Bio-based glacial acrylic acid, produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof and having impurities of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof, is polymerized to poly(acrylic acid) or superabsorbent polymer using the same processes as petroleum-derived glacial acrylic acid.

Methods for converting an alcohol, such as cyclohexanol to a ketone, such as cyclohexanone, include reacting the alcohol in the presence of a catalyst and oxygen to produce the ketone. In one exemplary embodiment, the catalyst comprises a microporous copper chloropyrophosphate framework including a plurality of noble metal nanoparticles. In one exemplary embodiment, the noble metal nanoparticles include at least one metal selected from the group consisting of platinum, palladium, and gold.

The present disclosure provides an exhaust gas purification catalyst having improved performance for purifying an exhaust gas, in particular, an exhaust gas containing NOx. The exhaust gas purification catalyst of the present disclosure includes Rh-supporting composite oxide support particles containing Al, Zr, and Ti and Rh-supporting aluminum phosphate-based support particles. Furthermore, in the exhaust gas purification catalyst of the present disclosure, the ratio of the moles of metals constituting the aluminum phosphate-based support particles, relative to the total moles of metals constituting the composite oxide support particles and the aluminum phosphate-based support particles is 7.5% or more and 15.0% or less.

An object of the present invention is to provide an exhaust gas purification catalyst having improved exhaust gas (e.g., NOx) purifying performance at low to medium temperature. In order to achieve the object, the present invention provides an exhaust gas purification catalyst including: a substrate; and a catalyst layer formed on the substrate, wherein the catalyst layer contains rhodium element, phosphorus element and a rare earth element other than cerium element, wherein a ratio of a mass of the phosphorus element contained in the catalyst layer to the mass of the rhodium element contained in the catalyst layer is from 1 to 10, and wherein a ratio of a mass of the rare earth element other than cerium element in terms of an oxide thereof contained in the catalyst layer to the mass of the rhodium element contained in the catalyst layer is from 1 to 5.

Synthesis of metallic glass nanoparticles and compositions thereof, including, particularly, the kinetically controlled synthesis of glass nanoparticles by flash carbothermic reactions and compositions thereof.

An object of the present invention is to provide a method for selectively producing a hydroxycarboxylic acid ester, the method including reducing a dicarboxylic acid monoester by means of a heterogeneous reaction. According to a method for producing a hydroxycarboxylic acid ester in an embodiment of the present invention, a hydroxycarboxylic acid ester represented by Formula (2) is produced by reducing a substrate dicarboxylic acid monoester represented by Formula (1) in the presence of a catalyst.

The catalyst comprises: metal species including M.sub.1 and M.sub.2; and a support supporting the metal species, and wherein M.sub.1 is rhodium, platinum, ruthenium, iridium or palladium; M.sub.2 is tin, vanadium, molybdenum, tungsten or rhenium; and the support is hydroxyapatite, fluorapatite, or hydrotalcite.

##STR00001##

The present invention relates to a method for preparing 2-chloro-N-(1-cyanocyclopropyl)-5-[2-methyl-5-(pentafluoroethyl)-4-(trifluoromethyl)-2H-1,3-bipyrazol-4-yl]benzamide, i.e. the compound of the formula (I) and to a method for purifying the compound of the formula I. The present invention additionally relates to new crystal forms of the compound of the formula I. ##STR00001##

The present invention discloses a process for the hydrogenation of imines of Formula I by palladium-based catalyst to provide product of Formula II with more than 95% conversion of substrate and more than 95% of desired hydrogenated product. ##STR00001##