Disclosed are cathodes comprising a conductive support substrate having an electrocatalyst coating containing nickel phosphide nanoparticles. The conductive support substrate is capable of incorporating a material to be reduced, such as CO.sub.2 or CO. A co-catalyst, either incorporated into the electrolyte solution, or adsorbed to, deposited on, or incorporated into the bulk cathode material, provides increased selectivity and activity of the nickel phosphide electrocatalyst. Also disclosed are electrochemical methods for selectively generating hydrocarbon and/or carbohydrate products from CO.sub.2 or CO using water as a source of hydrogen.

An oligomerization catalyst, oligomer products, methods for making and using same. The catalyst can include a supported nickel phosphate compound. The catalyst is stable at oligomerization temperatures of 500 C. or higher and particularly useful for making oligomer products containing C4 to C26 olefins having a boiling point in the range of 170 C. to 360 C.

An oligomerization catalyst, oligomer products, methods for making and using same. The catalyst can include a supported nickel phosphate compound. The catalyst is stable at oligomerization temperatures of 500 C. or higher and particularly useful for making oligomer products containing C4 to C26 olefins having a boiling point in the range of 170 C. to 360 C.

Disclosed are cathodes comprising a conductive support substrate having a catalyst coating containing nickel phosphide nanoparticles. The conductive support substrate is capable of incorporating a material to be reduced, such as CO.sub.2 or CO. Also disclosed are electrochemical methods for generating hydrocarbon and/or carbohydrate products from CO.sub.2 or CO using water as a source of hydrogen.

The invention relates to a supported catalyst that comprises an oxide substrate that is for the most part calcined aluminum and an active phase that comprises nickel, with the nickel content being between 5 and 65% by weight of said element in relation to the total mass of the catalyst, with said active phase not comprising a metal from group VIB, the nickel particles having a diameter that is less than or equal to 20 nm, said catalyst having a median mesopore diameter of between 8 nm and 25 nm, a median macropore diameter of greater than 200 nm, a mesopore volume that is measured by mercury porosimetry that is greater than or equal to 0.30 mL/g, and a total pore volume that is measured by mercury porosimetry that is greater than or equal to 0.34 mL/g. The invention also relates to the method for preparation of said catalyst and its use in a hydrogenation method.

The present disclosure relates to a catalyst for dehydration of glycerin, a preparation method thereof, and a production method of acrolein using the catalyst. Particularly, the catalyst according to an embodiment of the present disclosure is used in a dehydration reaction of glycerin to exhibit high catalytic activity, a high yield, and high selectivity to acrolein and acrylic acid, and has a longer lifetime compared to the conventional catalysts due to a characteristic that coke carbon cannot be easily deposited on the surface of the catalyst.

The invention provides a continuous preparation method of 2,3,3,3-tetrafluoropropene, comprising the following steps: carrying out liquid-phase catalytic telomerization reaction on ethylene and carbon tetrachloride serving as initial raw materials in the presence of a composite catalyst to obtain a reaction product; performing two-stage membrane separation and purification on the reaction product, and then sequentially performing a primary high-temperature cracking reaction, a gas-phase chlorination reaction, a secondary high-temperature cracking reaction, a primary gas-phase catalytic fluorination reaction and a secondary gas-phase catalytic fluorination reaction to obtain a reaction product; condensing and rectifying the secondary gas-phase catalytic fluorination reaction product to obtain the 2,3,3,3-tetrafluoropropene product.

This present disclosure is directed to methods for the preparation of a hydrotreatment catalyst, such as nanoscale nickel phosphide (i.e., Ni.sub.2P) particles supported on high-surface area metal oxides (e.g., silica, alumina, amorphous silica-alumina), in a manner that is compatible with conditions employed in commercial hydrotreating units. The catalyst synthesis includes impregnation, drying, and in situ reduction, and can provide highly active catalysts for the removal of S and N impurities from crude oil fractions.

A fuel tank for storing a hydrogen liquid carrier and a spent hydrogen liquid carrier includes a substantially rigid exterior tank wall including a first chamber and a second chamber. The first chamber is fluidly disconnected from the second chamber, and the second chamber includes a dynamically expandable and contractible enclosure, the enclosure being configured to define a dynamic boundary between the hydrogen liquid carrier and spent hydrogen liquid carrier. The fuel tank also includes a first channel in flow communication with one of the first chamber or the second chamber and a second channel in flow communication with another of the first chamber or the second chamber, wherein the first channel and the second channel are flow connected such that a flow through one of the first or second channels is returned to the another of the first or second channels, and that during the flow, the dynamic boundary changes position causing a change in a volume of the second chamber.

A modular device for generating hydrogen gas from a hydrogen liquid carrier may include a housing;

an inlet for receiving the hydrogen liquid carrier; and at least one cartridge arranged within the housing. The cartridge may include at least one catalyst configured to cause a release of hydrogen gas when exposed to the hydrogen liquid carrier. The modular device may include a gas outlet for expelling the hydrogen gas released in the modular device and a liquid outlet for expelling spent hydrogen liquid carrier.