Patent classifications
B01J27/043
Porous carbon catalyst loaded with metal sulfides based on high-sulfur petroleum coke and preparation method therefor and application thereof
The present invention provides a porous carbon catalyst loaded with metal sulfides based on high-sulfur petroleum coke and preparation method therefor and application thereof. The method includes the steps of preparing an in-situ activated precursor from a pre-treated high-sulfur petroleum coke, destabilizing bulk sulfur, conducting an in-situ metal-sulfur bonding reaction, and washing and drying, which achieve the high-value in-situ conversion of sulfur in high-sulfur petroleum coke, resulting in the preparation of a porous carbon catalyst loaded with metal sulfides based on high-sulfur petroleum coke. This catalyst is applied to catalyze magnesium-based hydrogen storage materials. It not only avoids the discharge of sulfur-containing gas or sulfur-containing wastewater in the conventional utilization route of high-sulfur petroleum coke, but also expands the green multi-scenario utilization route of high-sulfur petroleum coke to promote the synergy of pollution reduction and carbon reduction in the petroleum refining industry.
POROUS CARBON CATALYST LOADED WITH METAL SULFIDES BASED ON HIGH-SULFUR PETROLEUM COKE AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
The present invention provides a porous carbon catalyst loaded with metal sulfides based on high-sulfur petroleum coke and preparation method therefor and application thereof. The method includes the steps of preparing an in-situ activated precursor from a pre-treated high-sulfur petroleum coke, destabilizing bulk sulfur, conducting an in-situ metal-sulfur bonding reaction, and washing and drying, which achieve the high-value in-situ conversion of sulfur in high-sulfur petroleum coke, resulting in the preparation of a porous carbon catalyst loaded with metal sulfides based on high-sulfur petroleum coke. This catalyst is applied to catalyze magnesium-based hydrogen storage materials. It not only avoids the discharge of sulfur-containing gas or sulfur-containing wastewater in the conventional utilization route of high-sulfur petroleum coke, but also expands the green multi-scenario utilization route of high-sulfur petroleum coke to promote the synergy of pollution reduction and carbon reduction in the petroleum refining industry.
POROUS CARBON CATALYST LOADED WITH METAL SULFIDES BASED ON HIGH-SULFUR PETROLEUM COKE AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
The present invention provides a porous carbon catalyst loaded with metal sulfides based on high-sulfur petroleum coke and preparation method therefor and application thereof. The method includes the steps of preparing an in-situ activated precursor from a pre-treated high-sulfur petroleum coke, destabilizing bulk sulfur, conducting an in-situ metal-sulfur bonding reaction, and washing and drying, which achieve the high-value in-situ conversion of sulfur in high-sulfur petroleum coke, resulting in the preparation of a porous carbon catalyst loaded with metal sulfides based on high-sulfur petroleum coke. This catalyst is applied to catalyze magnesium-based hydrogen storage materials. It not only avoids the discharge of sulfur-containing gas or sulfur-containing wastewater in the conventional utilization route of high-sulfur petroleum coke, but also expands the green multi-scenario utilization route of high-sulfur petroleum coke to promote the synergy of pollution reduction and carbon reduction in the petroleum refining industry.
Sulfidized Nanoscale Zerovalent Metal Doped Carbon Substrate for Poly- And Perfluoroalkyl Substances (PFAS) Adsorption and Transformation
A nanoscale, metal-doped carbonaceous material and method of using such material to break down poly- and perfluoroalkyl substances (PFAS). The material can include a carbonaceous particulate matrix made of a carbon substrate, an oxidative metal, and a reductive metal. The method of breaking down. The method involves adsorbing PFAS with a metal-doped carbonaceous material, where the metal-doped carbonaceous material can be made of a carbon substrate, an oxidative metal, and a reductive metal, and degrading and reducing the PFAS.
Sulfidized Nanoscale Zerovalent Metal Doped Carbon Substrate for Poly- And Perfluoroalkyl Substances (PFAS) Adsorption and Transformation
A nanoscale, metal-doped carbonaceous material and method of using such material to break down poly- and perfluoroalkyl substances (PFAS). The material can include a carbonaceous particulate matrix made of a carbon substrate, an oxidative metal, and a reductive metal. The method of breaking down. The method involves adsorbing PFAS with a metal-doped carbonaceous material, where the metal-doped carbonaceous material can be made of a carbon substrate, an oxidative metal, and a reductive metal, and degrading and reducing the PFAS.
Systems and methods to produce hydrogen gas from hydrogen sulfide
The disclosure relates to systems and methods to produce hydrogen (H.sub.2) gas from hydrogen sulfide (H.sub.2S). H.sub.2S is contacted with a catalyst to form H.sub.2 gas and sulfur adsorbed to the catalyst. The adsorbed sulfur is contacted with oxygen (O.sub.2) gas to convert the adsorbed sulfur to sulfur dioxide (SO.sub.2) and regenerate the catalyst.
Sulfurized perovskite nanosheets, synthesis and uses thereof
The present invention relates to the field of renewable energy and photocatalysis (e.g. photocatalytic water splitting for hydrogen production), specifically focusing on sulfurized perovskite compounds, perovskite nanosheets, and synthesis method and uses thereof. The present invention relates to perovskite nanosheets comprising LaXO.sub.nS.sub.3-n, wherein X is a metal selected from Fe, Co, Mn, Cu, Zn, or Ni; and wherein 0<n<3. Further, the present invention explores the perovskite nanosheets to improve efficiency, stability, and light absorption in solar-driven hydrogen generation applications. The present perovskite nanosheet enhances visible light absorption, charge carrier mobility, and catalytic activity, making it useful for large-scale hydrogen production.
Sulfurized perovskite nanosheets, synthesis and uses thereof
The present invention relates to the field of renewable energy and photocatalysis (e.g. photocatalytic water splitting for hydrogen production), specifically focusing on sulfurized perovskite compounds, perovskite nanosheets, and synthesis method and uses thereof. The present invention relates to perovskite nanosheets comprising LaXO.sub.nS.sub.3-n, wherein X is a metal selected from Fe, Co, Mn, Cu, Zn, or Ni; and wherein 0<n<3. Further, the present invention explores the perovskite nanosheets to improve efficiency, stability, and light absorption in solar-driven hydrogen generation applications. The present perovskite nanosheet enhances visible light absorption, charge carrier mobility, and catalytic activity, making it useful for large-scale hydrogen production.