B01J23/892

Palladium-based supported hydrogenation catalyst, and preparation method and application thereof

The present invention relates to a palladium-based supported hydrogenation catalyst and a preparation method and application thereof. The catalyst is prepared by the following method: impregnating an Al.sub.2O.sub.3-containing carrier with an organic solution containing a bipyridine derivative having hydroxy group, optionally drying followed by impregnating with a mixed solution containing the main active component palladium ions and the auxiliary active component M.sup.n+ ions, where M is one selected from Ag, Au, Ni, Pb and Cu; and then optionally drying, and calcining to obtain the catalyst. The preparation method provided by the present invention allows Pd atoms and M atoms to be highly uniformly dispersed on the carrier, which overcomes the adverse impact of the surface tension of the impregnation solution and the solvation effect on the dispersibility of active components. The palladium-based supported hydrogenation catalyst provided by the present invention has excellent hydrogenation activity, ethylene selectivity and anti-coking performance, and can be used in a selective hydrogenation process of C2 fraction.

METHODS AND APPARATUSES FOR PRODUCING CARBON NANOTUBES, METHODS OF PRODUCING SUCH APPARATUSES, AND STRUCTURES FORMED FROM SUCH NANOTUBES
20240010497 · 2024-01-11 ·

Methods and apparatuses capable of enabling carbon nanotubes (CNTs) to be grown from a structured catalyst to produce zero-chirality strands (fibers), as well as methods for manufacturing catalytic membranes capable of use in such methods and apparatuses and structures produced with such methods, apparatuses, and membranes. Such a method includes forming interlinked cyclic graphene hexagons at a growth site on a permeable catalyst layer disposed on a porous support. The growth site is located over a pore in the porous support. A strand of zero-chiral carbon nanotube is continuously grown from the dome by providing a hydrocarbon feed at a positive pressure through the porous support and the permeable catalyst layer toward the growth site.

CO shift catalyst, CO shift reaction apparatus, and method for purifying gasified gas

A CO shift catalyst according to the present invention reforms carbon monoxide (CO) in gas. The CO shift catalyst has one of molybdenum (Mo) or iron (Fe) as a main component and has an active ingredient having one of nickel (Ni) or ruthenium (Ru) as an accessory component and one or two or more kinds of oxides from among titanium (Ti), zirconium (Zr), and cerium (Ce) for supporting the active ingredient as a support. The temperature at the time of manufacturing and firing the catalyst is equal to or higher than 550 C.

PEROVSKITE COMPOUND, METHOD FOR PRODUCING THE PEROVSKITE COMPOUND, CATALYST FOR FUEL CELL INCLUDING THE PEROVSKITE COMPOUND AND METHOD FOR PRODUCING THE CATALYST

Disclosed are a perovskite compound, a method for producing the perovskite compound, a catalyst for a fuel cell including the perovskite compound, and a method for producing the catalyst. The perovskite compound overcomes the low stability of palladium due to its perovskite structural properties. Therefore, the perovskite compound can be used as a catalyst material for a fuel cell. In addition, the use of palladium in the catalyst instead of expensive platinum leads to an improvement in the price competitiveness of fuel cells. The catalyst is highly durable and catalytically active due to its perovskite structure.

Processes to create multiple value streams from biomass sources

Use of diverse biomass feedstock in a process for the recovery of target C5 and C6 alditols and target glycols via staged hydrogenation and hydrogenolysis processes is disclosed. Particular alditols of interest include, but are not limited to, xylitol and sorbitol. Various embodiments of the present invention synergistically improve overall recovery of target alditols and/or glycols from a mixed C5/C6 sugar stream without needlessly driving total recovery of the individual target alditols and/or glycols. The result is a highly efficient, low complexity process having enhanced production flexibility, reduced waste and greater overall yield than conventional processes directed to alditol or glycol production.

INCREASING THE CATALYST SELECTIVITY IN THE CONTINUOUS HYDROGENATION OF NITRO COMPOUNDS BY ADDING AMMONIA

The present invention relates to a process for continuous hydrogenation of a nitro compound to the corresponding amine in a liquid reaction mixture comprising the nitro compound in a reaction chamber in the presence of a supported catalyst which comprises as the active component at least one element from groups 7 to 12 of the periodic table of the elements, wherein ammonia is added to the reaction chamber during the hydrogenation.

Porous shaped carbon products

Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided.

NANOCATALYSTS FOR ELECTROCHEMICAL HYDROGEN PRODUCTION AND CATALYST SCREENING METHODS
20200230581 · 2020-07-23 ·

Disclosed herein are trimetallic PtAu-based nanocatalysts for electrochemical hydrogen production and screening methods thereof. Nanocatalysts are produced through a polymer pen lithography (PPL) technique, which enables large-scale fabrication of nanoparticle arrays with programmable specifications such as size, shape, and composition, providing a route to the high-throughput screening and discovery of new catalysts.

CATALYST FOR REMOVING VOLATILE ORGANIC COMPOUNDS AND PREPARATION METHOD THEREFOR

The invention discloses a catalyst for removing volatile organic compounds and a preparation method therefor. In the catalyst, aluminum oxide modified by iron, cobalt and nickel is used as a carrier, cordierite honeycomb ceramic is used as a matrix, and an extremely low content of a mixture of platinum and palladium is used as an active component; a molar ratio of platinum to palladium is 0-1:0-9, and an amount of the mixture of platinum and palladium accounts for 0.01% to 0.05% of a mass of the matrix; and an amount of the carrier accounts for 3% to 5% of the mass of the matrix.

Compositions, Methods, and Apparatuses for Catalytic Combustion
20200197913 · 2020-06-25 ·

There is provided a catalyst composition including a hydrogen oxidation catalyst and an oxygen reduction catalyst and a process for applying the catalyst composition to a substrate. Heat exchange reactors including the catalyst composition and methods for heating a heat exchange medium are also provided. Catalytic combustors including a catalytic surface including the catalyst composition are further provided. The catalyst is adapted for low temperature activation of a hydrogen combustion reaction.