The present invention concerns a process of oxidizing an alcohol for the production of its corresponding carbonyl compounds wherein the oxidation is performed with oxygen or gases containing oxygen in the presence of a catalyst comprising at least a gold compound and a copper compound. Said alcohol oxidation by gaseous oxidant can achieve a high yield and selectivity with minimized degradation products or waste organic solvents.

A photocatalyst/alloy fine-particle dispersion containing two kinds of fine particles dispersed in an aqueous dispersion medium, (i) photocatalyst fine particles and (ii) alloy fine particles containing an antibacterial/antifungal metal, easily forms a photocatalyst/alloy fine-particle thin film of high transparency that exhibits antibacterial/antifungal properties regardless of the presence or absence of light irradiation.

An oxidation catalyst for treating an exhaust gas produced by a compression ignition engine comprising: a substrate having an inlet end surface and an outlet end surface; a catalytic material disposed on the substrate, wherein the catalytic material comprises platinum (Pt); and a capture material, wherein the capture material is disposed on the outlet end surface.

To produce a core-shell catalyst with high catalytic activity for a short period of time. Disclosed is a method for producing a core-shell catalyst comprising a core containing palladium and a shell containing platinum and coating the core, the method comprising: supplying palladium-containing particles and a copper-containing material to an acid solution; stirring the acid solution with introducing an oxygen-containing gas into the acid solution; coating at least a part of a surface of the palladium-containing particles with copper by applying a potential that is nobler than the oxidation reduction potential of copper to the palladium-containing particles in a copper ion-containing electrolyte after the stirring; and then forming the shell by substituting the copper coating at least a part of the surface of the palladium-containing particles with platinum by bringing the palladium-containing particles into contact with a platinum ion-containing solution.

Processes for regenerating an at least partially deactivated catalyst that can include a Group (10) element, an inorganic support, and a contaminant. The Group (10) element can have a concentration of from 0.001 wt % to 6 wt %, based on the weight of the inorganic support. The process can include (I) heating the deactivated catalyst using a heating gas mixture that includes H.sub.2O at a concentration >5 mol %, based on the total moles in the mixture to produce a precursor catalyst. The process can also include (II) providing an oxidative gas that includes ?5 mol % of H.sub.2O, based on the total moles in the oxidative gas, and (III) contacting the precursor catalyst at an oxidizing temperature with the oxidative gas for a duration of at least 30 seconds to produce an oxidized precursor catalyst. The process can also include (IV) obtaining a regenerated catalyst from the oxidized precursor catalyst.

Disclosed is a process for the preparation of cis-1,1,1,4,4,4-hexafluoro-2-butene comprising contacting 1,1,1-trifluorotrichloroethane with hydrogen in the presence of a catalyst comprising ruthenium to produce a product mixture comprising 1316mxx, recovering said 1316mxx as a mixture of Z- and E-isomers, contacting said 1316mxx with hydrogen, in the presence of a catalyst selected from the group consisting of copper on carbon, nickel on carbon, copper and nickel on carbon and copper and palladium on carbon, to produce a second product mixture, comprising E- or Z-CFC-1326mxz, and subjecting said second product mixture to a separation step to provide E- or Z-1326mxz. The E- or Z-1326mxz can be dehydrochlorinated in an aqueous basic solution with an alkali metal hydroxide in the presence of a phase transfer catalyst to produce hexafluoro-2-butyne, which can then be selectively hydrogenated to produce Z-1,1,1,4,4,4-hexafluoro-2-butene using either Lindlar's catalyst, or a palladium catalyst further comprising a lantanide element or silver.

The present invention relates to a catalyst that comprises a carrier body with a length L, which extends between a first end face a and a second end face b, and differently composed, catalytically-active material zones A, B, and C arranged on the carrier body, wherein material zone A contains platinum or platinum and palladium with a weight ratio Pt:Pd of 1 and, starting from end face a or starting from end face b, extends along 70 to 100% of the length L, and material zone B contains palladium or platinum and palladium and, starting from end face b, extends along a portion of the length L, and material zone C contains SCR-active material and, starting from end face a, extends along a portion of the length L,
wherein material zone C is arranged above material zone A.

A catalyst for producing light aromatics with heavy aromatics, a method for preparing the catalyst, and a use thereof are disclosed. The catalyst comprises a carrier, component (1), and component (2), wherein component (1) comprises one metal element or more metal elements selected from a group consisting of Pt, Pd, Ir, and Rh, and component (2) comprises one metal element or more metal elements selected from a group consisting of IA group, IIA group, IIIA group, IVA group, IB group, IIB group, IIIB group, IVB group, VB group, VIB group, VIIB group, La group, and VIII group other than Pt, Pd, Ir, and Rh. The catalyst can be used for producing light aromatics with heavy aromatics, whereby heavy aromatics hydrogenation selectivity and light aromatics yield can be improved.

A method of and apparatus for desalinating sea water using geothermal energy. A low voltage (such as less than 0.9V) is applied to a hydrogen generating catalysts to generate hydrogen and oxygen, wherein geothermal heat is used as a heat source. The hydrogen and oxygen are used to drive a gas turbine to generate electricity. The oxygen and hydrogen are transported away and combusted to generate heat and pure water, as such salt are separated from the pure water.

A catalyst including gold, or a compound thereof, and sulphur, a compound of sulphur, trichloroisocyanuric acid or a metal dichloroisocyanurate on a support, together with a process for manufacturing the catalyst and its use in a chemical process are described.