Patent classifications
B01J27/1853
Catalytic conversion of lactic acid to acrylic acid
Disclosed herein is a mixed phosphate catalyst for converting lactic acid to acrylic acid, which is characterized by a high conversion of lactic acid, a high selectivity for acrylic acid, a high yield of acrylic acid, and correspondingly low selectivity and molar yields for undesired by-products. This is achieved with a particular class of catalysts defined by a mixture of metal-containing phosphate salts. Further, the catalyst is believed to be stable and active for lengthy periods heretofore unseen in the art for such dehydration processes.
Catalyst for synthesizing ethylenimine as well as preparation method and application thereof
The present invention relates to a catalyst for synthesizing ethylenimine as well as a preparation method and application thereof. The related catalyst comprises a carrier and metal ions loaded on the carrier; the carrier is a composite oxide comprising titanium, silicon and phosphorus elements; the metal ions are magnesium ions, iron ions and cesium ions; the molar ratio of the magnesium ions to the iron ions to the cesium ions is (1-10):1:0.1; the mass of all metal ions is 0.5-10 percent of that of the carrier. In the related preparation method, a catalyst precursor is roasted at the temperature of 350-650 C., so that the catalyst is obtained; the catalyst precursor is the mixture of the carrier, soluble salt of magnesium, soluble salt of iron and soluble salt of cesium. The present invention also provides the application of the catalyst to synthesis of the ethylenimine by using amino alcohol as the raw material. Compared with a common catalyst which has the requirement on the temperature of over 400 C., the catalyst of the present invention obviously reduces the reaction temperature. The prepared catalyst can catalyze the intramolecular dehydration reaction of the amino alcohol and has relatively excellent selectivity.
Carrier for exhaust gas purification catalyst and exhaust gas purification catalyst
The invention relates to a catalyst carrier for exhaust gas purification catalyst which contains a metal phosphate containing Zr, and it provides a new catalyst carrier which exhibits excellent NOx purification performance in a high temperature region. The invention proposes a carrier for exhaust gas purification catalyst containing a metal phosphate which has a NASICON type structure and contains Zr.
A POLAR ADDITIVE-CONTAINING HYDROPROCESSING CATALYST AND METHOD OF MAKING AND USING THEREOF
A method of making a hydroprocessing catalyst composition that includes impregnating a support material with metals and an organic acid compound followed by a controlled drying of the impregnated support and incorporation thereafter of a polar additive into the dried, impregnated support. The hydroprocessing catalyst is made by this method.
Replaceable modular device for hydrogen release
A modular device for generating hydrogen gas from a hydrogen liquid carrier may include a housing; an inlet for receiving the hydrogen liquid carrier; and at least one cartridge arranged within the housing. The cartridge may include at least one catalyst configured to cause a release of hydrogen gas when exposed to the hydrogen liquid carrier. The modular device may include a gas outlet for expelling the hydrogen gas released in the modular device and a liquid outlet for expelling spent hydrogen liquid carrier.
Catalytic system for the treatment of an exhaust gas of a combustion engine
The present invention relates a system for the treatment of an exhaust gas of a diesel combustion engine, said system comprising a specific NOx adsorber component, a diesel oxidation catalyst (DOC) component, a selective catalytic reduction (SCR) component, a gas heating component, and a reductant injector, wherein in said system, the specific NOx adsorber component is arranged upstream of the gas heating component, the reductant injector is arranged up-stream of the SCR component, the gas heating component is arranged upstream of the reductant injector, the DOC component is arranged upstream of the reductant injector, and the DOC component and the gas heating component are directly consecutive components. Further, the present invention relates a process for preparing such a system and use thereof.
Purification Of Bio Based Acrylic Acid To Crude And Glacial Acrylic Acid
Processes for the purification of bio-based acrylic acid to crude and glacial acrylic acid are provided. The bio-based acrylic acid is produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof. The purification includes some or all of the following processes: extraction, drying, distillation, and melt crystallization. The produced glacial or crude acrylic acid contains hydroxypropionic, hydroxypropionic acid derivatives, or mixtures thereof as an impurity.
Process for production of acrylic acid or its derivatives from hydroxypropionic acid or its derivatives
Processes for the catalytic dehydration of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propanoic acid, and acetic acid, are provided.
Non-precious metal based water electrolysis catalyst for oxygen evolution at anode and hydrogen evolution at cathode and preparation method of the same
Disclosed is a non-precious metal based water electrolysis catalyst represented by CoX/C (X is at least one selected from the group consisting of P, O, B, S and N) for evolution of hydrogen and oxygen at a cathode and anode, respectively, at the same time, the catalyst including a cobalt-containing compound fixed to a carbon carrier.
CATALYST AND PROCESS FOR SELECTIVE PRODUCTION OF LOWER HYDROCARBONS C1-C5 FROM SYNGAS WITH LOW METHANE AND CO2 PRODUCTION
A catalyst composition containing cobalt manganese oxide which is modified with silicon in the form of a hydrophilic silica, the catalyst also containing at least one of lanthanum, phosphorus, Fe, Zr, and Zn, and optionally one or more basic elements selected from the group of alkali metal, alkaline earth metal, and transition metals. Also, methods for preparing and using the catalyst composition for producing aliphatic and aromatic hydrocarbons using the catalyst composition.