The present invention discloses a method for preparing the nano-porous oxide-noble metal composite material by deoxidation, comprising dissolving the noble metal ion or fine particles, the oxide salt to be dissolved and the target oxide salt in the pure water in a proportion to form the mixed solution, adding the surface active agent, and stirring magnetically; dropping the precipitant gradually to form the precipitate, stirring for 4 h, separating and cleaning the precipitate, and drying, grinding and calcining at a high temperature; corroding fully and dissolving part of the oxide with an etchant, preserving the noble metal and the target oxide, separating, cleaning, drying at 80 C., and heat treating at a high temperature to obtain the nano-porous oxide-noble metal composite material. The present invention has the technological advantages of simple operation, low energy consumption, environmental protection and suitable for batching, etc.

A process of oxidizing an alcohol for the production of its corresponding carbonyl compounds is disclosed, wherein the oxidation is performed with oxygen or gases containing oxygen in the presence of a catalyst comprising at least a gold compound and a copper compound. Said alcohol oxidation by gaseous oxidant can achieve a high yield and selectivity with minimized degradation products or waste organic solvents.

A method of and apparatus for optimizing a hydrogen producing system is provided. The method of optimizing the hydrogen producing system comprises producing hydrogen gas using a hydrogen producing formulation and removing a chemical substance that reduces the hydrogen gas producing efficiency. Further, the hydrogen producing system comprises a hydrogen producing catalyst, a hydrogen generating voltage applied to the hydrogen producing catalyst to generate hydrogen gas, and a catalyst regenerating device to regenerate the hydrogen producing catalyst to a chemical state capable of generating the hydrogen gas when a hydrogen generating voltage is applied.

A method of and apparatus for efficient on-demand production of H.sub.2 and O.sub.2 from water and heat using environmentally safe metals are disclosed. In one aspect, the apparatus for hydrogen generation through water-decomposition reaction includes a main reactor, an oxidizer reactor, and a computer-control system. The computer system is configured to control each of the components of the hydrogen gas production system for stable hydrogen-gas production.

Systems and methods of synthesizing nanoparticles on substrates using rapid, high temperature thermal shock. A method involves depositing micro-sized particles or salt precursors on a substrate, and applying a rapid, high temperature thermal pulse or shock to the micro-sized particles or the salt precursors and the substrate to cause the micro-sized particles or the salt precursors to become nanoparticles on the substrate. A system may include a rotatable member that receives a roll of a substrate sheet having micro-sized particles or salt precursors; a motor that rotates the rotatable member so as to unroll consecutive portions of the substrate sheet from the roll; and a thermal energy source that applies a short, high temperature thermal shock to consecutive portions of the substrate sheet that are unrolled from the roll by rotating the first rotatable member. Some systems and methods produce nanoparticles on existing substrate. The nanoparticles may be metallic, ceramic, inorganic, semiconductor, or compound nanoparticles. The substrate may be a carbon-based substrate, a conducting substrate, or a non-conducting substrate. The high temperature thermal shock process may be enabled by electrical Joule heating, microwave heating, thermal radiative heating, plasma heating, or laser heating.

The present invention relates to the synthesis and application of gold catalysts supported in mixed CuO/ZnO/Al.sub.2O.sub.3 oxides prepared on the basis of their corresponding solids with a hydrotalcite structure as catalysts in the water-gas shift reaction, for use in fuel processors coupled to fuel cells.

Disclosed is a process for the preparation of cis-1,1,1,4,4,4-hexafluoro-2-butene comprising contacting 1,1,1-trifluorotrichloroethane with hydrogen in the presence of a catalyst comprising ruthenium to produce a product mixture comprising 1316mxx, recovering said 1316mxx as a mixture of Z- and E-isomers, contacting said 1316mxx with hydrogen, in the presence of a catalyst selected from the group consisting of copper on carbon, nickel on carbon, copper and nickel on carbon and copper and palladium on carbon, to produce a second product mixture, comprising E- or Z-CFC-1326mxz, and subjecting said second product mixture to a separation step to provide E- or Z-1326mxz. The E- or Z-1326mxz can be dehydrochlorinated in an aqueous basic solution with an alkali metal hydroxide in the presence of a phase transfer catalyst to produce hexafluoro-2-butyne, which can then be selectively hydrogenated to produce Z-1,1,1,4,4,4-hexafluoro-2-butene using either Lindlar's catalyst, or a palladium catalyst further comprising a lantanide element or silver.

Catalysts and methods for the selective conversion of carbon dioxide and hydrogen into methanol using heat and high pressure in a hydrogenation reactor are disclosed. Key to this process are catalysts, which are comprised of multimetallic, aluminum oxide-supported nanoparticles. In some embodiments of the invention, the catalytic nanoparticles are made from mixtures of zinc and copper, or mixtures of palladium and copper, in different stoichiometric equivalents. In others, stoichiometric additives or dopants are added in order to improve the rate of product formation, improve selectivity, or allow for flow configurations. Methods for the use of these catalysts for the synthesis of methanol, and for the purification of CO.sub.2, H.sub.2, or CO gas streams by transforming contaminants into liquid methanol are also described.

The present disclosure belongs to the technical field of catalyst preparation, and provides a polynorbornene/carbon black-cross-linked three-dimensional network-immobilized bimetallic copper/gold (PNBI/CB-Cu/Au) nanocatalyst, and a preparation method and use thereof. Metallic copper and gold both exist in a form of nanoparticles in the catalyst and are uniformly dispersed, and further enhancing a catalytic performance. Moreover, the carrier is a polynorbornene/carbon black-cross-linked three-dimensional network, and a relative content of free hydroxyl groups in the catalyst is controlled by changing a monomer ratio to adjust a hydrophilic-lipophilic balance value of the catalyst, adapting to a reaction of an organic phase with an aqueous phase. Furthermore, the catalyst is insoluble in conventional solvents, and has a desirable effect in immobilizing nanoscale metallic copper, prolonging a service life of the catalyst.

Method for preparing a catalytic fabric filter comprising the steps of a) providing a fabric filter substrate, preferably consisting of glass fibers, having a gas inlet surface and a gas outlet surface, the gas inlet surface is coated with a polymeric membrane, preferably consisting of polytetrafluoroethylene; b) providing an aqueous impregnation liquid comprising one or more catalyst metal precursor compounds; c) impregnating the fabric filter substrate with the impregnation liquid; and d) drying and thermally activating the impregnated fabric filter substrate at a temperature below 300 C. to convert the one or more metal compounds of the catalyst precursor to their catalytically active form, wherein the drying of the impregnated fabric filter substrate in step d) is performed from the gas outlet surface.