Patent classifications
B01J27/224
CATALYST HAVING A MODIFIED SILICON CARBIDE SUPPORT AND ITS USE AS A HYDROGENATION CATALYST
Impure aromatic carboxylic acids such as are obtained by liquid phase oxidation of feed materials comprising aromatic compounds with substituent groups oxidizable to carboxylic acid groups, or comprising aromatic carboxylic acid and one or more aromatic carbonyl impurities that form hydrogenated species more soluble in aqueous solvents or with less color or color-forming tendencies than the aromatic carbonyl impurity, are purified to an aromatic carboxylic acid product with lower levels of impurities by a process comprising contacting an aqueous solution comprising the impure aromatic carboxylic acid with hydrogen at elevated temperature and pressure with an attrition-resistance, acid stable catalyst composition comprising at least one hydrogenation catalyst metal and a support comprising relatively high surface area of high porosity silicon carbide with low levels of iron and alkali metal impurities. The support may further contain titanium or rare earth metals.
Method for manufacturing honeycomb structure containing silicon carbide
A method for manufacturing a honeycomb structure containing silicon carbide, including blending a recycled raw material derived from a material constituting a first honeycomb structure containing silicon carbide in a process after firing as a part of an initial raw material for a second honeycomb structure containing silicon carbide, wherein the initial raw material comprises silicon carbide and metallic silicon; and the recycled raw material is a powder recovered from the material constituting the first honeycomb structure containing silicon carbide in the process after firing, and after the recovering, a particle size is adjusted so that a 10% diameter (D10) is 10 ?m or more and a 50% diameter (D50) is 35 ?m or less when a cumulative particle size distribution on a volume basis is measured by a laser diffraction/scattering method.
Method for manufacturing honeycomb structure containing silicon carbide
A method for manufacturing a honeycomb structure containing silicon carbide, including blending a recycled raw material derived from a material constituting a first honeycomb structure containing silicon carbide in a process after firing as a part of an initial raw material for a second honeycomb structure containing silicon carbide, wherein the initial raw material comprises silicon carbide and metallic silicon; and the recycled raw material is a powder recovered from the material constituting the first honeycomb structure containing silicon carbide in the process after firing, and after the recovering, a particle size is adjusted so that a 10% diameter (D10) is 10 ?m or more and a 50% diameter (D50) is 35 ?m or less when a cumulative particle size distribution on a volume basis is measured by a laser diffraction/scattering method.
Synthesis of trifluoroacetyl iodide (TFAI) from trifluoroacetyl chloride (TFAC) and hydrogen iodide (HI) in a liquid phase reaction
The present disclosure provides a process for making trifluoroacetyl iodide (TFAI) in a liquid phase reaction. Specifically, the present disclosure provides a liquid phase reaction of trifluoroacetyl chloride (TFAC) and hydrogen iodide (HI), with or without a catalyst, to form trifluoroacetyl iodide (TFAI). The reaction may be performed at ambient or elevated temperatures.
Porous iron-silicate with radially developed branch, and iron-carbide/silica composite catalyst prepared therefrom
The present invention provides an iron-carbide/silica composite catalyst that is highly reactive to a Fischer-Tropsch synthesis by firstly forming an iron-silicate structure having large specific surface area and well-developed pores through a hydrothermal reaction of an iron salt with a silica particle having a nanostructure, and then activating the iron-silicate structure in a high temperature carbon monoxide atmosphere. When using the iron-carbide/silica composite catalyst according to the present invention in the Fischer-Tropsch synthesis reaction, it is possible to effectively prepare liquid hydrocarbon with a high CO conversion rate and selectivity.
Method of Producing a Body Comprising Porous Alpha Silicon Carbide and the Body Produced by the Method
The present invention relates to a method of producing porous alpha-SiC containing shaped body and porous alpha-SiC containing shaped body produced by that method. The porous alpha-SiC containing shaped body shows a characteristic microstructure providing a high degree of mechanical stability.
Method of Producing a Body Comprising Porous Alpha Silicon Carbide and the Body Produced by the Method
The present invention relates to a method of producing porous alpha-SiC containing shaped body and porous alpha-SiC containing shaped body produced by that method. The porous alpha-SiC containing shaped body shows a characteristic microstructure providing a high degree of mechanical stability.
HONEYCOMB-TYPE HEATING DEVICE AND METHOD OF USING SAME
A honeycomb-type heating device includes a pillar-shaped honeycomb substrate that has partition walls defining a plurality of cells and that has a circumferential wall surrounding the partition walls; a plurality of heaters adjacently arranged on a circumferential face in a circumferential direction of the circumferential face that is an outer surface of the circumferential wall; a coated wire electrically connecting the plurality of heaters; and a metal case housing the honeycomb substrate and the plurality of heaters. Each of the plurality of heaters has an electrode for energization and is a resistance heating type heater that generates heat due to energization, the metal case has hole parts for protruding the electrodes of respective heaters to the outside of the metal case, and the coated wire electrically connects, outside the metal case, the electrodes of respective heaters protruding to the outside of the metal case from the hole parts.
DEVICE FOR CATALYTIC CONVERSION HAVING A REDUCED ACTIVATION TIME
A device for catalytic conversion of NOx to 8 and/or of CO to CO2, including: a ceramic support including at least a plurality of channels; a thermal barrier made of thermal insulating material covering at least one part of the internal surface of the channels; porous SiC at least partially covering the thermal barrier such that the SiC is separated from the support by the thermal barrier; one or more conversion catalysts at least on the SiC.
DEVICE FOR CATALYTIC CONVERSION HAVING A REDUCED ACTIVATION TIME
A device for catalytic conversion of NOx to 8 and/or of CO to CO2, including: a ceramic support including at least a plurality of channels; a thermal barrier made of thermal insulating material covering at least one part of the internal surface of the channels; porous SiC at least partially covering the thermal barrier such that the SiC is separated from the support by the thermal barrier; one or more conversion catalysts at least on the SiC.