sub.Pt) on the catalyst particles is within a range of 0.0044 or more and 0.0090 or less. The catalyst makes it possible to reduce the amount of solid electrolyte added and also a fuel cell with excellent initial performance, and thus contributes to a practical use of a fuel cell.

The present invention relates to catalysts, more particularly to a cobalt-containing catalyst composition. The present invention further relates to a process for preparing a cobalt-containing catalyst precursor, a process for preparing a cobalt-containing catalyst, and a hydrocarbon synthesis process wherein such a catalyst is used. According to a first aspect of the invention, there is provided a cobalt-containing catalyst composition comprising cobalt and/or a cobalt compound supported on and/or in a catalyst support; the catalyst composition also including a titanium compound on and/or in the catalyst support, and a manganese compound on and/or in the catalyst support.

Provided is a catalyst that can exhibit high activity. The catalyst is an electrode catalyst having catalytic metals supported on a catalyst support, in which the catalytic metals include platinum and a metal component other than platinum; the electrode catalyst has mesopores having a mode radius of pore distribution of mesopores having a radius of 1 nm or more, of 1 nm or more and less than 2.5 nm; alloy microparticles of platinum and the metal component other than platinum are supported inside the mesopores; and a molar content ratio of platinum with respect to the metal component other than platinum in the alloy microparticles supported inside the mesopores is 1.0 to 10.0.

Described herein are catalysts relating to liquid synthesis, methods of their preparation, and methods of their use. In an embodiment according to the present disclosure, a method of producing a catalyst for liquid synthesis comprises: providing a silica oxide support; pretreating the silica oxide support to remove air and moisture; impregnating the pretreated silica oxide support with cobalt from a cobalt source using a cobalt impregnation method; and calcinating the impregnated silica oxide support in an oven with a temperature ramping profile, wherein the calcinating comprises feeding air into the oven.

The invention relates to Fischer-Tropsch synthesis in a compact version. A compact reactor comprises a housing, rectangular reaction channels inside the housing, which are filled with a cobalt catalyst, synthesis gas injection nozzles in the number determined by the ratio of the number of channels to the number of synthesis gas injection nozzles, an input and output nozzle for heat transfer medium on which a pressure controller installed, and an assembly for withdrawing synthetic hydrocarbons. The cobalt catalyst is activated by passing hydrogen through it. Synthetic hydrocarbons are produced by passing synthesis gas through the reaction channels filled with the activated cobalt catalyst. The space velocity of synthesis gas is increased every 300-500 h, followed by returning to the initial process conditions. This provides a high-molecular-weight hydrocarbon output per unit mass of the reactor.

A method for preparing a silica-modified catalyst support is described comprising: (i) applying an alkyl silicate solution to a porous support material in an amount to produce a silica content of the silica-modified catalyst support, expressed as Si, in the range 0.25 to 15% by weight, (ii) drying the resulting silicate-modified support and recovering a first alcoholic solution, (iii) optionally treating the dried silicate-modified support with water, drying the resulting water-treated support and recovering a second alcoholic solution, and (iv) calcining the dried material to form the silica-modified catalyst support, wherein the first alcoholic solution contains 10 vol % water and at least a portion of the first alcoholic solution is mixed with alkyl silicate to form the alkyl silicate solution.

The present specification relates to a carrier-nanoparticle complex, a method for preparing the same, and a catalyst comprising the same.

The invention relates to a multitubular reactor for dehydrogenation of liquid phase alcohol dehydrogenation and a method of liquid phase alcohol dehydrogenation. Most of the alcohol dehydrogenation reaction is endothermic reaction, the reaction temperature is high and the equilibrium conversion rate is low.

A new family of crystalline microporous metallophosphates designated AlPO-90 has been synthesized. These metallophosphates are represented by the empirical formula

R.sup.+.sub.rM.sub.m.sup.2+EP.sub.xSi.sub.yO.sub.z

where R is an organoammonium cation, M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-90 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.