Patent classifications
B01J27/10
METHOD FOR PREPARING 1,4-BIS(4-PHENOXYBENZOYL)BENZENE AND 1,4-BIS(4- PHENOXYBENZOYL)BENZENE PREPARED THEREBY
A method for preparing 1,4-bis(4-phenoxybenzoyl)benzene is provided. According to the method, when a 1,4-bis(4-phenoxybenzoyl)benzene synthesis reaction is carried out at a specific temperature, the amount of heat used in the preparing process can be minimized while attaining the same yield as that of the existing preparing method. In addition, waste solvent generated in the preparing process does not undergo a color change and thus can be reused, and thus energy saving effects can be provided.
METHOD FOR PREPARING 1,4-BIS(4-PHENOXYBENZOYL)BENZENE AND 1,4-BIS(4- PHENOXYBENZOYL)BENZENE PREPARED THEREBY
A method for preparing 1,4-bis(4-phenoxybenzoyl)benzene is provided. According to the method, when a 1,4-bis(4-phenoxybenzoyl)benzene synthesis reaction is carried out at a specific temperature, the amount of heat used in the preparing process can be minimized while attaining the same yield as that of the existing preparing method. In addition, waste solvent generated in the preparing process does not undergo a color change and thus can be reused, and thus energy saving effects can be provided.
Process for preparing 3,3,3-trifluoroprop-1-ene
The present application provides a process of preparing 3,3,3-trifluoroprop-1-ene, comprising reacting 3-chloro-1,1,1-trifluoropropane with a base in an aqueous solvent component in the absence of a phase transfer catalyst.
Process for preparing 3,3,3-trifluoroprop-1-ene
The present application provides a process of preparing 3,3,3-trifluoroprop-1-ene, comprising reacting 3-chloro-1,1,1-trifluoropropane with a base in an aqueous solvent component in the absence of a phase transfer catalyst.
Method for regenerating a toxified catalyst containing ruthenium or ruthenium compounds
A process for regenerating a catalyst containing ruthenium or ruthenium compounds, which includes, optionally at elevated temperature, subjecting the catalyst to a hydrogen halide treatment, particularly a gas stream comprising hydrogen chloride, under non-oxidative conditions and, optionally at reduced temperature, to at least a two-stage oxidative post-treatment. The catalyst may have been poisoned by sulfur compounds. After the removal of sulfur, the catalyst is subjected to an oxidative post-treatment.
Method for regenerating a toxified catalyst containing ruthenium or ruthenium compounds
A process for regenerating a catalyst containing ruthenium or ruthenium compounds, which includes, optionally at elevated temperature, subjecting the catalyst to a hydrogen halide treatment, particularly a gas stream comprising hydrogen chloride, under non-oxidative conditions and, optionally at reduced temperature, to at least a two-stage oxidative post-treatment. The catalyst may have been poisoned by sulfur compounds. After the removal of sulfur, the catalyst is subjected to an oxidative post-treatment.
Metal Oxides for Selective Hydrogen Combustion
Metal oxides are provided that have selective hydrogen combustion activity while also acting as solid oxygen carriers (SOCs). The metal oxides correspond to a metal oxide core of at least one metal having multiple oxidation states that is modified with an alkali metal oxide and/or alkali metal halogen (such as an alkali metal chloride). The resulting modified metal oxide, corresponding to a solid oxygen carrier, can allow for selective combustion of hydrogen while reducing or minimizing combustion of hydrocarbons, such as within a propane dehydrogenation environment. Additionally, it has been unexpectedly found that modifying the core metal oxide with the alkali metal oxide and/or alkali metal chloride can also mitigate coke formation on the solid oxygen carrier. Methods of using such metal oxides for selective hydrogen combustion are also provided.
Catalyst for catalytic oxidation of furfural for preparation of maleic acid, preparation method and use thereof
A catalyst for catalytic oxidation of furfural to prepare maleic acid is composed of a carbon nitride doped with a potassium salt. A method for preparing the catalyst includes mixing the potassium salt, a precursor of the carbon nitride and a solvent to obtain a mixture, and drying and calcining the mixture to obtain the catalyst. A use of the catalyst in catalytic oxidation of furfural to prepare maleic acid, wherein the maleic acid is prepared by the step of oxidizing furfural in a solvent in the presence of the catalyst. The invention has the advantages that by using the method provided by the invention to prepare maleic acid, the conversion rate of furfural can be 99% or more and the yield of maleic acid can be up to 70.40%.
Catalyst for catalytic oxidation of furfural for preparation of maleic acid, preparation method and use thereof
A catalyst for catalytic oxidation of furfural to prepare maleic acid is composed of a carbon nitride doped with a potassium salt. A method for preparing the catalyst includes mixing the potassium salt, a precursor of the carbon nitride and a solvent to obtain a mixture, and drying and calcining the mixture to obtain the catalyst. A use of the catalyst in catalytic oxidation of furfural to prepare maleic acid, wherein the maleic acid is prepared by the step of oxidizing furfural in a solvent in the presence of the catalyst. The invention has the advantages that by using the method provided by the invention to prepare maleic acid, the conversion rate of furfural can be 99% or more and the yield of maleic acid can be up to 70.40%.
ACIDIC AROMATIZATION CATALYSTS WITH IMPROVED ACTIVITY AND SELECTIVITY
Methods for producing supported catalysts containing a transition metal and a bound zeolite base are disclosed. These methods employ a step of impregnating the bound zeolite base with the transition metal, fluorine, and high loadings of chlorine. The resultant high chlorine content supported catalysts have improved catalyst activity in aromatization reactions.