Described herein are heterogeneous materials comprising a p-type semiconductor comprising two metal oxide compounds of the same metal in two different oxidation states and an n-type semiconductor having a deeper valence band than the p-type semiconductor valence bands, wherein the semiconductor types are in ionic communication with each other. The heterogeneous materials enhance photocatalytic activity.

An antimicrobial toilet includes an inner surface of a toilet bowl which includes a non-doped titanium dioxide coating. The titanium dioxide coating is photocatalytic and antimicrobial in the presence of ultraviolet (UV) light. In the absence of UV light, the inner surface of the toilet bowl is not antimicrobial. The UV light source may be actuated after the waste has exited the toilet bowl. Consequently, the waste may be used in digesters used to produce clean energy or for analysis to assess the user's health status without being exposed to the antimicrobial properties of the titanium dioxide coating. The UV light may then be actuated to disinfect the toilet bowl. The outer shell of the toilet is coated with a doped titanium dioxide. The doped titanium dioxide is photocatalytic and antimicrobial in the presence of visible light. The outer shell is antimicrobial when standard room lights are actuated.

An antimicrobial toilet includes an inner surface of a toilet bowl which includes a non-doped titanium dioxide coating. The titanium dioxide coating is photocatalytic and antimicrobial in the presence of ultraviolet (UV) light. In the absence of UV light, the inner surface of the toilet bowl is not antimicrobial. The UV light source may be actuated after the waste has exited the toilet bowl. Consequently, the waste may be used in digesters used to produce clean energy or for analysis to assess the user's health status without being exposed to the antimicrobial properties of the titanium dioxide coating. The UV light may then be actuated to disinfect the toilet bowl. The outer shell of the toilet is coated with a doped titanium dioxide. The doped titanium dioxide is photocatalytic and antimicrobial in the presence of visible light. The outer shell is antimicrobial when standard room lights are actuated.

An antimicrobial toilet includes an inner surface of a toilet bowl which includes a non-doped titanium dioxide coating. The titanium dioxide coating is photocatalytic and antimicrobial in the presence of ultraviolet (UV) light. In the absence of UV light, the inner surface of the toilet bowl is not antimicrobial. The UV light source may be actuated after the waste has exited the toilet bowl. Consequently, the waste may be used in digesters used to produce clean energy or for analysis to assess the user's health status without being exposed to the antimicrobial properties of the titanium dioxide coating. The UV light may then be actuated to disinfect the toilet bowl. The outer shell of the toilet is coated with a doped titanium dioxide. The doped titanium dioxide is photocatalytic and antimicrobial in the presence of visible light. The outer shell is antimicrobial when standard room lights are actuated.

An antimicrobial toilet includes an inner surface of a toilet bowl which includes a non-doped titanium dioxide coating. The titanium dioxide coating is photocatalytic and antimicrobial in the presence of ultraviolet (UV) light. In the absence of UV light, the inner surface of the toilet bowl is not antimicrobial. The UV light source may be actuated after the waste has exited the toilet bowl. Consequently, the waste may be used in digesters used to produce clean energy or for analysis to assess the user's health status without being exposed to the antimicrobial properties of the titanium dioxide coating. The UV light may then be actuated to disinfect the toilet bowl. The outer shell of the toilet is coated with a doped titanium dioxide. The doped titanium dioxide is photocatalytic and antimicrobial in the presence of visible light. The outer shell is antimicrobial when standard room lights are actuated.

A transesterification catalyst that is heterogeneous and a method for preparing said transesterification catalyst are provided. The catalyst can be used in a variety of transesterification reactor configurations including CSTR (continuous stirred tank reactors), ebullated (or ebullating) beds or any other fluidized bed reactors, and PFR (plug flow, fixed bed reactors). The catalyst can be used for manufacturing commercial grade biodiesel, biolubricants and glycerin.

A transesterification catalyst that is heterogeneous and a method for preparing said transesterification catalyst are provided. The catalyst can be used in a variety of transesterification reactor configurations including CSTR (continuous stirred tank reactors), ebullated (or ebullating) beds or any other fluidized bed reactors, and PFR (plug flow, fixed bed reactors). The catalyst can be used for manufacturing commercial grade biodiesel, biolubricants and glycerin.

Disclosed herein are processes of making furan-based polyamides using solvent-free melt condensation of a diamine and an ester derivative of 2,5-furandicarboxylic acid with a C.sub.2 to C.sub.12 aliphatic diol or a polyol. The processes comprise a) forming a reaction mixture by mixing one or more diamines, a diester comprising an ester derivative of 2,5-furandicarboxylic acid with a C.sub.2 to C.sub.12 aliphatic diol or a polyol, and a catalyst, such that the diamine is present in an excess amount of at least 1 mol % with respect to the diester amount; and b) melt polycondensing the reaction mixture in the absence of a solvent at a temperature in the range of 60? C. to a maximum temperature of 250? C. under an inert atmosphere, while removing alkyl alcohol to form a furan-based polyamide, wherein the one or more diamines comprises an aliphatic diamine, an aromatic diamine, or an alkylaromatic diamine.

A process for the oxidation of an organic carbonyl compound comprising reacting the compound, optionally in the presence of a solvent, with hydrogen peroxide in the presence of a catalyst comprising a tin-containing zeolitic material and at least one potassium salt.

The present disclosure describes hybrid binary catalysts (HBCs) that can be used as engine aftertreatment catalyst compositions. The HBCs provide solutions to the challenges facing emissions control. In general, the HBCs include a porous primary catalyst and a secondary catalyst. The secondary catalyst partial coats the surfaces (e.g., the internal porous surface and/or the external surface) of the primary catalyst resulting in a hybridized composition. The synthesis of the HBCs can provide a primary catalyst whose entire surface, or portions thereof, can be coated with the secondary catalyst.